百科

<(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-3-<3''(R)-(E)-hydroxyoct-1''-enyl>tetrahydropyran-2-yl>acetonitrile

<(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-3-<3''(R)-(E)-hydroxyoct-1''-enyl>tetrahydropyran-2-yl>acetonitrile

CAS号：131926-04-0

英文名：<(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-3-<3''(R)-(E)-hydroxyoct-1''-enyl>tetrahydropyran-2-yl>acetonitrile

分子式：C21H39NO3Si

分子量：381.625

合成路线

(-)-(2S,3R,4R)-2-Bromomethyl-4-(t-butyldimethylsilyloxy)-tetrahydropyran-3-yl Benzoate

(-)-(2S,3R,4R)-2-Bromomethyl-4-(t-butyldimethylsilyloxy)-tetrahydropyran-3-yl Benzoate

<(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-3-<3''(R)-(E)-hydroxyoct-1''-enyl>tetrahydropyran-2-yl>acetonitrile

<(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-3-<3''(R)-(E)-hydroxyoct-1''-enyl>tetrahydropyran-2-yl>acetonitrile

(+)-<(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-3-<(E)-3''-hydroxyprop-1''-enyl>tetrahydropyran-2-yl>acetonitrile

(+)-<(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-3-<(E)-3''-hydroxyprop-1''-enyl>tetrahydropyran-2-yl>acetonitrile

<(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-3-<3''(R)-(E)-hydroxyoct-1''-enyl>tetrahydropyran-2-yl>acetonitrile

<(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-3-<3''(R)-(E)-hydroxyoct-1''-enyl>tetrahydropyran-2-yl>acetonitrile

(-)-(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-2-(cyanomethyl)-tetrahydropyran-3-yl Benzoate

(-)-(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-2-(cyanomethyl)-tetrahydropyran-3-yl Benzoate

<(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-3-<3''(R)-(E)-hydroxyoct-1''-enyl>tetrahydropyran-2-yl>acetonitrile

<(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-3-<3''(R)-(E)-hydroxyoct-1''-enyl>tetrahydropyran-2-yl>acetonitrile

上游原料

(-)-(2S,3R,4R)-2-Bromomethyl-4-(t-butyldimethylsilyloxy)-tetrahydropyran-3-yl Benzoate (-)-(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-2-(cyanomethyl)-tetrahydropyran-3-yl Benzoate (+)-<(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-3-<(E)-3''-hydroxyprop-1''-enyl>tetrahydropyran-2-yl>acetonitrile

下游产品

(Z)-7-[(2R,3S,4R)-4-Hydroxy-3-((E)-(S)-3-hydroxy-oct-1-enyl)-tetrahydro-pyran-2-yl]-hept-5-enoic acid methyl ester