百科

(+)-9(1E,3Z)-(9S,10S)-9-(5-hydroxy-3-methyl-1,3-pentadienyl)-3,3,8,8,10-pentamethyl-1,5-dioxaspiro<5,5>undecan-9-ol

(+)-9(1E,3Z)-(9S,10S)-9-(5-hydroxy-3-methyl-1,3-pentadienyl)-3,3,8,8,10-pentamethyl-1,5-dioxaspiro<5,5>undecan-9-ol

CAS号：130694-73-4

英文名：(+)-9(1E,3Z)-(9S,10S)-9-(5-hydroxy-3-methyl-1,3-pentadienyl)-3,3,8,8,10-pentamethyl-1,5-dioxaspiro<5,5>undecan-9-ol

分子式：C20H34O4

分子量：338.482

合成路线

(+)-(4R,6S)-4-tert-butyldimethylsiloxy-2,2,6-trimethylcyclohexanone

(+)-(4R,6S)-4-tert-butyldimethylsiloxy-2,2,6-trimethylcyclohexanone

(+)-9(1E,3Z)-(9S,10S)-9-(5-hydroxy-3-methyl-1,3-pentadienyl)-3,3,8,8,10-pentamethyl-1,5-dioxaspiro<5,5>undecan-9-ol

(+)-9(1E,3Z)-(9S,10S)-9-(5-hydroxy-3-methyl-1,3-pentadienyl)-3,3,8,8,10-pentamethyl-1,5-dioxaspiro<5,5>undecan-9-ol

(+)-1(Z)-(1R,4R,6S)-4-tert-butyldimethylsiloxy-1-(5-hydroxy-3-methylpent-3-en-1-ynyl)-2,2,6-trimethylcyclohexanol

(+)-1(Z)-(1R,4R,6S)-4-tert-butyldimethylsiloxy-1-(5-hydroxy-3-methylpent-3-en-1-ynyl)-2,2,6-trimethylcyclohexanol

(+)-9(1E,3Z)-(9S,10S)-9-(5-hydroxy-3-methyl-1,3-pentadienyl)-3,3,8,8,10-pentamethyl-1,5-dioxaspiro<5,5>undecan-9-ol

(+)-9(1E,3Z)-(9S,10S)-9-(5-hydroxy-3-methyl-1,3-pentadienyl)-3,3,8,8,10-pentamethyl-1,5-dioxaspiro<5,5>undecan-9-ol

上游原料

(+)-(4R,6S)-4-tert-butyldimethylsiloxy-2,2,6-trimethylcyclohexanone (+)-1(Z)-(1R,4R,6S)-4-tert-butyldimethylsiloxy-1-(5-hydroxy-3-methylpent-3-en-1-ynyl)-2,2,6-trimethylcyclohexanol

下游产品

(+)-(4S,5S)-methyl dihydroabscisate (+)-4(1E,3Z)-(4S,5S)-4-hydroxy-4-(5-hydroxy-3-methyl-1,3-pentadienyl)-3,3,5-trimethylcyclohexanone