百科

tert-Butyl-[(1S,2S)-1-((R)-2-iodo-1-methyl-ethyl)-3-(4-methoxy-benzyloxy)-2-methyl-propoxy]-dimethyl-silane

tert-Butyl-[(1S,2S)-1-((R)-2-iodo-1-methyl-ethyl)-3-(4-methoxy-benzyloxy)-2-methyl-propoxy]-dimethyl-silane

CAS号：132969-64-3

英文名：tert-Butyl-[(1S,2S)-1-((R)-2-iodo-1-methyl-ethyl)-3-(4-methoxy-benzyloxy)-2-methyl-propoxy]-dimethyl-silane

分子式：C21H37IO3Si

分子量：492.507

合成路线

methyl (2R,3S,4S)-2,4-dimethyl-3-hydroxy-5-(4-methoxybenzyloxy)pentanoate

methyl (2R,3S,4S)-2,4-dimethyl-3-hydroxy-5-(4-methoxybenzyloxy)pentanoate

tert-Butyl-[(1S,2S)-1-((R)-2-iodo-1-methyl-ethyl)-3-(4-methoxy-benzyloxy)-2-methyl-propoxy]-dimethyl-silane

tert-Butyl-[(1S,2S)-1-((R)-2-iodo-1-methyl-ethyl)-3-(4-methoxy-benzyloxy)-2-methyl-propoxy]-dimethyl-silane

上游原料

methyl (2R,3S,4S)-2,4-dimethyl-3-hydroxy-5-(4-methoxybenzyloxy)pentanoate

下游产品

(2S,3R,4S,6S)-3,7-bis(tert-butyldimethylsilyloxy)-2,4,6-trimethylheptan-1-ol 1-(((2S,3R,4S,6S)-3,7-bis(tert-butyldimethylsilyloxy)-2,4,6-trimethylheptyloxy)methyl)-4-methoxybenzene (5R,6S,8S)-5-((S)-4,4-dibromobut-3-en-2-yl)-2,2,3,3,6,8,11,11,12,12-decamethyl-4,10-dioxa-3,11-disilatridecane (3Z,5E,11Z)-(7R,8S,13S,14R,15S,17S,20R,21R,22S)-8,14,20-Tris-(tert-butyl-dimethyl-silanyloxy)-7,13,15,17,21-pentamethyl-22-((Z)-(S)-1-methyl-penta-2,4-dienyl)-oxacyclodocosa-3,5,11-triene-2,10-dione (2Z,4E,10Z,23Z)-(6R,7S,12S,13R,14S,16S,19R,20R,21S,22S)-7,13,19-Tris-(tert-butyl-dimethyl-silanyloxy)-21-hydroxy-6,12,14,16,20,22-hexamethyl-9-oxo-hexacosa-2,4,10,23,25-pentaenoic acid (2S,3R,4S,6S)-4-(tert-butyldimethylsilyloxy)-7-((tert-butyldimethylsilyloxy)methyl)-3,5-dimethyloct-1-yne (2S,4S,5R,6S)-7-(4-methoxybenzyloxy)-5-(tert-butyldimethylsilyloxy)-2,4,6-trimethylheptan-1-ol (3Z,5E,11Z)-(7R,8S,10S,13S,14R,15S,17S,20R,21R,22S)-8,14,20-Tris-(tert-butyl-dimethyl-silanyloxy)-10-hydroxy-7,13,15,17,21-pentamethyl-22-((Z)-(S)-1-methyl-penta-2,4-dienyl)-oxacyclodocosa-3,5,11-trien-2-one (3S,4R,5S,7S)-4-(tert-butyldimethylsilyloxy)-3,5-dimethyl-7-((triethylsilyloxy)methyl)-oct-1-yne (2S,3R,4S,6S,9R,10S,11S,12S,Z)-3-(tert-butyldimethylsilyloxy)-2,4,6,10,12-pentamethylhexadeca-13,15-diene-1,9,11-triol (4R,5S,7S,10S,11R,12S,14S,E)-5,11-bis(tert-butyldimethylsilyloxy)-4,10,12,14-tetramethyl-15-(triethylsilyloxy)-1-(trityloxy)pentadec-2-en-8-yn-7-ol (Z)-(2R,3R,4S,6S,9R,10R,11S,12S)-3,9-Bis-(tert-butyl-dimethyl-silanyloxy)-11-hydroxy-2,4,6,10,12-pentamethyl-hexadeca-13,15-dienal (Z)-(5S,6S,7R,8R,11S,13S,14R,15S)-8,14,16-Tris-(tert-butyl-dimethyl-silanyloxy)-5,7,11,13,15-pentamethyl-hexadeca-1,3-dien-6-ol (3Z,9E)-(5S,6S,7R,11R,13S,14R,15S)-14-(tert-Butyl-dimethyl-silanyloxy)-6,16-bis-(4-methoxy-benzyloxy)-5,7,11,13,15-pentamethyl-hexadeca-1,3,9-trien-8-one (4R,5S,10S,11R,12S,14S,E)-5,11-bis(tert-butyldimethylsilyloxy)-4,10,12,14-tetramethyl-15-(triethylsilyloxy)-1-(trityloxy)pentadec-2-en-8-yn-7-one