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(4E,7S)-N-{(2R)-2-[(4R,5S,6R)-6-benzyloxy-4-(tert-butyldimethylsilyloxy)-5-methylcyclohex-1-enyl]-2-hydroxyethyl}-7-methoxydodec-4-enamide

(4E,7S)-N-{(2R)-2-[(4R,5S,6R)-6-benzyloxy-4-(tert-butyldimethylsilyloxy)-5-methylcyclohex-1-enyl]-2-hydroxyethyl}-7-methoxydodec-4-enamide

CAS号：1309930-59-3

英文名：(4E,7S)-N-{(2R)-2-[(4R,5S,6R)-6-benzyloxy-4-(tert-butyldimethylsilyloxy)-5-methylcyclohex-1-enyl]-2-hydroxyethyl}-7-methoxydodec-4-enamide

分子式：C35H59NO5Si

分子量：601.932

合成路线

(2R,3R,5R)-3-hydroxy-2-methyl-5-(1-methylethenyl)cyclohexanone

(2R,3R,5R)-3-hydroxy-2-methyl-5-(1-methylethenyl)cyclohexanone

(4E,7S)-N-{(2R)-2-[(4R,5S,6R)-6-benzyloxy-4-(tert-butyldimethylsilyloxy)-5-methylcyclohex-1-enyl]-2-hydroxyethyl}-7-methoxydodec-4-enamide

(4E,7S)-N-{(2R)-2-[(4R,5S,6R)-6-benzyloxy-4-(tert-butyldimethylsilyloxy)-5-methylcyclohex-1-enyl]-2-hydroxyethyl}-7-methoxydodec-4-enamide

1309930-56-0

(4E,7S)-N-{(2R)-2-[(4R,5S,6R)-6-benzyloxy-4-(tert-butyldimethylsilyloxy)-5-methylcyclohex-1-enyl]-2-hydroxyethyl}-7-methoxydodec-4-enamide

(4E,7S)-N-{(2R)-2-[(4R,5S,6R)-6-benzyloxy-4-(tert-butyldimethylsilyloxy)-5-methylcyclohex-1-enyl]-2-hydroxyethyl}-7-methoxydodec-4-enamide

(5R,6R)-5-((tert-butyldimethylsilyl)oxy)-6-methylcyclohex-2-en-1-one

(5R,6R)-5-((tert-butyldimethylsilyl)oxy)-6-methylcyclohex-2-en-1-one

(4E,7S)-N-{(2R)-2-[(4R,5S,6R)-6-benzyloxy-4-(tert-butyldimethylsilyloxy)-5-methylcyclohex-1-enyl]-2-hydroxyethyl}-7-methoxydodec-4-enamide

(4E,7S)-N-{(2R)-2-[(4R,5S,6R)-6-benzyloxy-4-(tert-butyldimethylsilyloxy)-5-methylcyclohex-1-enyl]-2-hydroxyethyl}-7-methoxydodec-4-enamide

1309930-42-4

(4E,7S)-N-{(2R)-2-[(4R,5S,6R)-6-benzyloxy-4-(tert-butyldimethylsilyloxy)-5-methylcyclohex-1-enyl]-2-hydroxyethyl}-7-methoxydodec-4-enamide

(4E,7S)-N-{(2R)-2-[(4R,5S,6R)-6-benzyloxy-4-(tert-butyldimethylsilyloxy)-5-methylcyclohex-1-enyl]-2-hydroxyethyl}-7-methoxydodec-4-enamide

(1R,5R,6S)-5-((tert-butyldimethylsilyl)oxy)-2-iodo-6-methylcyclohex-2-en-1-ol

(1R,5R,6S)-5-((tert-butyldimethylsilyl)oxy)-2-iodo-6-methylcyclohex-2-en-1-ol

(4E,7S)-N-{(2R)-2-[(4R,5S,6R)-6-benzyloxy-4-(tert-butyldimethylsilyloxy)-5-methylcyclohex-1-enyl]-2-hydroxyethyl}-7-methoxydodec-4-enamide

(4E,7S)-N-{(2R)-2-[(4R,5S,6R)-6-benzyloxy-4-(tert-butyldimethylsilyloxy)-5-methylcyclohex-1-enyl]-2-hydroxyethyl}-7-methoxydodec-4-enamide

[(1R,5R,6S)-5-benzyloxy-4-iodo-6-methylcyclohex-3-enyloxy]-tert-butyldimethylsilane

[(1R,5R,6S)-5-benzyloxy-4-iodo-6-methylcyclohex-3-enyloxy]-tert-butyldimethylsilane

(4E,7S)-N-{(2R)-2-[(4R,5S,6R)-6-benzyloxy-4-(tert-butyldimethylsilyloxy)-5-methylcyclohex-1-enyl]-2-hydroxyethyl}-7-methoxydodec-4-enamide

(4E,7S)-N-{(2R)-2-[(4R,5S,6R)-6-benzyloxy-4-(tert-butyldimethylsilyloxy)-5-methylcyclohex-1-enyl]-2-hydroxyethyl}-7-methoxydodec-4-enamide

1309930-36-6

(4E,7S)-N-{(2R)-2-[(4R,5S,6R)-6-benzyloxy-4-(tert-butyldimethylsilyloxy)-5-methylcyclohex-1-enyl]-2-hydroxyethyl}-7-methoxydodec-4-enamide

(4E,7S)-N-{(2R)-2-[(4R,5S,6R)-6-benzyloxy-4-(tert-butyldimethylsilyloxy)-5-methylcyclohex-1-enyl]-2-hydroxyethyl}-7-methoxydodec-4-enamide

(2R,3R,5R)-3-tert-butyldimethylsilyloxy-2-methyl-5-(1-methylethenyl)cyclohexanone

(2R,3R,5R)-3-tert-butyldimethylsilyloxy-2-methyl-5-(1-methylethenyl)cyclohexanone

(4E,7S)-N-{(2R)-2-[(4R,5S,6R)-6-benzyloxy-4-(tert-butyldimethylsilyloxy)-5-methylcyclohex-1-enyl]-2-hydroxyethyl}-7-methoxydodec-4-enamide

(4E,7S)-N-{(2R)-2-[(4R,5S,6R)-6-benzyloxy-4-(tert-butyldimethylsilyloxy)-5-methylcyclohex-1-enyl]-2-hydroxyethyl}-7-methoxydodec-4-enamide

(-)-(4E,7S)-7-methoxydodec-4-enoic acid

(-)-(4E,7S)-7-methoxydodec-4-enoic acid

(4E,7S)-N-{(2R)-2-[(4R,5S,6R)-6-benzyloxy-4-(tert-butyldimethylsilyloxy)-5-methylcyclohex-1-enyl]-2-hydroxyethyl}-7-methoxydodec-4-enamide

(4E,7S)-N-{(2R)-2-[(4R,5S,6R)-6-benzyloxy-4-(tert-butyldimethylsilyloxy)-5-methylcyclohex-1-enyl]-2-hydroxyethyl}-7-methoxydodec-4-enamide

上游原料

[(1R,5R,6S)-5-benzyloxy-4-iodo-6-methylcyclohex-3-enyloxy]-tert-butyldimethylsilane (2R,3R,5R)-3-hydroxy-2-methyl-5-(1-methylethenyl)cyclohexanone (2R,3R,5R)-3-tert-butyldimethylsilyloxy-2-methyl-5-(1-methylethenyl)cyclohexanone (-)-(4E,7S)-7-methoxydodec-4-enoic acid

下游产品

(4E,7S)-N-{(2R)-2-[(4R,5R)-4-(tert-butyldimethylsilyloxy)-5-methyl-6-oxocyclohex-1-enyl]-2-methoxyethyl}-7-methoxydodec-4-enamide malyngamide W