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(4R,6R)-2,2-di-tert-butyl-4-((R,E)-4-iodopent-3-en-2-yl)-6-methyl-1,3,2-dioxasilinane

(4R,6R)-2,2-di-tert-butyl-4-((R,E)-4-iodopent-3-en-2-yl)-6-methyl-1,3,2-dioxasilinane

CAS号：1352927-97-9

英文名：(4R,6R)-2,2-di-tert-butyl-4-((R,E)-4-iodopent-3-en-2-yl)-6-methyl-1,3,2-dioxasilinane

分子式：C17H33IO2Si

分子量：424.433

合成路线

(3R,4R,6R)-6-((tert-butyldimethylsilyl)oxy)-3-methylhept-1-en-4-ol

(3R,4R,6R)-6-((tert-butyldimethylsilyl)oxy)-3-methylhept-1-en-4-ol

(4R,6R)-2,2-di-tert-butyl-4-((R,E)-4-iodopent-3-en-2-yl)-6-methyl-1,3,2-dioxasilinane

(4R,6R)-2,2-di-tert-butyl-4-((R,E)-4-iodopent-3-en-2-yl)-6-methyl-1,3,2-dioxasilinane

(2S,3R,5R)-3,5-bis((tert-butyldimethylsilyl)oxy)-2-methylhexanal

(2S,3R,5R)-3,5-bis((tert-butyldimethylsilyl)oxy)-2-methylhexanal

(4R,6R)-2,2-di-tert-butyl-4-((R,E)-4-iodopent-3-en-2-yl)-6-methyl-1,3,2-dioxasilinane

(4R,6R)-2,2-di-tert-butyl-4-((R,E)-4-iodopent-3-en-2-yl)-6-methyl-1,3,2-dioxasilinane

(5R,7R)-5-((R,E)-4-iodopent-3-en-2-yl)-2,2,3,3,7,9,9,10,10-nonamethyl-4,8-dioxa-3,9-disilaundecane

(5R,7R)-5-((R,E)-4-iodopent-3-en-2-yl)-2,2,3,3,7,9,9,10,10-nonamethyl-4,8-dioxa-3,9-disilaundecane

(4R,6R)-2,2-di-tert-butyl-4-((R,E)-4-iodopent-3-en-2-yl)-6-methyl-1,3,2-dioxasilinane

(4R,6R)-2,2-di-tert-butyl-4-((R,E)-4-iodopent-3-en-2-yl)-6-methyl-1,3,2-dioxasilinane

(5R,7R)-5-((R)-but-3-en-2-yl)-2,2,3,3,7,9,9,10,10-nonamethyl-4,8-dioxa-3,9-disilaundecane

(5R,7R)-5-((R)-but-3-en-2-yl)-2,2,3,3,7,9,9,10,10-nonamethyl-4,8-dioxa-3,9-disilaundecane

(4R,6R)-2,2-di-tert-butyl-4-((R,E)-4-iodopent-3-en-2-yl)-6-methyl-1,3,2-dioxasilinane

(4R,6R)-2,2-di-tert-butyl-4-((R,E)-4-iodopent-3-en-2-yl)-6-methyl-1,3,2-dioxasilinane

(5R,7R)-5-((R)-4,4-dibromobut-3-en-2-yl)-2,2,3,3,7,9,9,10,10-nonamethyl-4,8-dioxa-3,9-disilaundecane

(5R,7R)-5-((R)-4,4-dibromobut-3-en-2-yl)-2,2,3,3,7,9,9,10,10-nonamethyl-4,8-dioxa-3,9-disilaundecane

(4R,6R)-2,2-di-tert-butyl-4-((R,E)-4-iodopent-3-en-2-yl)-6-methyl-1,3,2-dioxasilinane

(4R,6R)-2,2-di-tert-butyl-4-((R,E)-4-iodopent-3-en-2-yl)-6-methyl-1,3,2-dioxasilinane

上游原料

(5R,7R)-5-((R,E)-4-iodopent-3-en-2-yl)-2,2,3,3,7,9,9,10,10-nonamethyl-4,8-dioxa-3,9-disilaundecane (3R,4R,6R)-6-((tert-butyldimethylsilyl)oxy)-3-methylhept-1-en-4-ol (2S,3R,5R)-3,5-bis((tert-butyldimethylsilyl)oxy)-2-methylhexanal (5R,7R)-5-((R)-4,4-dibromobut-3-en-2-yl)-2,2,3,3,7,9,9,10,10-nonamethyl-4,8-dioxa-3,9-disilaundecane (5R,7R)-5-((R)-but-3-en-2-yl)-2,2,3,3,7,9,9,10,10-nonamethyl-4,8-dioxa-3,9-disilaundecane

下游产品

(6S,7S,12R,E)-12-((2S,6R,E)-6-((4R,6R)-2,2-di-tert-butyl-6-methyl-1,3,2-dioxasilinan-4-yl)-4-methylhept-4-en-2-yl)-6-hydroxy-7,9-dimethyloxacyclododec-9-en-2-one