百科

(S)-3-((S)-5-benzyloxy-3-methyl-pentyl)-6-(tert-butyl-dimethyl-silanyloxy)-5,5-dimethyl-5,6,7,8-tetrahydro-naphthalene-1,2-dicarboxylic acid

(S)-3-((S)-5-benzyloxy-3-methyl-pentyl)-6-(tert-butyl-dimethyl-silanyloxy)-5,5-dimethyl-5,6,7,8-tetrahydro-naphthalene-1,2-dicarboxylic acid

CAS号：1312554-83-8

英文名：(S)-3-((S)-5-benzyloxy-3-methyl-pentyl)-6-(tert-butyl-dimethyl-silanyloxy)-5,5-dimethyl-5,6,7,8-tetrahydro-naphthalene-1,2-dicarboxylic acid

分子式：C35H52O6Si

分子量：596.869

合成路线

tert-butyl-{(S)-1-[2-(4-methoxy-benzyloxy)-1,1-dimethyl-ethyl]-pent-4-enyloxy}-dimethyl-silane

tert-butyl-{(S)-1-[2-(4-methoxy-benzyloxy)-1,1-dimethyl-ethyl]-pent-4-enyloxy}-dimethyl-silane

(S)-3-((S)-5-benzyloxy-3-methyl-pentyl)-6-(tert-butyl-dimethyl-silanyloxy)-5,5-dimethyl-5,6,7,8-tetrahydro-naphthalene-1,2-dicarboxylic acid

(S)-3-((S)-5-benzyloxy-3-methyl-pentyl)-6-(tert-butyl-dimethyl-silanyloxy)-5,5-dimethyl-5,6,7,8-tetrahydro-naphthalene-1,2-dicarboxylic acid

(2R)-1,2-epoxy-4-(p-methoxyphenyl)methoxy-3,3-dimethylbutane

(2R)-1,2-epoxy-4-(p-methoxyphenyl)methoxy-3,3-dimethylbutane

(S)-3-((S)-5-benzyloxy-3-methyl-pentyl)-6-(tert-butyl-dimethyl-silanyloxy)-5,5-dimethyl-5,6,7,8-tetrahydro-naphthalene-1,2-dicarboxylic acid

(S)-3-((S)-5-benzyloxy-3-methyl-pentyl)-6-(tert-butyl-dimethyl-silanyloxy)-5,5-dimethyl-5,6,7,8-tetrahydro-naphthalene-1,2-dicarboxylic acid

上游原料

tert-butyl-{(S)-1-[2-(4-methoxy-benzyloxy)-1,1-dimethyl-ethyl]-pent-4-enyloxy}-dimethyl-silane (2R)-1,2-epoxy-4-(p-methoxyphenyl)methoxy-3,3-dimethylbutane

下游产品

(((S)-7-((S)-5-(benzyloxy)-3-methylpentyl)-5,6-bis(bromomethyl)-1,1-dimethyl-1,2,3,4-tetrahydronaphthalen-2-yl)oxy)(tert-butyl)dimethylsilane