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[(2R,3S,4R)-3-Allyl-4-(tert-butyl-dimethyl-silanyloxy)-tetrahydro-pyran-2-yl]-acetonitrile

[(2R,3S,4R)-3-Allyl-4-(tert-butyl-dimethyl-silanyloxy)-tetrahydro-pyran-2-yl]-acetonitrile

CAS号：131926-06-2

英文名：[(2R,3S,4R)-3-Allyl-4-(tert-butyl-dimethyl-silanyloxy)-tetrahydro-pyran-2-yl]-acetonitrile

分子式：C16H29NO2Si

分子量：295.492

合成路线

(-)-(2S,3R,4R)-2-Bromomethyl-4-(t-butyldimethylsilyloxy)-tetrahydropyran-3-yl Benzoate

(-)-(2S,3R,4R)-2-Bromomethyl-4-(t-butyldimethylsilyloxy)-tetrahydropyran-3-yl Benzoate

[(2R,3S,4R)-3-Allyl-4-(tert-butyl-dimethyl-silanyloxy)-tetrahydro-pyran-2-yl]-acetonitrile

[(2R,3S,4R)-3-Allyl-4-(tert-butyl-dimethyl-silanyloxy)-tetrahydro-pyran-2-yl]-acetonitrile

[(2R,3S,4R)-3-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-tetrahydro-pyran-2-yl]-acetonitrile

[(2R,3S,4R)-3-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-tetrahydro-pyran-2-yl]-acetonitrile

[(2R,3S,4R)-3-Allyl-4-(tert-butyl-dimethyl-silanyloxy)-tetrahydro-pyran-2-yl]-acetonitrile

[(2R,3S,4R)-3-Allyl-4-(tert-butyl-dimethyl-silanyloxy)-tetrahydro-pyran-2-yl]-acetonitrile

(-)-(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-2-(cyanomethyl)-tetrahydropyran-3-yl Benzoate

(-)-(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-2-(cyanomethyl)-tetrahydropyran-3-yl Benzoate

[(2R,3S,4R)-3-Allyl-4-(tert-butyl-dimethyl-silanyloxy)-tetrahydro-pyran-2-yl]-acetonitrile

[(2R,3S,4R)-3-Allyl-4-(tert-butyl-dimethyl-silanyloxy)-tetrahydro-pyran-2-yl]-acetonitrile

上游原料

[(2R,3S,4R)-3-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-tetrahydro-pyran-2-yl]-acetonitrile (-)-(2S,3R,4R)-2-Bromomethyl-4-(t-butyldimethylsilyloxy)-tetrahydropyran-3-yl Benzoate (-)-(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-2-(cyanomethyl)-tetrahydropyran-3-yl Benzoate

下游产品

(+)-<(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-2-<(E)-2''-formylvinyl>tetrahydropyran-2-yl>acetonitrile (+)-<(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-3-<(E)-3''-hydroxyprop-1''-enyl>tetrahydropyran-2-yl>acetonitrile