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(-)-(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-2-(cyanomethyl)-tetrahydropyran-3-yl Benzoate

(-)-(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-2-(cyanomethyl)-tetrahydropyran-3-yl Benzoate

CAS号：135123-07-8

英文名：(-)-(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-2-(cyanomethyl)-tetrahydropyran-3-yl Benzoate

分子式：C20H29NO4Si

分子量：375.534

合成路线

Acetic acid (2R,3S,4R)-2,4-diacetoxy-tetrahydro-pyran-3-yl ester

Acetic acid (2R,3S,4R)-2,4-diacetoxy-tetrahydro-pyran-3-yl ester

(-)-(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-2-(cyanomethyl)-tetrahydropyran-3-yl Benzoate

(-)-(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-2-(cyanomethyl)-tetrahydropyran-3-yl Benzoate

1,2,3-tri-O-acetyl-4-deoxy-α-L-threo-pent-4-enopyranose

1,2,3-tri-O-acetyl-4-deoxy-α-L-threo-pent-4-enopyranose

(-)-(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-2-(cyanomethyl)-tetrahydropyran-3-yl Benzoate

(-)-(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-2-(cyanomethyl)-tetrahydropyran-3-yl Benzoate

4-Deoxy-D-erythro-pentose

4-Deoxy-D-erythro-pentose

(-)-(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-2-(cyanomethyl)-tetrahydropyran-3-yl Benzoate

(-)-(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-2-(cyanomethyl)-tetrahydropyran-3-yl Benzoate

(-)-(1S,3R,6R,10R)-10-(t-Butyldimethylsiloxy)-3-phenyl-2,4,7-trioxabicyclo<4.4.0>decane

(-)-(1S,3R,6R,10R)-10-(t-Butyldimethylsiloxy)-3-phenyl-2,4,7-trioxabicyclo<4.4.0>decane

(-)-(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-2-(cyanomethyl)-tetrahydropyran-3-yl Benzoate

(-)-(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-2-(cyanomethyl)-tetrahydropyran-3-yl Benzoate

上游原料

Acetic acid (2R,3S,4R)-2,4-diacetoxy-tetrahydro-pyran-3-yl ester (-)-(1S,3R,6R,10R)-10-(t-Butyldimethylsiloxy)-3-phenyl-2,4,7-trioxabicyclo<4.4.0>decane 1,2,3-tri-O-acetyl-4-deoxy-α-L-threo-pent-4-enopyranose 4-Deoxy-D-erythro-pentose

下游产品

(+)-<(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-3-<(E)-3''-oxooct-1''-enyl>tetrahydropyran-2-yl>acetonitrile <(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-3-<3''(R)-(E)-hydroxyoct-1''-enyl>tetrahydropyran-2-yl>acetonitrile [(2R,3S,4R)-3-Allyl-4-(tert-butyl-dimethyl-silanyloxy)-tetrahydro-pyran-2-yl]-acetonitrile