百科

benzyl 2-((2R,6S)-6-((2S,4R,5S)-2-(benzyloxy)-4-((tert-butyldimethylsilyl)oxy)-5-methylhept-6-en-1-yl)tetrahydro-2H-pyran-2-yl)-2-methylpropanoate

benzyl 2-((2R,6S)-6-((2S,4R,5S)-2-(benzyloxy)-4-((tert-butyldimethylsilyl)oxy)-5-methylhept-6-en-1-yl)tetrahydro-2H-pyran-2-yl)-2-methylpropanoate

CAS号：1325653-37-9

英文名：benzyl 2-((2R,6S)-6-((2S,4R,5S)-2-(benzyloxy)-4-((tert-butyldimethylsilyl)oxy)-5-methylhept-6-en-1-yl)tetrahydro-2H-pyran-2-yl)-2-methylpropanoate

分子式：C37H56O5Si

分子量：608.923

合成路线

(2R,3S)-3-(dimethyl(phenyl)silyl)-2-hydroxypent-4-en-1-yl 2,4,6-trimethylbenzenesulfonate

(2R,3S)-3-(dimethyl(phenyl)silyl)-2-hydroxypent-4-en-1-yl 2,4,6-trimethylbenzenesulfonate

benzyl 2-((2R,6S)-6-((2S,4R,5S)-2-(benzyloxy)-4-((tert-butyldimethylsilyl)oxy)-5-methylhept-6-en-1-yl)tetrahydro-2H-pyran-2-yl)-2-methylpropanoate

benzyl 2-((2R,6S)-6-((2S,4R,5S)-2-(benzyloxy)-4-((tert-butyldimethylsilyl)oxy)-5-methylhept-6-en-1-yl)tetrahydro-2H-pyran-2-yl)-2-methylpropanoate

(2R,3S)-3-(dimethyl(phenyl)silyl)-2-((trimethylsilyl)oxy)pent-4-en-1-yl 2,4,6-trimethylbenzenesulfonate

(2R,3S)-3-(dimethyl(phenyl)silyl)-2-((trimethylsilyl)oxy)pent-4-en-1-yl 2,4,6-trimethylbenzenesulfonate

benzyl 2-((2R,6S)-6-((2S,4R,5S)-2-(benzyloxy)-4-((tert-butyldimethylsilyl)oxy)-5-methylhept-6-en-1-yl)tetrahydro-2H-pyran-2-yl)-2-methylpropanoate

benzyl 2-((2R,6S)-6-((2S,4R,5S)-2-(benzyloxy)-4-((tert-butyldimethylsilyl)oxy)-5-methylhept-6-en-1-yl)tetrahydro-2H-pyran-2-yl)-2-methylpropanoate

benzyl 2-((2R,6S)-6-((R)-2-(benzyloxy)pent-4-en-1-yl)tetrahydro-2H-pyran-2-yl)-2-methylpropanoate

benzyl 2-((2R,6S)-6-((R)-2-(benzyloxy)pent-4-en-1-yl)tetrahydro-2H-pyran-2-yl)-2-methylpropanoate

benzyl 2-((2R,6S)-6-((2S,4R,5S)-2-(benzyloxy)-4-((tert-butyldimethylsilyl)oxy)-5-methylhept-6-en-1-yl)tetrahydro-2H-pyran-2-yl)-2-methylpropanoate

benzyl 2-((2R,6S)-6-((2S,4R,5S)-2-(benzyloxy)-4-((tert-butyldimethylsilyl)oxy)-5-methylhept-6-en-1-yl)tetrahydro-2H-pyran-2-yl)-2-methylpropanoate

((2S,6R)-6-(1-hydroxy-2-methylpropan-2-yl)tetrahydro-2H-pyran-2-yl)methyl 2,4,6-trimethylbenzenesulfonate

((2S,6R)-6-(1-hydroxy-2-methylpropan-2-yl)tetrahydro-2H-pyran-2-yl)methyl 2,4,6-trimethylbenzenesulfonate

benzyl 2-((2R,6S)-6-((2S,4R,5S)-2-(benzyloxy)-4-((tert-butyldimethylsilyl)oxy)-5-methylhept-6-en-1-yl)tetrahydro-2H-pyran-2-yl)-2-methylpropanoate

benzyl 2-((2R,6S)-6-((2S,4R,5S)-2-(benzyloxy)-4-((tert-butyldimethylsilyl)oxy)-5-methylhept-6-en-1-yl)tetrahydro-2H-pyran-2-yl)-2-methylpropanoate

上游原料

((2S,6R)-6-(1-hydroxy-2-methylpropan-2-yl)tetrahydro-2H-pyran-2-yl)methyl 2,4,6-trimethylbenzenesulfonate benzyl 2-((2R,6S)-6-((R)-2-(benzyloxy)pent-4-en-1-yl)tetrahydro-2H-pyran-2-yl)-2-methylpropanoate (2R,3S)-3-(dimethyl(phenyl)silyl)-2-((trimethylsilyl)oxy)pent-4-en-1-yl 2,4,6-trimethylbenzenesulfonate (2R,3S)-3-(dimethyl(phenyl)silyl)-2-hydroxypent-4-en-1-yl 2,4,6-trimethylbenzenesulfonate

下游产品