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(-)-(1S,3R,6R,10R)-10-(t-Butyldimethylsiloxy)-3-phenyl-2,4,7-trioxabicyclo<4.4.0>decane

(-)-(1S,3R,6R,10R)-10-(t-Butyldimethylsiloxy)-3-phenyl-2,4,7-trioxabicyclo<4.4.0>decane

CAS号：135214-84-5

英文名：(-)-(1S,3R,6R,10R)-10-(t-Butyldimethylsiloxy)-3-phenyl-2,4,7-trioxabicyclo<4.4.0>decane

分子式：C19H30O4Si

分子量：350.525

合成路线

Acetic acid (2R,3S,4R)-2,4-diacetoxy-tetrahydro-pyran-3-yl ester

Acetic acid (2R,3S,4R)-2,4-diacetoxy-tetrahydro-pyran-3-yl ester

(-)-(1S,3R,6R,10R)-10-(t-Butyldimethylsiloxy)-3-phenyl-2,4,7-trioxabicyclo<4.4.0>decane

(-)-(1S,3R,6R,10R)-10-(t-Butyldimethylsiloxy)-3-phenyl-2,4,7-trioxabicyclo<4.4.0>decane

上游原料

Acetic acid (2R,3S,4R)-2,4-diacetoxy-tetrahydro-pyran-3-yl ester

下游产品

Toluene-4-sulfonic acid (2R,3R,4R)-4-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-tetrahydro-pyran-2-ylmethyl ester (+)-<(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-3-<(E)-3''-oxooct-1''-enyl>tetrahydropyran-2-yl>acetonitrile (2R,3R,4R)-4-(tert-Butyl-dimethyl-silanyloxy)-2-methyl-tetrahydro-pyran-3-ol [(2R,3S,4R)-3-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-tetrahydro-pyran-2-yl]-acetonitrile (-)-(2S,3R,4R)-2-Bromomethyl-4-(t-butyldimethylsilyloxy)-tetrahydropyran-3-yl Benzoate Acrylic acid (2R,3R,4R)-4-(tert-butyl-dimethyl-silanyloxy)-2-methyl-tetrahydro-pyran-3-yl ester (-)-(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-2-(cyanomethyl)-tetrahydropyran-3-yl Benzoate (+)-<(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-2-<(E)-2''-formylvinyl>tetrahydropyran-2-yl>acetonitrile (+)-<(2R,3R,4R)-4-(t-Butyldimethylsiloxy)-3-<(E)-3''-hydroxyprop-1''-enyl>tetrahydropyran-2-yl>acetonitrile