百科

(7R,9R)-9-[(4S)-4-benzyloxy-3,3-dimethyl-6-hydroxy-2-(2-trimethylsilylethoxy)methoxyhexyl]-7-tert-butyldimethylsilyloxymethyl-1,4,8-trioxaspiro[4.5]decane

(7R,9R)-9-[(4S)-4-benzyloxy-3,3-dimethyl-6-hydroxy-2-(2-trimethylsilylethoxy)methoxyhexyl]-7-tert-butyldimethylsilyloxymethyl-1,4,8-trioxaspiro[4.5]decane

CAS号：1352746-37-2

英文名：(7R,9R)-9-[(4S)-4-benzyloxy-3,3-dimethyl-6-hydroxy-2-(2-trimethylsilylethoxy)methoxyhexyl]-7-tert-butyldimethylsilyloxymethyl-1,4,8-trioxaspiro[4.5]decane

分子式：C35H64O8Si2

分子量：669.049

合成路线

(7R,9R)-9-[(4S)-4-benzyloxy-3,3-dimethyl-2-(2-trimethylsilylethoxy)methoxyhex-5-enyl]-7-tert-butyldimethylsilyloxymethyl-1,4,8-trioxaspiro[4.5]decane

(7R,9R)-9-[(4S)-4-benzyloxy-3,3-dimethyl-2-(2-trimethylsilylethoxy)methoxyhex-5-enyl]-7-tert-butyldimethylsilyloxymethyl-1,4,8-trioxaspiro[4.5]decane

(7R,9R)-9-[(4S)-4-benzyloxy-3,3-dimethyl-6-hydroxy-2-(2-trimethylsilylethoxy)methoxyhexyl]-7-tert-butyldimethylsilyloxymethyl-1,4,8-trioxaspiro[4.5]decane

(7R,9R)-9-[(4S)-4-benzyloxy-3,3-dimethyl-6-hydroxy-2-(2-trimethylsilylethoxy)methoxyhexyl]-7-tert-butyldimethylsilyloxymethyl-1,4,8-trioxaspiro[4.5]decane

(7R,9R)-9-[(4S)-4-benzyloxy-3,3-dimethyl-2-oxohex-5-enyl]-7-tert-butyldimethysilyloxymethyl-1,4,8-trioxaspiro[4.5]-decane

(7R,9R)-9-[(4S)-4-benzyloxy-3,3-dimethyl-2-oxohex-5-enyl]-7-tert-butyldimethysilyloxymethyl-1,4,8-trioxaspiro[4.5]-decane

(7R,9R)-9-[(4S)-4-benzyloxy-3,3-dimethyl-6-hydroxy-2-(2-trimethylsilylethoxy)methoxyhexyl]-7-tert-butyldimethylsilyloxymethyl-1,4,8-trioxaspiro[4.5]decane

(7R,9R)-9-[(4S)-4-benzyloxy-3,3-dimethyl-6-hydroxy-2-(2-trimethylsilylethoxy)methoxyhexyl]-7-tert-butyldimethylsilyloxymethyl-1,4,8-trioxaspiro[4.5]decane

(7R,9R)-9-[(4S)-4-benzyloxy-3,3-dimethyl-2-oxohex-5-enyl]-7-hydroxymethyl-1,4,8-trioxaspiro[4.5]decane

(7R,9R)-9-[(4S)-4-benzyloxy-3,3-dimethyl-2-oxohex-5-enyl]-7-hydroxymethyl-1,4,8-trioxaspiro[4.5]decane

(7R,9R)-9-[(4S)-4-benzyloxy-3,3-dimethyl-6-hydroxy-2-(2-trimethylsilylethoxy)methoxyhexyl]-7-tert-butyldimethylsilyloxymethyl-1,4,8-trioxaspiro[4.5]decane

(7R,9R)-9-[(4S)-4-benzyloxy-3,3-dimethyl-6-hydroxy-2-(2-trimethylsilylethoxy)methoxyhexyl]-7-tert-butyldimethylsilyloxymethyl-1,4,8-trioxaspiro[4.5]decane

上游原料

(7R,9R)-9-[(4S)-4-benzyloxy-3,3-dimethyl-2-oxohex-5-enyl]-7-tert-butyldimethysilyloxymethyl-1,4,8-trioxaspiro[4.5]-decane (7R,9R)-9-[(4S)-4-benzyloxy-3,3-dimethyl-2-oxohex-5-enyl]-7-hydroxymethyl-1,4,8-trioxaspiro[4.5]decane (7R,9R)-9-[(4S)-4-benzyloxy-3,3-dimethyl-2-(2-trimethylsilylethoxy)methoxyhex-5-enyl]-7-tert-butyldimethylsilyloxymethyl-1,4,8-trioxaspiro[4.5]decane

下游产品

(5S,7S)-7-benzyloxy-10-{(7R,9R)-9-tert-butyldimethylsilyloxymethyl-1,4,8-trioxaspiro[4.5]dec-7-yl}-1-(tert-butyldiphenylsilyloxy)-5-hydroxy-8,8-dimethyl-9-(2-trimethylsilylethoxy)methoxydecan-3-one (7R,9R)-9-[(4S)-4-benzyloxy-3,3-dimethyl-5-formyl-2-(trimethylsilylethoxy)methoxypentyl]-7-tert-butyldimethylsilyloxymethyl-1,4,8-trioxaspiro[4.5]decane (3S,5R,7S)-7-benzyloxy-10-{(7R,9R)-9-(tert-butyldimethylsilyloxymethyl)-1,4,8-trioxaspiro[4.5]dec-7-yl}-1-tert-butyldiphenylsilyloxy-8,8-dimethyl-9-(2-trimethylsilylethoxy)methoxydecane-3,5-diol