百科

benzyl (2S,9S,E)-1-(tert-butyldimethylsilyloxy)-9-hydroxy-6-oxotridec-4-en-2-ylcarbamate

benzyl (2S,9S,E)-1-(tert-butyldimethylsilyloxy)-9-hydroxy-6-oxotridec-4-en-2-ylcarbamate

CAS号：1352964-70-5

英文名：benzyl (2S,9S,E)-1-(tert-butyldimethylsilyloxy)-9-hydroxy-6-oxotridec-4-en-2-ylcarbamate

分子式：C27H45NO5Si

分子量：491.735

合成路线

(S)-dimethyl 5-hydroxy-2-oxononylphosphonate

(S)-dimethyl 5-hydroxy-2-oxononylphosphonate

(S)-3-(Cbz-amino)-4-(tert-butyldimethylsilyloxy)butanal

(S)-3-(Cbz-amino)-4-(tert-butyldimethylsilyloxy)butanal

benzyl (2S,9S,E)-1-(tert-butyldimethylsilyloxy)-9-hydroxy-6-oxotridec-4-en-2-ylcarbamate

benzyl (2S,9S,E)-1-(tert-butyldimethylsilyloxy)-9-hydroxy-6-oxotridec-4-en-2-ylcarbamate

methyl (S)-3-(((benzyloxy)carbonyl)amino)-4-((tert-butyldimethylsilyl)oxy)butanoate

methyl (S)-3-(((benzyloxy)carbonyl)amino)-4-((tert-butyldimethylsilyl)oxy)butanoate

benzyl (2S,9S,E)-1-(tert-butyldimethylsilyloxy)-9-hydroxy-6-oxotridec-4-en-2-ylcarbamate

benzyl (2S,9S,E)-1-(tert-butyldimethylsilyloxy)-9-hydroxy-6-oxotridec-4-en-2-ylcarbamate

上游原料

(S)-dimethyl 5-hydroxy-2-oxononylphosphonate (S)-3-(Cbz-amino)-4-(tert-butyldimethylsilyloxy)butanal

下游产品

(E)-ethyl 3-((3R,5S,8aR)-3-butyl-octahydroindolizin-5-yl)acrylate (3R,5S,8aR)-3-butyl-5-(chloromethyl)-octahydroindolizine (S)-1-((2R,6S)-6-((tert-butyldimethylsilyloxy)methyl)piperidin-2-yl)heptan-3-ol ((3R,5S,8aR)-3-butyl-octahydroindolizin-5-yl)methanol ethyl 3-((3R,5S,8aR)-3-butyloctahydroindolizin-5-yl)propanoate