百科

(1S,3a'R,5S,5'S,6R,6a'R)-2',2'-dimethyl-5'-(2-methyl-1,3-dioxolan-4-yl)-7-(prop-1-enyl)dihydro-3a'H-3-oxaspiro[bicyclo[3.2.0]heptane-6,6'-furo[2,3-d][1,3]dioxole]

(1S,3a'R,5S,5'S,6R,6a'R)-2',2'-dimethyl-5'-(2-methyl-1,3-dioxolan-4-yl)-7-(prop-1-enyl)dihydro-3a'H-3-oxaspiro[bicyclo[3.2.0]heptane-6,6'-furo[2,3-d][1,3]dioxole]

CAS号：1314906-10-9

英文名：(1S,3a'R,5S,5'S,6R,6a'R)-2',2'-dimethyl-5'-(2-methyl-1,3-dioxolan-4-yl)-7-(prop-1-enyl)dihydro-3a'H-3-oxaspiro[bicyclo[3.2.0]heptane-6,6'-furo[2,3-d][1,3]dioxole]

分子式：C19H28O6

分子量：352.422

合成路线

1,2:5,6-di-O-isopropylidene-α-D-threo-D-glycero-3-hexofuranosulose

1,2:5,6-di-O-isopropylidene-α-D-threo-D-glycero-3-hexofuranosulose

(1S,3a'R,5S,5'S,6R,6a'R)-2',2'-dimethyl-5'-(2-methyl-1,3-dioxolan-4-yl)-7-(prop-1-enyl)dihydro-3a'H-3-oxaspiro[bicyclo[3.2.0]heptane-6,6'-furo[2,3-d][1,3]dioxole]

(1S,3a'R,5S,5'S,6R,6a'R)-2',2'-dimethyl-5'-(2-methyl-1,3-dioxolan-4-yl)-7-(prop-1-enyl)dihydro-3a'H-3-oxaspiro[bicyclo[3.2.0]heptane-6,6'-furo[2,3-d][1,3]dioxole]

(Z)-3-deoxy-3-C-[(hydroxymethyl)methylene]-1,2:5,6-di-O-isopropylidene-α-D-ribo-hexofuranose

(Z)-3-deoxy-3-C-[(hydroxymethyl)methylene]-1,2:5,6-di-O-isopropylidene-α-D-ribo-hexofuranose

(1S,3a'R,5S,5'S,6R,6a'R)-2',2'-dimethyl-5'-(2-methyl-1,3-dioxolan-4-yl)-7-(prop-1-enyl)dihydro-3a'H-3-oxaspiro[bicyclo[3.2.0]heptane-6,6'-furo[2,3-d][1,3]dioxole]

(1S,3a'R,5S,5'S,6R,6a'R)-2',2'-dimethyl-5'-(2-methyl-1,3-dioxolan-4-yl)-7-(prop-1-enyl)dihydro-3a'H-3-oxaspiro[bicyclo[3.2.0]heptane-6,6'-furo[2,3-d][1,3]dioxole]

上游原料

(Z)-3-deoxy-3-C-[(hydroxymethyl)methylene]-1,2:5,6-di-O-isopropylidene-α-D-ribo-hexofuranose 1,2:5,6-di-O-isopropylidene-α-D-threo-D-glycero-3-hexofuranosulose

下游产品

(R)-1-((1S,3a'R,5S,5'S,6R,6a'R)-2',2'-dimethyl-7-(prop-1-enyl)dihydro-3a'H-3-oxaspiro[bicyclo[3.2.0]heptane-6,6'-furo[2,3-d][1,3]dioxole]-5'-yl)ethane-1,2-diol