百科

(R)-4-methoxy-5-((3a'R,4'R,6'R,7a'R)-4'-methyltetrahydro-4'H-spiro[cyclohexane-1,2'-[1,3]dioxolo[4,5-c]pyran]-6'-yl)-3-(phenylsulfonyl)isobenzofuran-1(3H)-one

(R)-4-methoxy-5-((3a'R,4'R,6'R,7a'R)-4'-methyltetrahydro-4'H-spiro[cyclohexane-1,2'-[1,3]dioxolo[4,5-c]pyran]-6'-yl)-3-(phenylsulfonyl)isobenzofuran-1(3H)-one

CAS号：132041-05-5

英文名：(R)-4-methoxy-5-((3a'R,4'R,6'R,7a'R)-4'-methyltetrahydro-4'H-spiro[cyclohexane-1,2'-[1,3]dioxolo[4,5-c]pyran]-6'-yl)-3-(phenylsulfonyl)isobenzofuran-1(3H)-one

分子式：C27H30O8S

分子量：514.587

合成路线

4-((2S,3S,4S,5R,6R)-4,5-Bis-benzyloxy-3-bromo-2-hydroxy-6-methyl-tetrahydro-pyran-2-yl)-3-methoxy-benzoic acid

4-((2S,3S,4S,5R,6R)-4,5-Bis-benzyloxy-3-bromo-2-hydroxy-6-methyl-tetrahydro-pyran-2-yl)-3-methoxy-benzoic acid

(R)-4-methoxy-5-((3a'R,4'R,6'R,7a'R)-4'-methyltetrahydro-4'H-spiro[cyclohexane-1,2'-[1,3]dioxolo[4,5-c]pyran]-6'-yl)-3-(phenylsulfonyl)isobenzofuran-1(3H)-one

(R)-4-methoxy-5-((3a'R,4'R,6'R,7a'R)-4'-methyltetrahydro-4'H-spiro[cyclohexane-1,2'-[1,3]dioxolo[4,5-c]pyran]-6'-yl)-3-(phenylsulfonyl)isobenzofuran-1(3H)-one

4-((2R,4R,5R,6R)-4,5-Bis-methoxymethoxy-6-methyl-tetrahydro-pyran-2-yl)-N,N-diethyl-2-formyl-3-methoxy-benzamide

4-((2R,4R,5R,6R)-4,5-Bis-methoxymethoxy-6-methyl-tetrahydro-pyran-2-yl)-N,N-diethyl-2-formyl-3-methoxy-benzamide

(R)-4-methoxy-5-((3a'R,4'R,6'R,7a'R)-4'-methyltetrahydro-4'H-spiro[cyclohexane-1,2'-[1,3]dioxolo[4,5-c]pyran]-6'-yl)-3-(phenylsulfonyl)isobenzofuran-1(3H)-one

(R)-4-methoxy-5-((3a'R,4'R,6'R,7a'R)-4'-methyltetrahydro-4'H-spiro[cyclohexane-1,2'-[1,3]dioxolo[4,5-c]pyran]-6'-yl)-3-(phenylsulfonyl)isobenzofuran-1(3H)-one

上游原料

4-((2R,4R,5R,6R)-4,5-Bis-methoxymethoxy-6-methyl-tetrahydro-pyran-2-yl)-N,N-diethyl-2-formyl-3-methoxy-benzamide 4-((2S,3S,4S,5R,6R)-4,5-Bis-benzyloxy-3-bromo-2-hydroxy-6-methyl-tetrahydro-pyran-2-yl)-3-methoxy-benzoic acid

下游产品

[(1R,3S,4R)-8-((2R,4R,5S,6R)-4,5-Dihydroxy-6-methyl-tetrahydro-pyran-2-yl)-4-hydroxy-5,9,10-trimethoxy-1-methyl-3,4-dihydro-1H-benzo[g]isochromen-3-yl]-acetic acid ethyl ester