百科

tert-butyldimethyl((2R,4S,8R,Z)-2,4,8-trimethyl-6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)dec-6-enyloxy)silane

tert-butyldimethyl((2R,4S,8R,Z)-2,4,8-trimethyl-6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)dec-6-enyloxy)silane

CAS号：1351458-73-5

英文名：tert-butyldimethyl((2R,4S,8R,Z)-2,4,8-trimethyl-6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)dec-6-enyloxy)silane

分子式：C25H51BO3Si

分子量：438.567

合成路线

(R,Z)-2-(1-bromo-3-methylpent-1-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

(R,Z)-2-(1-bromo-3-methylpent-1-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

(2S,4R)-5-(tert-butyldimethylsilyloxy)-2,4-dimethyl-1-pentanyl iodide

(2S,4R)-5-(tert-butyldimethylsilyloxy)-2,4-dimethyl-1-pentanyl iodide

tert-butyldimethyl((2R,4S,8R,Z)-2,4,8-trimethyl-6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)dec-6-enyloxy)silane

tert-butyldimethyl((2R,4S,8R,Z)-2,4,8-trimethyl-6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)dec-6-enyloxy)silane

(R)-1,1-dibromo-3-methyl-1-pentene

(R)-1,1-dibromo-3-methyl-1-pentene

tert-butyldimethyl((2R,4S,8R,Z)-2,4,8-trimethyl-6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)dec-6-enyloxy)silane

tert-butyldimethyl((2R,4S,8R,Z)-2,4,8-trimethyl-6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)dec-6-enyloxy)silane

上游原料

(2S,4R)-5-(tert-butyldimethylsilyloxy)-2,4-dimethyl-1-pentanyl iodide (R)-1,1-dibromo-3-methyl-1-pentene (R,Z)-2-(1-bromo-3-methylpent-1-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

下游产品

(E)-(2R,4S,8R)-2,4,6,8-tetramethyl-6-decen-1-ol (3R,4E,7S,9R)-10-(tert-butyl(dimethyl)silyloxy)-3,5,7,9-tetramethyldec-4-ene