百科

(5S,7R)-5-((1S,E)-1-((4-methoxybenzyl)oxy)-5-((tetrahydro-2H-pyran-2-yl)oxy)pent-3-en-1-yl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

CAS号：1313511-86-2

英文名：(5S,7R)-5-((1S,E)-1-((4-methoxybenzyl)oxy)-5-((tetrahydro-2H-pyran-2-yl)oxy)pent-3-en-1-yl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

分子式：C35H64O6Si2

分子量：637.05

合成路线

83632-96-6

6-tetrahydropyranyloxy-4-hexen-1-ol

1313511-86-2

(5S,7R)-5-((1S,E)-1-((4-methoxybenzyl)oxy)-5-((tetrahydro-2H-pyran-2-yl)oxy)pent-3-en-1-yl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

1313511-82-8

(2S,E)-6-((tetrahydro-2H-pyran-2-yl)oxy)hex-4-ene-1,2-diol

1313511-86-2

(5S,7R)-5-((1S,E)-1-((4-methoxybenzyl)oxy)-5-((tetrahydro-2H-pyran-2-yl)oxy)pent-3-en-1-yl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

1313511-83-9

1313511-86-2

(5S,7R)-5-((1S,E)-1-((4-methoxybenzyl)oxy)-5-((tetrahydro-2H-pyran-2-yl)oxy)pent-3-en-1-yl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

1313511-84-0

(2S,E)-2-((4-methoxybenzyl)oxy)-6-((tetrahydro-2H-pyran-2-yl)oxy)hex-4-en-1-ol

1313511-86-2

(5S,7R)-5-((1S,E)-1-((4-methoxybenzyl)oxy)-5-((tetrahydro-2H-pyran-2-yl)oxy)pent-3-en-1-yl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

1313511-94-2

1313511-86-2

(5S,7R)-5-((1S,E)-1-((4-methoxybenzyl)oxy)-5-((tetrahydro-2H-pyran-2-yl)oxy)pent-3-en-1-yl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

1313511-73-7

(2S,E)-N-methoxy-2-((4-methoxybenzyl)oxy)-N-methyl-6-((tetrahydro-2H-pyran-2-yl)oxy)hex-4-enamide

1313511-86-2

(5S,7R)-5-((1S,E)-1-((4-methoxybenzyl)oxy)-5-((tetrahydro-2H-pyran-2-yl)oxy)pent-3-en-1-yl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

1313511-85-1

(2R,5S,E)-1-((tert-butyldimethylsilyl)oxy)-5-((4-methoxybenzyl)oxy)-2-methyl-9-((tetrahydro-2H-pyran-2-yl)oxy)non-7-en-4-one

1313511-86-2

(5S,7R)-5-((1S,E)-1-((4-methoxybenzyl)oxy)-5-((tetrahydro-2H-pyran-2-yl)oxy)pent-3-en-1-yl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

上游原料

(2S,E)-N-methoxy-2-((4-methoxybenzyl)oxy)-N-methyl-6-((tetrahydro-2H-pyran-2-yl)oxy)hex-4-enamide (2S,E)-6-((tetrahydro-2H-pyran-2-yl)oxy)hex-4-ene-1,2-diol (2S,E)-2-((4-methoxybenzyl)oxy)-6-((tetrahydro-2H-pyran-2-yl)oxy)hex-4-en-1-ol 6-tetrahydropyranyloxy-4-hexen-1-ol

下游产品

(3aS,4E,7S,11S,12aS,13aS,14E,15aS)-2,2,7-trimethyl-11-((5S,7R)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecan-5-yl)-6,7,8,11,12,12a,13a,15a-octahydro-[1,3]dioxolo[4,5-h]oxireno[2,3-d][1]oxacyclopentadecin-9(3aH)-one (5S,6S,8R,E)-6,9-bis((tert-butyldimethylsilyl)oxy)-5-((4-methoxybenzyl)oxy)-8-methylnon-2-en-1-ol (3aS,4E,7S,11S,12aS,13aS,14E,15aS)-11-((1S,3R)-1-((tert-butyldimethylsilyl)oxy)-4-hydroxy-3-methylbutyl)-2,2,7-trimethyl-6,7,8,11,12,12a,13a,15a-octahydro-[1,3]dioxolo[4,5-h]oxireno[2,3-d][1]oxacyclopentadecin-9(3aH)-one