百科

(5S,7R)-5-((S)-1-((4-methoxybenzyl)oxy)-2-((2R,3S)-3-vinyloxiran-2-yl)ethyl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

(5S,7R)-5-((S)-1-((4-methoxybenzyl)oxy)-2-((2R,3S)-3-vinyloxiran-2-yl)ethyl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

CAS号：1313511-89-5

英文名：(5S,7R)-5-((S)-1-((4-methoxybenzyl)oxy)-2-((2R,3S)-3-vinyloxiran-2-yl)ethyl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

分子式：C31H56O5Si2

分子量：564.944

合成路线

6-tetrahydropyranyloxy-4-hexen-1-ol

6-tetrahydropyranyloxy-4-hexen-1-ol

(5S,7R)-5-((S)-1-((4-methoxybenzyl)oxy)-2-((2R,3S)-3-vinyloxiran-2-yl)ethyl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

(5S,7R)-5-((S)-1-((4-methoxybenzyl)oxy)-2-((2R,3S)-3-vinyloxiran-2-yl)ethyl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

(2S,E)-6-((tetrahydro-2H-pyran-2-yl)oxy)hex-4-ene-1,2-diol

(2S,E)-6-((tetrahydro-2H-pyran-2-yl)oxy)hex-4-ene-1,2-diol

(5S,7R)-5-((S)-1-((4-methoxybenzyl)oxy)-2-((2R,3S)-3-vinyloxiran-2-yl)ethyl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

(5S,7R)-5-((S)-1-((4-methoxybenzyl)oxy)-2-((2R,3S)-3-vinyloxiran-2-yl)ethyl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

(2S,E)-N-methoxy-2-((4-methoxybenzyl)oxy)-N-methyl-6-((tetrahydro-2H-pyran-2-yl)oxy)hex-4-enamide

(2S,E)-N-methoxy-2-((4-methoxybenzyl)oxy)-N-methyl-6-((tetrahydro-2H-pyran-2-yl)oxy)hex-4-enamide

(5S,7R)-5-((S)-1-((4-methoxybenzyl)oxy)-2-((2R,3S)-3-vinyloxiran-2-yl)ethyl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

(5S,7R)-5-((S)-1-((4-methoxybenzyl)oxy)-2-((2R,3S)-3-vinyloxiran-2-yl)ethyl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

(5S,7R)-5-((1S,E)-1-((4-methoxybenzyl)oxy)-5-((tetrahydro-2H-pyran-2-yl)oxy)pent-3-en-1-yl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

(5S,7R)-5-((1S,E)-1-((4-methoxybenzyl)oxy)-5-((tetrahydro-2H-pyran-2-yl)oxy)pent-3-en-1-yl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

(5S,7R)-5-((S)-1-((4-methoxybenzyl)oxy)-2-((2R,3S)-3-vinyloxiran-2-yl)ethyl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

(5S,7R)-5-((S)-1-((4-methoxybenzyl)oxy)-2-((2R,3S)-3-vinyloxiran-2-yl)ethyl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

上游原料

(2S,E)-N-methoxy-2-((4-methoxybenzyl)oxy)-N-methyl-6-((tetrahydro-2H-pyran-2-yl)oxy)hex-4-enamide (2S,E)-6-((tetrahydro-2H-pyran-2-yl)oxy)hex-4-ene-1,2-diol (5S,7R)-5-((1S,E)-1-((4-methoxybenzyl)oxy)-5-((tetrahydro-2H-pyran-2-yl)oxy)pent-3-en-1-yl)-2,2,3,3,7,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane 6-tetrahydropyranyloxy-4-hexen-1-ol

下游产品

(3aS,4E,7S,11S,12aS,13aS,14E,15aS)-11-((1S,3R)-1-((tert-butyldimethylsilyl)oxy)-4-hydroxy-3-methylbutyl)-2,2,7-trimethyl-6,7,8,11,12,12a,13a,15a-octahydro-[1,3]dioxolo[4,5-h]oxireno[2,3-d][1]oxacyclopentadecin-9(3aH)-one