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(1R,5R,6R)-4-(((tert-butyldimethylsilyl)oxy)methyl)-3-(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)-5-hydroxy-6-methyl-7-oxabicyclo[4.1.0]hept-3-en-2-one

(1R,5R,6R)-4-(((tert-butyldimethylsilyl)oxy)methyl)-3-(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)-5-hydroxy-6-methyl-7-oxabicyclo[4.1.0]hept-3-en-2-one

CAS号：1352916-42-7

英文名：(1R,5R,6R)-4-(((tert-butyldimethylsilyl)oxy)methyl)-3-(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)-5-hydroxy-6-methyl-7-oxabicyclo[4.1.0]hept-3-en-2-one

分子式

C28H38O8Si

熔点

50 - 52 °C

密度

分子量

530.682

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(1R,5R,6R)-4-(((tert-butyldimethylsilyl)oxy)methyl)-3-(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)-5-hydroxy-6-methyl-7-oxabicyclo[4.1.0]hept-3-en-2-one

英文名称

(1R,5R,6R)-4-(((tert-butyldimethylsilyl)oxy)methyl)-3-(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)-5-hydroxy-6-methyl-7-oxabicyclo[4.1.0]hept-3-en-2-one

中文别名

英文别名

CAS号

1352916-42-7

分子式

C28H38O8Si

分子量

530.682

精确质量

530.234

PSA

95.98

LOGP

4.7162

物化性质

熔点

50 - 52 °C

下游产品

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(1R,2R,5S,6S)-5-((tert-butoxycarbonyl)oxy)-3-(((tert-butyldimethylsilyl)oxy)methyl)-4-(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)-1-methyl-7-oxabicyclo[4.1.0]hept-3-en-2-yl acetate

(1R,2R,5S,6S)-5-((tert-butoxycarbonyl)oxy)-3-(((tert-butyldimethylsilyl)oxy)methyl)-4-(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)-1-methyl-7-oxabicyclo[4.1.0]hept-3-en-2-yl acetate

(1aS,2S,10R,10aR)-2,7-bis((tert-butyldiphenylsilyl)oxy)-3,8-dimethoxy-10a-methyl-9-oxo-1a,9,10,10a-tetrahydro-2H-benzo[6,7]fluoreno[2,3-b]oxiren-10-yl acetate

(1aS,2S,10R,10aR)-2,7-bis((tert-butyldiphenylsilyl)oxy)-3,8-dimethoxy-10a-methyl-9-oxo-1a,9,10,10a-tetrahydro-2H-benzo[6,7]fluoreno[2,3-b]oxiren-10-yl acetate

(1aS,2S,10R,10aR)-2,7-dihydroxy-3,8-dimethoxy-10a-methyl-9-oxo-1a,9,10,10a-tetrahydro-2H-benzo[6,7]fluoreno[2,3-b]oxiren-10-yl acetate

(1aS,2S,10R,10aR)-2,7-dihydroxy-3,8-dimethoxy-10a-methyl-9-oxo-1a,9,10,10a-tetrahydro-2H-benzo[6,7]fluoreno[2,3-b]oxiren-10-yl acetate

(1aS,2S,10R,10aR)-10-acetoxy-3,8-dimethoxy-7-(methoxymethoxy)-10a-methyl-9-oxo-1a,9,10,10a-tetrahydro-2H-benzo[6,7]fluoreno[2,3-b]oxiren-2-yl 4-azidobutanoate

(1aS,2S,10R,10aR)-10-acetoxy-3,8-dimethoxy-7-(methoxymethoxy)-10a-methyl-9-oxo-1a,9,10,10a-tetrahydro-2H-benzo[6,7]fluoreno[2,3-b]oxiren-2-yl 4-azidobutanoate

(1aS,2S,10R,10aR)-3,8-dimethoxy-10a-methyl-9-oxo-7-(2,2,2-trifluoroacetoxy)-1a,9,10,10a-tetrahydro-2H-benzo[6,7]fluoreno[2,3-b]oxirene-2,10-diyl diacetate

(1aS,2S,10R,10aR)-3,8-dimethoxy-10a-methyl-9-oxo-7-(2,2,2-trifluoroacetoxy)-1a,9,10,10a-tetrahydro-2H-benzo[6,7]fluoreno[2,3-b]oxirene-2,10-diyl diacetate

(1aS,2S,10R,10aR)-10-acetoxy-7-hydroxy-3,8-dimethoxy-10a-methyl-9-oxo-1a,9,10,10a-tetrahydro-2H-benzo[6,7]fluoreno[2,3-b]oxiren-2-yl 4-azidobutanoate

(1aS,2S,10R,10aR)-10-acetoxy-7-hydroxy-3,8-dimethoxy-10a-methyl-9-oxo-1a,9,10,10a-tetrahydro-2H-benzo[6,7]fluoreno[2,3-b]oxiren-2-yl 4-azidobutanoate

下游产品

(1R,2R,5S,6S)-5-((tert-butoxycarbonyl)oxy)-3-(((tert-butyldimethylsilyl)oxy)methyl)-4-(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)-1-methyl-7-oxabicyclo[4.1.0]hept-3-en-2-yl acetate (1aS,2S,10R,10aR)-2,7-bis((tert-butyldiphenylsilyl)oxy)-3,8-dimethoxy-10a-methyl-9-oxo-1a,9,10,10a-tetrahydro-2H-benzo[6,7]fluoreno[2,3-b]oxiren-10-yl acetate (1aS,2S,10R,10aR)-2,7-dihydroxy-3,8-dimethoxy-10a-methyl-9-oxo-1a,9,10,10a-tetrahydro-2H-benzo[6,7]fluoreno[2,3-b]oxiren-10-yl acetate (1aS,2S,10R,10aR)-10-acetoxy-3,8-dimethoxy-7-(methoxymethoxy)-10a-methyl-9-oxo-1a,9,10,10a-tetrahydro-2H-benzo[6,7]fluoreno[2,3-b]oxiren-2-yl 4-azidobutanoate (1aS,2S,10R,10aR)-3,8-dimethoxy-10a-methyl-9-oxo-7-(2,2,2-trifluoroacetoxy)-1a,9,10,10a-tetrahydro-2H-benzo[6,7]fluoreno[2,3-b]oxirene-2,10-diyl diacetate (1aS,2S,10R,10aR)-10-acetoxy-7-hydroxy-3,8-dimethoxy-10a-methyl-9-oxo-1a,9,10,10a-tetrahydro-2H-benzo[6,7]fluoreno[2,3-b]oxiren-2-yl 4-azidobutanoate (1R,2R,5S,6S)-3-(((tert-butyldimethylsilyl)oxy)methyl)-4-(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)-5-hydroxy-1-methyl-7-oxabicyclo[4.1.0]hept-3-en-2-yl acetate (1S,2S,5R,6R)-5-acetoxy-4-(((tert-butyldimethylsilyl)oxy)methyl)-3-(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)-6-methyl-7-oxabicyclo[4.1.0]hept-3-en-2-yl 4-azidobutanoate (7R,7aR,8aS,9S)-1-hydroxy-11-methoxy-7a-methyl-6-oxo-7,7a,8a,9-tetrahydro-6H-benzo[h]oxireno[2',3':4,5]benzo[1,2-c]chromene-7,9-diyl diacetate (1R,2R,5S,6S)-2,5-diacetoxy-4-(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)-1-methyl-7-oxabicyclo[4.1.0]hept-3-ene-3-carboxylic acid (1R,2R,5S,6S)-2-acetoxy-5-((4-azidobutanoyl)oxy)-4-(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)-1-methyl-7-oxabicyclo[4.1.0]hept-3-ene-3-carboxylic acid (1aS,2S,10R,10aR)-7-hydroxy-3,8-dimethoxy-10a-methyl-9-oxo-1a,9,10,10a-tetrahydro-2H-benzo[6,7]fluoreno[2,3-b]oxirene-2,10-diyl diacetate (1R,2R,5S,6S)-4-(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)-3-formyl-1-methyl-7-oxabicyclo[4.1.0]hept-3-ene-2,5-diyl diacetate (1S,2S,5R,6R)-5-acetoxy-3-(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)-4-formyl-6-methyl-7-oxabicyclo[4.1.0]hept-3-en-2-yl 4-azidobutanoate (1R,2R,5S,6S)-4-(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)-3-(hydroxymethyl)-1-methyl-7-oxabicyclo[4.1.0]hept-3-ene-2,5-diyl diacetate (1R,2R,5S,6S)-2-acetoxy-5-((tert-butoxycarbonyl)oxy)-4-(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)-1-methyl-7-oxabicyclo[4.1.0]hept-3-ene-3-carboxylic acid (7R,7aR,8aS,9S)-7-acetoxy-1-hydroxy-11-methoxy-7a-methyl-6-oxo-7,7a,8a,9-tetrahydro-6H-benzo[h]oxireno[2',3':4,5]benzo[1,2-c]chromen-9-yl 4-azidobutanoate (1aS,2S,10R,10aR)-3,8-dimethoxy-7-(methoxymethoxy)-10a-methyl-9-oxo-1a,9,10,10a-tetrahydro-2H-benzo[6,7]fluoreno[2,3-b]oxirene-2,10-diyl diacetate (1R,2R,5S,6S)-3-(((tert-butyldimethylsilyl)oxy)methyl)-4-(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)-1-methyl-7-oxabicyclo[4.1.0]hept-3-ene-2,5-diyl diacetate (1S,2S,5R,6R)-5-acetoxy-3-(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)-4-(hydroxymethyl)-6-methyl-7-oxabicyclo[4.1.0]hept-3-en-2-yl 4-azidobutanoate (1R,2R,5S,6S)-5-((tert-butoxycarbonyl)oxy)-4-(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)-3-formyl-1-methyl-7-oxabicyclo[4.1.0]hept-3-en-2-yl acetate (1aS,2S,10R,10aR)-2,7-bis((tert-butyldiphenylsilyl)oxy)-9-diazo-10a-methyl-3,8-dioxo-1a,3,8,9,10,10a-hexahydro-2H-benzo[6,7]fluoreno[2,3-b]oxiren-10-yl acetate (1R,2R,5S,6S)-5-((tert-butoxycarbonyl)oxy)-4-(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)-3-(hydroxymethyl)-1-methyl-7-oxabicyclo[4.1.0]hept-3-en-2-yl acetate (1aS,2S,10R,10aR)-2,7-bis((tert-butyldiphenylsilyl)oxy)-3,8-dimethoxy-10a-methyl-9-(2-(methylsulfonyl)hydrazineylidene)-1a,9,10,10a-tetrahydro-2H-benzo[6,7]fluoreno[2,3-b]oxiren-10-yl acetate