百科

(4E,7S)-N-[(2Z)-((5R)-5-allyloxy-2-oxocyclohex-1-enyl)-2-chloromethyleneethyl]-7-methoxytetradec-4-enamide

(4E,7S)-N-[(2Z)-((5R)-5-allyloxy-2-oxocyclohex-1-enyl)-2-chloromethyleneethyl]-7-methoxytetradec-4-enamide

CAS号：1303528-22-4

英文名：(4E,7S)-N-[(2Z)-((5R)-5-allyloxy-2-oxocyclohex-1-enyl)-2-chloromethyleneethyl]-7-methoxytetradec-4-enamide

分子式：C27H42ClNO4

分子量：480.08

合成路线

(R)-2-bromo-4-tert-butyldimethylsilyloxycyclohex-2-enone

(R)-2-bromo-4-tert-butyldimethylsilyloxycyclohex-2-enone

(4E,7S)-N-[(2Z)-((5R)-5-allyloxy-2-oxocyclohex-1-enyl)-2-chloromethyleneethyl]-7-methoxytetradec-4-enamide

(4E,7S)-N-[(2Z)-((5R)-5-allyloxy-2-oxocyclohex-1-enyl)-2-chloromethyleneethyl]-7-methoxytetradec-4-enamide

1303528-18-8

(4E,7S)-N-[(2Z)-((5R)-5-allyloxy-2-oxocyclohex-1-enyl)-2-chloromethyleneethyl]-7-methoxytetradec-4-enamide

(4E,7S)-N-[(2Z)-((5R)-5-allyloxy-2-oxocyclohex-1-enyl)-2-chloromethyleneethyl]-7-methoxytetradec-4-enamide

(8R)-6-bromo-8-hydroxy-spiro-[4.5]dec-6-ene

(8R)-6-bromo-8-hydroxy-spiro-[4.5]dec-6-ene

(4E,7S)-N-[(2Z)-((5R)-5-allyloxy-2-oxocyclohex-1-enyl)-2-chloromethyleneethyl]-7-methoxytetradec-4-enamide

(4E,7S)-N-[(2Z)-((5R)-5-allyloxy-2-oxocyclohex-1-enyl)-2-chloromethyleneethyl]-7-methoxytetradec-4-enamide

(8R)-8-allyloxy-6-bromospiro-[4.5]dec-6-ene

(8R)-8-allyloxy-6-bromospiro-[4.5]dec-6-ene

(4E,7S)-N-[(2Z)-((5R)-5-allyloxy-2-oxocyclohex-1-enyl)-2-chloromethyleneethyl]-7-methoxytetradec-4-enamide

(4E,7S)-N-[(2Z)-((5R)-5-allyloxy-2-oxocyclohex-1-enyl)-2-chloromethyleneethyl]-7-methoxytetradec-4-enamide

(+)-(R)-4-hydroxycyclohex-2-enone

(+)-(R)-4-hydroxycyclohex-2-enone

(4E,7S)-N-[(2Z)-((5R)-5-allyloxy-2-oxocyclohex-1-enyl)-2-chloromethyleneethyl]-7-methoxytetradec-4-enamide

(4E,7S)-N-[(2Z)-((5R)-5-allyloxy-2-oxocyclohex-1-enyl)-2-chloromethyleneethyl]-7-methoxytetradec-4-enamide

上游原料

(8R)-8-allyloxy-6-bromospiro-[4.5]dec-6-ene (R)-2-bromo-4-tert-butyldimethylsilyloxycyclohex-2-enone (+)-(R)-4-hydroxycyclohex-2-enone (8R)-6-bromo-8-hydroxy-spiro-[4.5]dec-6-ene

下游产品

5''-epi-malyngamide C (4E,7S)-N-[(2Z)-2-((1S,5R,6S)-5-tert-butyldimethylsilyloxy-2-oxo-7-oxabicyclo[4.1.0]heptan-1-yl)-2-chloromethyleneethyl]methoxytetradec-4-enamide