百科

(+)-(RS,2S,3R,4R,5S)-N-[1-(tert-butyldimethylsilyloxy)-2,3-dibenzyloxy-5-(methoxymethoxy)hept-6-yn-4-yl]-2-methylpropane-2-sulfinamide

(+)-(RS,2S,3R,4R,5S)-N-[1-(tert-butyldimethylsilyloxy)-2,3-dibenzyloxy-5-(methoxymethoxy)hept-6-yn-4-yl]-2-methylpropane-2-sulfinamide

CAS号：1349097-57-9

英文名：(+)-(RS,2S,3R,4R,5S)-N-[1-(tert-butyldimethylsilyloxy)-2,3-dibenzyloxy-5-(methoxymethoxy)hept-6-yn-4-yl]-2-methylpropane-2-sulfinamide

分子式：C33H51NO6SSi

分子量：617.912

合成路线

2,3-Di-O-benzyl-4-O-(tert-butyldimethylsilyl)-D-erythrose

2,3-Di-O-benzyl-4-O-(tert-butyldimethylsilyl)-D-erythrose

(+)-(RS,2S,3R,4R,5S)-N-[1-(tert-butyldimethylsilyloxy)-2,3-dibenzyloxy-5-(methoxymethoxy)hept-6-yn-4-yl]-2-methylpropane-2-sulfinamide

(+)-(RS,2S,3R,4R,5S)-N-[1-(tert-butyldimethylsilyloxy)-2,3-dibenzyloxy-5-(methoxymethoxy)hept-6-yn-4-yl]-2-methylpropane-2-sulfinamide

(2R,3R)-2,3-bis(benzyloxy)-4-hydroxybutanoic acid 1,4-lactone

(2R,3R)-2,3-bis(benzyloxy)-4-hydroxybutanoic acid 1,4-lactone

(+)-(RS,2S,3R,4R,5S)-N-[1-(tert-butyldimethylsilyloxy)-2,3-dibenzyloxy-5-(methoxymethoxy)hept-6-yn-4-yl]-2-methylpropane-2-sulfinamide

(+)-(RS,2S,3R,4R,5S)-N-[1-(tert-butyldimethylsilyloxy)-2,3-dibenzyloxy-5-(methoxymethoxy)hept-6-yn-4-yl]-2-methylpropane-2-sulfinamide

(-)-(RS,2S,3R,4R,5S)-N-[1-(tert-butyldimethylsilyloxy)-2,3-dibenzyloxy-5-methoxymethoxy-7-(trimethylsilyl)hept-6-yn-4-yl]-2-methylpropane-2-sulfinamide

(-)-(RS,2S,3R,4R,5S)-N-[1-(tert-butyldimethylsilyloxy)-2,3-dibenzyloxy-5-methoxymethoxy-7-(trimethylsilyl)hept-6-yn-4-yl]-2-methylpropane-2-sulfinamide

(+)-(RS,2S,3R,4R,5S)-N-[1-(tert-butyldimethylsilyloxy)-2,3-dibenzyloxy-5-(methoxymethoxy)hept-6-yn-4-yl]-2-methylpropane-2-sulfinamide

(+)-(RS,2S,3R,4R,5S)-N-[1-(tert-butyldimethylsilyloxy)-2,3-dibenzyloxy-5-(methoxymethoxy)hept-6-yn-4-yl]-2-methylpropane-2-sulfinamide

1349097-36-4

(+)-(RS,2S,3R,4R,5S)-N-[1-(tert-butyldimethylsilyloxy)-2,3-dibenzyloxy-5-(methoxymethoxy)hept-6-yn-4-yl]-2-methylpropane-2-sulfinamide

(+)-(RS,2S,3R,4R,5S)-N-[1-(tert-butyldimethylsilyloxy)-2,3-dibenzyloxy-5-(methoxymethoxy)hept-6-yn-4-yl]-2-methylpropane-2-sulfinamide

(2R,3R)-2,3-Bis(benzyloxy)-4-hydroxy-N-methoxy-N-methylbutanamide

(2R,3R)-2,3-Bis(benzyloxy)-4-hydroxy-N-methoxy-N-methylbutanamide

(+)-(RS,2S,3R,4R,5S)-N-[1-(tert-butyldimethylsilyloxy)-2,3-dibenzyloxy-5-(methoxymethoxy)hept-6-yn-4-yl]-2-methylpropane-2-sulfinamide

(+)-(RS,2S,3R,4R,5S)-N-[1-(tert-butyldimethylsilyloxy)-2,3-dibenzyloxy-5-(methoxymethoxy)hept-6-yn-4-yl]-2-methylpropane-2-sulfinamide

(2R,3R)-2,3-Bis(benzyloxy)-4-<(tert-butyldimethylsilyl)oxy>-N-methoxy-N-methylbutanamide

(2R,3R)-2,3-Bis(benzyloxy)-4-<(tert-butyldimethylsilyl)oxy>-N-methoxy-N-methylbutanamide

(+)-(RS,2S,3R,4R,5S)-N-[1-(tert-butyldimethylsilyloxy)-2,3-dibenzyloxy-5-(methoxymethoxy)hept-6-yn-4-yl]-2-methylpropane-2-sulfinamide

(+)-(RS,2S,3R,4R,5S)-N-[1-(tert-butyldimethylsilyloxy)-2,3-dibenzyloxy-5-(methoxymethoxy)hept-6-yn-4-yl]-2-methylpropane-2-sulfinamide

上游原料

2,3-Di-O-benzyl-4-O-(tert-butyldimethylsilyl)-D-erythrose (-)-(RS,2S,3R,4R,5S)-N-[1-(tert-butyldimethylsilyloxy)-2,3-dibenzyloxy-5-methoxymethoxy-7-(trimethylsilyl)hept-6-yn-4-yl]-2-methylpropane-2-sulfinamide (2R,3R)-2,3-Bis(benzyloxy)-4-hydroxy-N-methoxy-N-methylbutanamide (2R,3R)-2,3-Bis(benzyloxy)-4-<(tert-butyldimethylsilyl)oxy>-N-methoxy-N-methylbutanamide (2R,3R)-2,3-bis(benzyloxy)-4-hydroxybutanoic acid 1,4-lactone

下游产品

(1S,2R,8S,8aR)-1,2,8-trihydroxy-octahydroindolizine (-)-(1S,2R,8S,8aR)-1,2-di(benzyloxy)-8-methoxymethoxy-1,2,3,5,8,8a-hexahydroindolizine (+)-(2R,3S,4R)-1-allyl-3,4-di(benzyloxy)-2-[(S)-1-(methoxymethoxy)allyl]pyrrolidine