tert-butyl(((7R,8R,9S,13S,14S,17S)-3-methoxy-7,13-dimethyl-7,8,9,11,12,13,14,15,16,17-decahydro-6H-cyclopenta[a]phenanthren-17-yl)oxy)dimethylsilane

tert-butyl(((7R,8R,9S,13S,14S,17S)-3-methoxy-7,13-dimethyl-7,8,9,11,12,13,14,15,16,17-decahydro-6H-cyclopenta[a]phenanthren-17-yl)oxy)dimethylsilane

CAS号：133152-42-8

英文名：tert-butyl(((7R,8R,9S,13S,14S,17S)-3-methoxy-7,13-dimethyl-7,8,9,11,12,13,14,15,16,17-decahydro-6H-cyclopenta[a]phenanthren-17-yl)oxy)dimethylsilane

分子式：C26H42O2Si

分子量：414.696

合成路线

((7R,8R,9S,13S,14S,17S)-17-((tert-butyldimethylsilyl)oxy)-3-methoxy-13-methyl-7,8,9,11,12,13,14,15,16,17-decahydro-6H-cyclopenta[a]phenanthren-7-yl)methyl 4-methylbenzenesulfonate

((7R,8R,9S,13S,14S,17S)-17-((tert-butyldimethylsilyl)oxy)-3-methoxy-13-methyl-7,8,9,11,12,13,14,15,16,17-decahydro-6H-cyclopenta[a]phenanthren-7-yl)methyl 4-methylbenzenesulfonate

tert-butyl(((7R,8R,9S,13S,14S,17S)-3-methoxy-7,13-dimethyl-7,8,9,11,12,13,14,15,16,17-decahydro-6H-cyclopenta[a]phenanthren-17-yl)oxy)dimethylsilane

tert-butyl(((7R,8R,9S,13S,14S,17S)-3-methoxy-7,13-dimethyl-7,8,9,11,12,13,14,15,16,17-decahydro-6H-cyclopenta[a]phenanthren-17-yl)oxy)dimethylsilane

(7α,17β)-17-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3-methoxyestra-1,3,5(10),8-tetraene-7-methanol

(7α,17β)-17-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3-methoxyestra-1,3,5(10),8-tetraene-7-methanol

tert-butyl(((7R,8R,9S,13S,14S,17S)-3-methoxy-7,13-dimethyl-7,8,9,11,12,13,14,15,16,17-decahydro-6H-cyclopenta[a]phenanthren-17-yl)oxy)dimethylsilane

tert-butyl(((7R,8R,9S,13S,14S,17S)-3-methoxy-7,13-dimethyl-7,8,9,11,12,13,14,15,16,17-decahydro-6H-cyclopenta[a]phenanthren-17-yl)oxy)dimethylsilane

((7R,8R,9S,13S,14S,17S)-17-((tert-butyldimethylsilyl)oxy)-3-methoxy-13-methyl-7,8,9,11,12,13,14,15,16,17-decahydro-6H-cyclopenta[a]phenanthren-7-yl)methanol

((7R,8R,9S,13S,14S,17S)-17-((tert-butyldimethylsilyl)oxy)-3-methoxy-13-methyl-7,8,9,11,12,13,14,15,16,17-decahydro-6H-cyclopenta[a]phenanthren-7-yl)methanol

tert-butyl(((7R,8R,9S,13S,14S,17S)-3-methoxy-7,13-dimethyl-7,8,9,11,12,13,14,15,16,17-decahydro-6H-cyclopenta[a]phenanthren-17-yl)oxy)dimethylsilane

tert-butyl(((7R,8R,9S,13S,14S,17S)-3-methoxy-7,13-dimethyl-7,8,9,11,12,13,14,15,16,17-decahydro-6H-cyclopenta[a]phenanthren-17-yl)oxy)dimethylsilane

上游原料

((7R,8R,9S,13S,14S,17S)-17-((tert-butyldimethylsilyl)oxy)-3-methoxy-13-methyl-7,8,9,11,12,13,14,15,16,17-decahydro-6H-cyclopenta[a]phenanthren-7-yl)methyl 4-methylbenzenesulfonate ((7R,8R,9S,13S,14S,17S)-17-((tert-butyldimethylsilyl)oxy)-3-methoxy-13-methyl-7,8,9,11,12,13,14,15,16,17-decahydro-6H-cyclopenta[a]phenanthren-7-yl)methanol (7α,17β)-17-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3-methoxyestra-1,3,5(10),8-tetraene-7-methanol

下游产品

(7alpha,17beta)-3-甲氧基-7-甲基-雌甾-1,3,5(10)-三烯-17-醇