百科

(5R,6S,8S)-6-((tert-butyldimethylsilyl)oxy)-5-(1,3-dithian-2-yl)-2,2,3,3,8,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

(5R,6S,8S)-6-((tert-butyldimethylsilyl)oxy)-5-(1,3-dithian-2-yl)-2,2,3,3,8,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

CAS号：1352927-88-8

英文名：(5R,6S,8S)-6-((tert-butyldimethylsilyl)oxy)-5-(1,3-dithian-2-yl)-2,2,3,3,8,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

分子式：C27H60O3S2Si3

分子量：581.15

合成路线

(R)-1-((4S,5R)-5-(1,3-dithian-2-yl)-2,2-dimethyl-1,3-dioxolan-4-yl)propan-2-ol

(R)-1-((4S,5R)-5-(1,3-dithian-2-yl)-2,2-dimethyl-1,3-dioxolan-4-yl)propan-2-ol

(5R,6S,8S)-6-((tert-butyldimethylsilyl)oxy)-5-(1,3-dithian-2-yl)-2,2,3,3,8,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

(5R,6S,8S)-6-((tert-butyldimethylsilyl)oxy)-5-(1,3-dithian-2-yl)-2,2,3,3,8,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

(S)-1-((4S,5R)-5-(1,3-dithian-2-yl)-2,2-dimethyl-1,3-dioxolan-4-yl)propan-2-ol

(S)-1-((4S,5R)-5-(1,3-dithian-2-yl)-2,2-dimethyl-1,3-dioxolan-4-yl)propan-2-ol

(5R,6S,8S)-6-((tert-butyldimethylsilyl)oxy)-5-(1,3-dithian-2-yl)-2,2,3,3,8,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

(5R,6S,8S)-6-((tert-butyldimethylsilyl)oxy)-5-(1,3-dithian-2-yl)-2,2,3,3,8,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

4,6-Didesoxy-D-xylo-hexose-trimethylendithioacetal

4,6-Didesoxy-D-xylo-hexose-trimethylendithioacetal

(5R,6S,8S)-6-((tert-butyldimethylsilyl)oxy)-5-(1,3-dithian-2-yl)-2,2,3,3,8,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

(5R,6S,8S)-6-((tert-butyldimethylsilyl)oxy)-5-(1,3-dithian-2-yl)-2,2,3,3,8,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

(S)-1-((4S,5R)-5-(1,3-dithian-2-yl)-2,2-dimethyl-1,3-dioxolan-4-yl)propan-2-yl benzoate

(S)-1-((4S,5R)-5-(1,3-dithian-2-yl)-2,2-dimethyl-1,3-dioxolan-4-yl)propan-2-yl benzoate

(5R,6S,8S)-6-((tert-butyldimethylsilyl)oxy)-5-(1,3-dithian-2-yl)-2,2,3,3,8,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

(5R,6S,8S)-6-((tert-butyldimethylsilyl)oxy)-5-(1,3-dithian-2-yl)-2,2,3,3,8,10,10,11,11-nonamethyl-4,9-dioxa-3,10-disiladodecane

上游原料

(S)-1-((4S,5R)-5-(1,3-dithian-2-yl)-2,2-dimethyl-1,3-dioxolan-4-yl)propan-2-ol 4,6-Didesoxy-D-xylo-hexose-trimethylendithioacetal (R)-1-((4S,5R)-5-(1,3-dithian-2-yl)-2,2-dimethyl-1,3-dioxolan-4-yl)propan-2-ol (S)-1-((4S,5R)-5-(1,3-dithian-2-yl)-2,2-dimethyl-1,3-dioxolan-4-yl)propan-2-yl benzoate

下游产品

(4S,5S,7S,E)-4,5,7-tris((tert-butyldimethylsilyl)oxy)-2-methyloct-2-en-1-ol (4S,5S,7S,2E)-4,5,7-tris[(tert-butyldimethylsilyl)oxy]-2-methyloct-2-enal