百科

methyl (8E,10S,11S,12S)-2,3-di-O-benzyl-1,4-dideoxy-1β-<11-methyl-12-triphenylmethoxymethylcyclopropylethenyl>-D-glucoheptopyranuronate

methyl (8E,10S,11S,12S)-2,3-di-O-benzyl-1,4-dideoxy-1β-<11-methyl-12-triphenylmethoxymethylcyclopropylethenyl>-D-glucoheptopyranuronate

CAS号：130799-09-6

英文名：methyl (8E,10S,11S,12S)-2,3-di-O-benzyl-1,4-dideoxy-1β-<11-methyl-12-triphenylmethoxymethylcyclopropylethenyl>-D-glucoheptopyranuronate

分子式：C48H50O6

分子量：722.907

合成路线

menthyl (1S,2S,3S)-2-(2,2-dibromovinyl)-3-methylcyclopropane-1-carboxylate

menthyl (1S,2S,3S)-2-(2,2-dibromovinyl)-3-methylcyclopropane-1-carboxylate

methyl (8E,10S,11S,12S)-2,3-di-O-benzyl-1,4-dideoxy-1β-<11-methyl-12-triphenylmethoxymethylcyclopropylethenyl>-D-glucoheptopyranuronate

methyl (8E,10S,11S,12S)-2,3-di-O-benzyl-1,4-dideoxy-1β-<11-methyl-12-triphenylmethoxymethylcyclopropylethenyl>-D-glucoheptopyranuronate

methyl 2,3-di-O-benzyl-6-O-t-butyldiphenylsilyl-4-deoxy-α-D-glucopyranoside

methyl 2,3-di-O-benzyl-6-O-t-butyldiphenylsilyl-4-deoxy-α-D-glucopyranoside

methyl (8E,10S,11S,12S)-2,3-di-O-benzyl-1,4-dideoxy-1β-<11-methyl-12-triphenylmethoxymethylcyclopropylethenyl>-D-glucoheptopyranuronate

methyl (8E,10S,11S,12S)-2,3-di-O-benzyl-1,4-dideoxy-1β-<11-methyl-12-triphenylmethoxymethylcyclopropylethenyl>-D-glucoheptopyranuronate

[(1S,2S,3S)-2-(2,2-Dibromo-vinyl)-3-methyl-cyclopropyl]-methanol

[(1S,2S,3S)-2-(2,2-Dibromo-vinyl)-3-methyl-cyclopropyl]-methanol

methyl (8E,10S,11S,12S)-2,3-di-O-benzyl-1,4-dideoxy-1β-<11-methyl-12-triphenylmethoxymethylcyclopropylethenyl>-D-glucoheptopyranuronate

methyl (8E,10S,11S,12S)-2,3-di-O-benzyl-1,4-dideoxy-1β-<11-methyl-12-triphenylmethoxymethylcyclopropylethenyl>-D-glucoheptopyranuronate

130798-98-0

130799-08-5

methyl (8E,10S,11S,12S)-2,3-di-O-benzyl-1,4-dideoxy-1β-<11-methyl-12-triphenylmethoxymethylcyclopropylethenyl>-D-glucoheptopyranuronate

methyl (8E,10S,11S,12S)-2,3-di-O-benzyl-1,4-dideoxy-1β-<11-methyl-12-triphenylmethoxymethylcyclopropylethenyl>-D-glucoheptopyranuronate

上游原料

menthyl (1S,2S,3S)-2-(2,2-dibromovinyl)-3-methylcyclopropane-1-carboxylate [(1S,2S,3S)-2-(2,2-Dibromo-vinyl)-3-methyl-cyclopropyl]-methanol methyl 2,3-di-O-benzyl-6-O-t-butyldiphenylsilyl-4-deoxy-α-D-glucopyranoside

下游产品

methyl 5β,6α-dihydroxypolyangioate 安布替星 {(2S,4S,5R,6S)-4,5-Bis-benzyloxy-6-[(E)-2-((1S,2S,3S)-2-hydroxymethyl-3-methyl-cyclopropyl)-vinyl]-tetrahydro-pyran-2-yl}-acetic acid methyl ester