百科

(3S,4R)-3-[(R)-1-(t-butyldimethylsilyloxy)ethyl]-4-[(2'R,6'R)-2'-(t-butyldimethylsilyloxymethyl)cyclohexanone-6'-yl]azetidin-2-one

(3S,4R)-3-[(R)-1-(t-butyldimethylsilyloxy)ethyl]-4-[(2'R,6'R)-2'-(t-butyldimethylsilyloxymethyl)cyclohexanone-6'-yl]azetidin-2-one

CAS号：135297-29-9

英文名：(3S,4R)-3-[(R)-1-(t-butyldimethylsilyloxy)ethyl]-4-[(2'R,6'R)-2'-(t-butyldimethylsilyloxymethyl)cyclohexanone-6'-yl]azetidin-2-one

分子式：C24H47NO4Si2

分子量：469.805

合成路线

(1R,2R)-2-t-butyldimethylsilyloxymethylcyclohexanol

(1R,2R)-2-t-butyldimethylsilyloxymethylcyclohexanol

(3S,4R)-3-[(R)-1-(t-butyldimethylsilyloxy)ethyl]-4-[(2'R,6'R)-2'-(t-butyldimethylsilyloxymethyl)cyclohexanone-6'-yl]azetidin-2-one

(3S,4R)-3-[(R)-1-(t-butyldimethylsilyloxy)ethyl]-4-[(2'R,6'R)-2'-(t-butyldimethylsilyloxymethyl)cyclohexanone-6'-yl]azetidin-2-one

ethyl (1S,2R)-2-hydroxycyclohexanecarboxylate

ethyl (1S,2R)-2-hydroxycyclohexanecarboxylate

(3S,4R)-3-[(R)-1-(t-butyldimethylsilyloxy)ethyl]-4-[(2'R,6'R)-2'-(t-butyldimethylsilyloxymethyl)cyclohexanone-6'-yl]azetidin-2-one

(3S,4R)-3-[(R)-1-(t-butyldimethylsilyloxy)ethyl]-4-[(2'R,6'R)-2'-(t-butyldimethylsilyloxymethyl)cyclohexanone-6'-yl]azetidin-2-one

上游原料

(1R,2R)-2-t-butyldimethylsilyloxymethylcyclohexanol ethyl (1S,2R)-2-hydroxycyclohexanecarboxylate

下游产品

allyl (4S,8S,9R,10S)-10-[(R)-1-(t-butyldimethylsilyloxy)ethyl]-4-triethylsilyloxymethyl-11-oxo-azatricyclo[7.2.0.03,8]undec-2-ene-2-carboxylate allyl (4S,8S,9R,10S)-10-[(R)-1-(t-butyldimethylsilyloxy)ethyl]-4-t-butyldimethylsilyloxymethyl-11-oxo-azatricyclo[7.2.0.03,8]undec-2-ene-2-carboxylate (3S,4R)-3-[(R)-1-(t-butyldimethylsilyloxy)ethyl]-4-[(2'R,6'R)-2'-hydroxymethylcyclohexanone-6'-yl]azetidin-2-one