百科

(2R,4aR,6S,7R,8aS)-4a,6-Dimethyl-6-((2R,3R)-3-methyl-3-vinyl-oxiranylmethyl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

(2R,4aR,6S,7R,8aS)-4a,6-Dimethyl-6-((2R,3R)-3-methyl-3-vinyl-oxiranylmethyl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

CAS号：131330-95-5

英文名：(2R,4aR,6S,7R,8aS)-4a,6-Dimethyl-6-((2R,3R)-3-methyl-3-vinyl-oxiranylmethyl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

分子式：C21H28O5

分子量：360.444

合成路线

{(2R,3R)-3-[(2R,4aR,6S,7R,8aS)-7-(tert-Butyl-dimethyl-silanyloxy)-4a,6-dimethyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-ylmethyl]-2-methyl-oxiranyl}-methanol

{(2R,3R)-3-[(2R,4aR,6S,7R,8aS)-7-(tert-Butyl-dimethyl-silanyloxy)-4a,6-dimethyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-ylmethyl]-2-methyl-oxiranyl}-methanol

(2R,4aR,6S,7R,8aS)-4a,6-Dimethyl-6-((2R,3R)-3-methyl-3-vinyl-oxiranylmethyl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

(2R,4aR,6S,7R,8aS)-4a,6-Dimethyl-6-((2R,3R)-3-methyl-3-vinyl-oxiranylmethyl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

Trimethyl-[(2R,4S,5R)-5-methyl-4-((2R,3R)-3-methyl-3-vinyl-oxiranylmethyl)-2-phenyl-[1,3]dioxan-5-yloxy]-silane

Trimethyl-[(2R,4S,5R)-5-methyl-4-((2R,3R)-3-methyl-3-vinyl-oxiranylmethyl)-2-phenyl-[1,3]dioxan-5-yloxy]-silane

(2R,4aR,6S,7R,8aS)-4a,6-Dimethyl-6-((2R,3R)-3-methyl-3-vinyl-oxiranylmethyl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

(2R,4aR,6S,7R,8aS)-4a,6-Dimethyl-6-((2R,3R)-3-methyl-3-vinyl-oxiranylmethyl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

(E)-2-Methyl-4-((2R,4S,5R)-5-methyl-2-phenyl-5-trimethylsilanyloxy-[1,3]dioxan-4-yl)-but-2-en-1-ol

(E)-2-Methyl-4-((2R,4S,5R)-5-methyl-2-phenyl-5-trimethylsilanyloxy-[1,3]dioxan-4-yl)-but-2-en-1-ol

(2R,4aR,6S,7R,8aS)-4a,6-Dimethyl-6-((2R,3R)-3-methyl-3-vinyl-oxiranylmethyl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

(2R,4aR,6S,7R,8aS)-4a,6-Dimethyl-6-((2R,3R)-3-methyl-3-vinyl-oxiranylmethyl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

上游原料

{(2R,3R)-3-[(2R,4aR,6S,7R,8aS)-7-(tert-Butyl-dimethyl-silanyloxy)-4a,6-dimethyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-ylmethyl]-2-methyl-oxiranyl}-methanol Trimethyl-[(2R,4S,5R)-5-methyl-4-((2R,3R)-3-methyl-3-vinyl-oxiranylmethyl)-2-phenyl-[1,3]dioxan-5-yloxy]-silane (E)-2-Methyl-4-((2R,4S,5R)-5-methyl-2-phenyl-5-trimethylsilanyloxy-[1,3]dioxan-4-yl)-but-2-en-1-ol

下游产品

(E)-3-[(2R,3S,4aR,6S,7R,8aS)-7-Benzyloxy-6-(2-benzyloxy-ethyl)-3-(tert-butyl-dimethyl-silanyloxy)-2,6,8a-trimethyl-octahydro-pyrano[3,2-b]pyran-2-yl]-acrylic acid methyl ester 2-((2R,4aR,6R,7S,8aR,9aS,10aS)-6-Benzyloxy-4a,7,10a-trimethyl-2-phenyl-octahydro-1,3,8,10-tetraoxa-anthracen-7-yl)-ethanol