百科

4-((1S,2S,4aR,6S,8aR)-6-((tert-butyldimethylsilyl)oxy)-2-(((2-methoxyethoxy)methoxy)methyl)-5,5,8a-trimethyldecahydronaphthalen-1-yl)butan-1-ol

4-((1S,2S,4aR,6S,8aR)-6-((tert-butyldimethylsilyl)oxy)-2-(((2-methoxyethoxy)methoxy)methyl)-5,5,8a-trimethyldecahydronaphthalen-1-yl)butan-1-ol

CAS号：1352318-86-5

英文名：4-((1S,2S,4aR,6S,8aR)-6-((tert-butyldimethylsilyl)oxy)-2-(((2-methoxyethoxy)methoxy)methyl)-5,5,8a-trimethyldecahydronaphthalen-1-yl)butan-1-ol

分子式：C28H56O5Si

分子量：500.827

合成路线

(1S,4aR,6S,8aS)-6-(tert-Butyl-dimethyl-silanyloxy)-5,5,8a-trimethyl-2-methylene-decahydro-naphthalene-1-carbaldehyde

(1S,4aR,6S,8aS)-6-(tert-Butyl-dimethyl-silanyloxy)-5,5,8a-trimethyl-2-methylene-decahydro-naphthalene-1-carbaldehyde

4-((1S,2S,4aR,6S,8aR)-6-((tert-butyldimethylsilyl)oxy)-2-(((2-methoxyethoxy)methoxy)methyl)-5,5,8a-trimethyldecahydronaphthalen-1-yl)butan-1-ol

4-((1S,2S,4aR,6S,8aR)-6-((tert-butyldimethylsilyl)oxy)-2-(((2-methoxyethoxy)methoxy)methyl)-5,5,8a-trimethyldecahydronaphthalen-1-yl)butan-1-ol

((2S,4aS,5S)-decahydro-1,1,4a-trimethyl-6-methylene-5-((E)-2-(phenylsulfonyl)vinyl)naphthalen-2-yloxy)(tert-butyl)dimethylsilane

((2S,4aS,5S)-decahydro-1,1,4a-trimethyl-6-methylene-5-((E)-2-(phenylsulfonyl)vinyl)naphthalen-2-yloxy)(tert-butyl)dimethylsilane

4-((1S,2S,4aR,6S,8aR)-6-((tert-butyldimethylsilyl)oxy)-2-(((2-methoxyethoxy)methoxy)methyl)-5,5,8a-trimethyldecahydronaphthalen-1-yl)butan-1-ol

4-((1S,2S,4aR,6S,8aR)-6-((tert-butyldimethylsilyl)oxy)-2-(((2-methoxyethoxy)methoxy)methyl)-5,5,8a-trimethyldecahydronaphthalen-1-yl)butan-1-ol

((2S,4aS,5S)-decahydro-1,1,4a-trimethyl-6-methylene-5-((E)-2-(phenylsulfonyl)ethyl)naphthalen-2-yloxy)(tert-butyl)dimethylsilane

((2S,4aS,5S)-decahydro-1,1,4a-trimethyl-6-methylene-5-((E)-2-(phenylsulfonyl)ethyl)naphthalen-2-yloxy)(tert-butyl)dimethylsilane

4-((1S,2S,4aR,6S,8aR)-6-((tert-butyldimethylsilyl)oxy)-2-(((2-methoxyethoxy)methoxy)methyl)-5,5,8a-trimethyldecahydronaphthalen-1-yl)butan-1-ol

4-((1S,2S,4aR,6S,8aR)-6-((tert-butyldimethylsilyl)oxy)-2-(((2-methoxyethoxy)methoxy)methyl)-5,5,8a-trimethyldecahydronaphthalen-1-yl)butan-1-ol

((1S,2S,4aR,6S,8aR)-6-((tert-butyldimethylsilyl)oxy)-5,5,8a-trimethyl-1-(2-(phenylsulfonyl)ethyl)decahydronaphthalen-2-yl)methanol

((1S,2S,4aR,6S,8aR)-6-((tert-butyldimethylsilyl)oxy)-5,5,8a-trimethyl-1-(2-(phenylsulfonyl)ethyl)decahydronaphthalen-2-yl)methanol

4-((1S,2S,4aR,6S,8aR)-6-((tert-butyldimethylsilyl)oxy)-2-(((2-methoxyethoxy)methoxy)methyl)-5,5,8a-trimethyldecahydronaphthalen-1-yl)butan-1-ol

4-((1S,2S,4aR,6S,8aR)-6-((tert-butyldimethylsilyl)oxy)-2-(((2-methoxyethoxy)methoxy)methyl)-5,5,8a-trimethyldecahydronaphthalen-1-yl)butan-1-ol

上游原料

((2S,4aS,5S)-decahydro-1,1,4a-trimethyl-6-methylene-5-((E)-2-(phenylsulfonyl)vinyl)naphthalen-2-yloxy)(tert-butyl)dimethylsilane ((1S,2S,4aR,6S,8aR)-6-((tert-butyldimethylsilyl)oxy)-5,5,8a-trimethyl-1-(2-(phenylsulfonyl)ethyl)decahydronaphthalen-2-yl)methanol ((2S,4aS,5S)-decahydro-1,1,4a-trimethyl-6-methylene-5-((E)-2-(phenylsulfonyl)ethyl)naphthalen-2-yloxy)(tert-butyl)dimethylsilane (1S,4aR,6S,8aS)-6-(tert-Butyl-dimethyl-silanyloxy)-5,5,8a-trimethyl-2-methylene-decahydro-naphthalene-1-carbaldehyde

下游产品

6-((1S,2S,4aR,6S,8aR)-6-((tert-butyldimethylsilyl)oxy)-2-(((2-methoxyethoxy)methoxy)methyl)-5,5,8a-trimethyldecahydronaphthalen-1-yl)hex-1-en-3-one (R)-1-(2-((1S,2S,4aR,6S,8aR)-6-((tert-butyldimethylsilyl)oxy)-2-(((2-methoxyethoxy)methoxy)methyl)-5,5,8a-trimethyldecahydronaphthalen-1-yl)ethyl)-4a,7,7-trimethyl-4,4a,5,6,7,8-hexahydronaphthalen-2(3H)-one