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(2S,5R,10S,11R)-5-(benzyloxy)-2-hydroxy-12-((4-methoxybenzyl)oxy)-11-methyl-10-((triethylsilyl)oxy)-1-((S)-2,2,4-trimethyl-1,3-dioxolan-4-yl)dodec-7-yn-6-one

CAS号：1335029-14-5

英文名：(2S,5R,10S,11R)-5-(benzyloxy)-2-hydroxy-12-((4-methoxybenzyl)oxy)-11-methyl-10-((triethylsilyl)oxy)-1-((S)-2,2,4-trimethyl-1,3-dioxolan-4-yl)dodec-7-yn-6-one

分子式：C40H60O8Si

分子量：696.985

合成路线

1335029-09-8

(3R,6S)-3-(benzyloxy)-6-(((S)-2,2,4-trimethyl-1,3-dioxolan-4-yl)methyl)tetrahydro-2H-pyran-2-one

1335028-95-9

triethyl(((2R,3S)-1-((4-methoxybenzyl)oxy)-2-methylhex-5-yn-3-yl)oxy)silane

1335029-14-5

(2S,5R,10S,11R)-5-(benzyloxy)-2-hydroxy-12-((4-methoxybenzyl)oxy)-11-methyl-10-((triethylsilyl)oxy)-1-((S)-2,2,4-trimethyl-1,3-dioxolan-4-yl)dodec-7-yn-6-one

1335028-91-5

(2R,5S)-2-(benzyloxy)-7-methyloct-7-ene-1,5-diol

1335029-14-5

(2S,5R,10S,11R)-5-(benzyloxy)-2-hydroxy-12-((4-methoxybenzyl)oxy)-11-methyl-10-((triethylsilyl)oxy)-1-((S)-2,2,4-trimethyl-1,3-dioxolan-4-yl)dodec-7-yn-6-one

1335028-92-6

(3R,6S)-3-(benzyloxy)-6-(2-methylallyl)tetrahydro-2H-pyran-2-one

1335029-14-5

(2S,5R,10S,11R)-5-(benzyloxy)-2-hydroxy-12-((4-methoxybenzyl)oxy)-11-methyl-10-((triethylsilyl)oxy)-1-((S)-2,2,4-trimethyl-1,3-dioxolan-4-yl)dodec-7-yn-6-one

1335028-93-7

1335029-14-5

(2S,5R,10S,11R)-5-(benzyloxy)-2-hydroxy-12-((4-methoxybenzyl)oxy)-11-methyl-10-((triethylsilyl)oxy)-1-((S)-2,2,4-trimethyl-1,3-dioxolan-4-yl)dodec-7-yn-6-one

1335029-08-7

(S)-3-((2S,5R,6R)-5-(benzyloxy)-6-((tert-butyldimethylsilyl)oxy)tetrahydro-2H-pyran-2-yl)-2-methylpropane-1,2-diol

1335029-14-5

(2S,5R,10S,11R)-5-(benzyloxy)-2-hydroxy-12-((4-methoxybenzyl)oxy)-11-methyl-10-((triethylsilyl)oxy)-1-((S)-2,2,4-trimethyl-1,3-dioxolan-4-yl)dodec-7-yn-6-one

上游原料

triethyl(((2R,3S)-1-((4-methoxybenzyl)oxy)-2-methylhex-5-yn-3-yl)oxy)silane (2R,5S)-2-(benzyloxy)-7-methyloct-7-ene-1,5-diol (3R,6S)-3-(benzyloxy)-6-(2-methylallyl)tetrahydro-2H-pyran-2-one (3R,6S)-3-(benzyloxy)-6-(((S)-2,2,4-trimethyl-1,3-dioxolan-4-yl)methyl)tetrahydro-2H-pyran-2-one

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