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((1S,4S,5S,6R)-5-(3-((tert-butyldiphenylsilyl)oxy)propyl)-6-hydroxyspiro[bicyclo[2.2.2]octane-2,2'-[1,3]dioxane]-1,4-diyl)dimethanol

((1S,4S,5S,6R)-5-(3-((tert-butyldiphenylsilyl)oxy)propyl)-6-hydroxyspiro[bicyclo[2.2.2]octane-2,2'-[1,3]dioxane]-1,4-diyl)dimethanol

CAS号：1352816-02-4

英文名：((1S,4S,5S,6R)-5-(3-((tert-butyldiphenylsilyl)oxy)propyl)-6-hydroxyspiro[bicyclo[2.2.2]octane-2,2'-[1,3]dioxane]-1,4-diyl)dimethanol

分子式：C32H46O6Si

分子量：554.79

合成路线

diethyl (1S,4S)-5-(((trifluoromethyl)sulfonyl)oxy)spiro[bicyclo[2.2.2]octane-2,2'-[1,3]dioxan]-5-ene-1,4-dicarboxylate

diethyl (1S,4S)-5-(((trifluoromethyl)sulfonyl)oxy)spiro[bicyclo[2.2.2]octane-2,2'-[1,3]dioxan]-5-ene-1,4-dicarboxylate

3-(tert-butyldiphenylsilyloxy)prop-1-ene

3-(tert-butyldiphenylsilyloxy)prop-1-ene

((1S,4S,5S,6R)-5-(3-((tert-butyldiphenylsilyl)oxy)propyl)-6-hydroxyspiro[bicyclo[2.2.2]octane-2,2'-[1,3]dioxane]-1,4-diyl)dimethanol

((1S,4S,5S,6R)-5-(3-((tert-butyldiphenylsilyl)oxy)propyl)-6-hydroxyspiro[bicyclo[2.2.2]octane-2,2'-[1,3]dioxane]-1,4-diyl)dimethanol

diethyl (1S,4S)-5-(3-((tert-butyldiphenylsilyl)oxy)propyl)spiro[bicyclo[2.2.2]octane-2,2'-[1,3]dioxan]-5-ene-1,4-dicarboxylate

diethyl (1S,4S)-5-(3-((tert-butyldiphenylsilyl)oxy)propyl)spiro[bicyclo[2.2.2]octane-2,2'-[1,3]dioxan]-5-ene-1,4-dicarboxylate

((1S,4S,5S,6R)-5-(3-((tert-butyldiphenylsilyl)oxy)propyl)-6-hydroxyspiro[bicyclo[2.2.2]octane-2,2'-[1,3]dioxane]-1,4-diyl)dimethanol

((1S,4S,5S,6R)-5-(3-((tert-butyldiphenylsilyl)oxy)propyl)-6-hydroxyspiro[bicyclo[2.2.2]octane-2,2'-[1,3]dioxane]-1,4-diyl)dimethanol

diethyl (1S,4S)-5-oxospiro[bicyclo[2.2.2]octane-2,2'-[1,3]dioxane]-1,4-dicarboxylate

diethyl (1S,4S)-5-oxospiro[bicyclo[2.2.2]octane-2,2'-[1,3]dioxane]-1,4-dicarboxylate

((1S,4S,5S,6R)-5-(3-((tert-butyldiphenylsilyl)oxy)propyl)-6-hydroxyspiro[bicyclo[2.2.2]octane-2,2'-[1,3]dioxane]-1,4-diyl)dimethanol

((1S,4S,5S,6R)-5-(3-((tert-butyldiphenylsilyl)oxy)propyl)-6-hydroxyspiro[bicyclo[2.2.2]octane-2,2'-[1,3]dioxane]-1,4-diyl)dimethanol

上游原料

3-(tert-butyldiphenylsilyloxy)prop-1-ene diethyl (1S,4S)-5-oxospiro[bicyclo[2.2.2]octane-2,2'-[1,3]dioxane]-1,4-dicarboxylate diethyl (1S,4S)-5-(3-((tert-butyldiphenylsilyl)oxy)propyl)spiro[bicyclo[2.2.2]octane-2,2'-[1,3]dioxan]-5-ene-1,4-dicarboxylate diethyl (1S,4S)-5-(((trifluoromethyl)sulfonyl)oxy)spiro[bicyclo[2.2.2]octane-2,2'-[1,3]dioxan]-5-ene-1,4-dicarboxylate

下游产品

(4aS,7S,8S,8aR)-8-(3-((tert-butyldiphenylsilyl)oxy)propyl)-7-(hydroxymethyl)-2,2-dimethyltetrahydro-4H,5H-4a,7-ethanobenzo[d][1,3]dioxin-5-one