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(2R,3R,4R,5R,6S)-3-(benzyloxy)-5-((tert-butyldimethylsilyl)oxy)-2,4,6-trimethyloctan-1-ol

(2R,3R,4R,5R,6S)-3-(benzyloxy)-5-((tert-butyldimethylsilyl)oxy)-2,4,6-trimethyloctan-1-ol

CAS号：1322669-24-8

英文名：(2R,3R,4R,5R,6S)-3-(benzyloxy)-5-((tert-butyldimethylsilyl)oxy)-2,4,6-trimethyloctan-1-ol

分子式：C24H44O3Si

分子量：408.69

合成路线

(2R,3R,4R,5R,6R)-3-(benzyloxy)-5-[1-(tert-butyl)-1,1-dimethylsilyl]oxy-2,4-dimethyl-6-([(4-methylphenyl)sulfonyl]oxymethyl)octyl pivalate

(2R,3R,4R,5R,6R)-3-(benzyloxy)-5-[1-(tert-butyl)-1,1-dimethylsilyl]oxy-2,4-dimethyl-6-([(4-methylphenyl)sulfonyl]oxymethyl)octyl pivalate

(2R,3R,4R,5R,6S)-3-(benzyloxy)-5-((tert-butyldimethylsilyl)oxy)-2,4,6-trimethyloctan-1-ol

(2R,3R,4R,5R,6S)-3-(benzyloxy)-5-((tert-butyldimethylsilyl)oxy)-2,4,6-trimethyloctan-1-ol

(1S,4S,5S,6R,7S,8S)-7-(benzyloxy)-4-ethyl-6,8-dimethyl-2,9-dioxabicyclo[3.3.1]nonan-3-one

(1S,4S,5S,6R,7S,8S)-7-(benzyloxy)-4-ethyl-6,8-dimethyl-2,9-dioxabicyclo[3.3.1]nonan-3-one

(2R,3R,4R,5R,6S)-3-(benzyloxy)-5-((tert-butyldimethylsilyl)oxy)-2,4,6-trimethyloctan-1-ol

(2R,3R,4R,5R,6S)-3-(benzyloxy)-5-((tert-butyldimethylsilyl)oxy)-2,4,6-trimethyloctan-1-ol

(1R,2R,3r,4S,5S)-3-(benzyloxy)-2,4-dimethyl-8-oxa-bicyclo[3.2.1]oct-6-ene

(1R,2R,3r,4S,5S)-3-(benzyloxy)-2,4-dimethyl-8-oxa-bicyclo[3.2.1]oct-6-ene

(2R,3R,4R,5R,6S)-3-(benzyloxy)-5-((tert-butyldimethylsilyl)oxy)-2,4,6-trimethyloctan-1-ol

(2R,3R,4R,5R,6S)-3-(benzyloxy)-5-((tert-butyldimethylsilyl)oxy)-2,4,6-trimethyloctan-1-ol

上游原料

(1S,4S,5S,6R,7S,8S)-7-(benzyloxy)-4-ethyl-6,8-dimethyl-2,9-dioxabicyclo[3.3.1]nonan-3-one (2R,3R,4R,5R,6R)-3-(benzyloxy)-5-[1-(tert-butyl)-1,1-dimethylsilyl]oxy-2,4-dimethyl-6-([(4-methylphenyl)sulfonyl]oxymethyl)octyl pivalate (1R,2R,3r,4S,5S)-3-(benzyloxy)-2,4-dimethyl-8-oxa-bicyclo[3.2.1]oct-6-ene

下游产品

(2R,3R,4R,5R,6S)-5-(tert-butyl(dimethyl)silyloxy)-3-hydroxy-2,4,6-trimethyloctanal (E)-(4R,5R,6R,7R,8S)-5-hydroxy-2,4,6,8-tetramethyl-7-(tert-butyldimethylsilanyloxy)dec-2-enoic acid ethyl ester