百科

(-)-(2S,3R,4R)-2-Bromomethyl-4-(t-butyldimethylsilyloxy)-tetrahydropyran-3-yl Benzoate

(-)-(2S,3R,4R)-2-Bromomethyl-4-(t-butyldimethylsilyloxy)-tetrahydropyran-3-yl Benzoate

CAS号：131926-01-7

英文名：(-)-(2S,3R,4R)-2-Bromomethyl-4-(t-butyldimethylsilyloxy)-tetrahydropyran-3-yl Benzoate

分子式：C19H29BrO4Si

分子量：429.421

合成路线

(-)-(1S,3R,6R,10R)-10-(t-Butyldimethylsiloxy)-3-phenyl-2,4,7-trioxabicyclo<4.4.0>decane

(-)-(1S,3R,6R,10R)-10-(t-Butyldimethylsiloxy)-3-phenyl-2,4,7-trioxabicyclo<4.4.0>decane

(-)-(2S,3R,4R)-2-Bromomethyl-4-(t-butyldimethylsilyloxy)-tetrahydropyran-3-yl Benzoate

(-)-(2S,3R,4R)-2-Bromomethyl-4-(t-butyldimethylsilyloxy)-tetrahydropyran-3-yl Benzoate

1,2,3-tri-O-acetyl-4-deoxy-α-L-threo-pent-4-enopyranose

1,2,3-tri-O-acetyl-4-deoxy-α-L-threo-pent-4-enopyranose

(-)-(2S,3R,4R)-2-Bromomethyl-4-(t-butyldimethylsilyloxy)-tetrahydropyran-3-yl Benzoate

(-)-(2S,3R,4R)-2-Bromomethyl-4-(t-butyldimethylsilyloxy)-tetrahydropyran-3-yl Benzoate

4-Deoxy-D-erythro-pentose

4-Deoxy-D-erythro-pentose

(-)-(2S,3R,4R)-2-Bromomethyl-4-(t-butyldimethylsilyloxy)-tetrahydropyran-3-yl Benzoate

(-)-(2S,3R,4R)-2-Bromomethyl-4-(t-butyldimethylsilyloxy)-tetrahydropyran-3-yl Benzoate

Acetic acid (2R,3S,4R)-2,4-diacetoxy-tetrahydro-pyran-3-yl ester

Acetic acid (2R,3S,4R)-2,4-diacetoxy-tetrahydro-pyran-3-yl ester

(-)-(2S,3R,4R)-2-Bromomethyl-4-(t-butyldimethylsilyloxy)-tetrahydropyran-3-yl Benzoate

(-)-(2S,3R,4R)-2-Bromomethyl-4-(t-butyldimethylsilyloxy)-tetrahydropyran-3-yl Benzoate

上游原料

(-)-(1S,3R,6R,10R)-10-(t-Butyldimethylsiloxy)-3-phenyl-2,4,7-trioxabicyclo<4.4.0>decane Acetic acid (2R,3S,4R)-2,4-diacetoxy-tetrahydro-pyran-3-yl ester 1,2,3-tri-O-acetyl-4-deoxy-α-L-threo-pent-4-enopyranose 4-Deoxy-D-erythro-pentose

下游产品

(+)-<(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-3-<(E)-3''-oxooct-1''-enyl>tetrahydropyran-2-yl>acetonitrile <(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-3-<3''(R)-(E)-hydroxyoct-1''-enyl>tetrahydropyran-2-yl>acetonitrile [(2R,3S,4R)-3-Allyl-4-(tert-butyl-dimethyl-silanyloxy)-tetrahydro-pyran-2-yl]-acetonitrile [(2R,3S,4R)-3-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-tetrahydro-pyran-2-yl]-acetonitrile