百科

((3aR,4R,6S,6aS)-6-((E)-5-(benzyloxy)pent-2-enyl)-2,2-dimethyl-tetrahydrofuro[3,4-d][1,3]dioxol-4-yl)methyl acetate

((3aR,4R,6S,6aS)-6-((E)-5-(benzyloxy)pent-2-enyl)-2,2-dimethyl-tetrahydrofuro[3,4-d][1,3]dioxol-4-yl)methyl acetate

CAS号：1353667-07-8

英文名：((3aR,4R,6S,6aS)-6-((E)-5-(benzyloxy)pent-2-enyl)-2,2-dimethyl-tetrahydrofuro[3,4-d][1,3]dioxol-4-yl)methyl acetate

分子式：C22H30O6

分子量：390.47

合成路线

3-(5-O-acetyl-2,3-O-isopropylidene-β-D-ribofuranosyl)prop-1-ene

3-(5-O-acetyl-2,3-O-isopropylidene-β-D-ribofuranosyl)prop-1-ene

((3aR,4R,6S,6aS)-6-((E)-5-(benzyloxy)pent-2-enyl)-2,2-dimethyl-tetrahydrofuro[3,4-d][1,3]dioxol-4-yl)methyl acetate

((3aR,4R,6S,6aS)-6-((E)-5-(benzyloxy)pent-2-enyl)-2,2-dimethyl-tetrahydrofuro[3,4-d][1,3]dioxol-4-yl)methyl acetate

((3aR,4R,6S,6aS)-2,2-dimethyl-6-(2-oxoethyl)tetrahydrofuro[3,4-d][1,3]dioxol-4-yl)methyl acetate

((3aR,4R,6S,6aS)-2,2-dimethyl-6-(2-oxoethyl)tetrahydrofuro[3,4-d][1,3]dioxol-4-yl)methyl acetate

1-((3-(benzyloxy)propyl)sulfonyl)-5-phenyl-1H-tetrazole

1-((3-(benzyloxy)propyl)sulfonyl)-5-phenyl-1H-tetrazole

((3aR,4R,6S,6aS)-6-((E)-5-(benzyloxy)pent-2-enyl)-2,2-dimethyl-tetrahydrofuro[3,4-d][1,3]dioxol-4-yl)methyl acetate

((3aR,4R,6S,6aS)-6-((E)-5-(benzyloxy)pent-2-enyl)-2,2-dimethyl-tetrahydrofuro[3,4-d][1,3]dioxol-4-yl)methyl acetate

上游原料

3-(5-O-acetyl-2,3-O-isopropylidene-β-D-ribofuranosyl)prop-1-ene 1-((3-(benzyloxy)propyl)sulfonyl)-5-phenyl-1H-tetrazole ((3aR,4R,6S,6aS)-2,2-dimethyl-6-(2-oxoethyl)tetrahydrofuro[3,4-d][1,3]dioxol-4-yl)methyl acetate

下游产品

(3aS,4S,6S,6aS)-4-(5-(benzyloxy)pentyl)-6-(chloromethyl)-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxole ((3aR,4R,6S,6aS)-6-(5-(benzyloxy)pentyl)-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxol-4-yl)methyl acetate (R)-6-(benzyloxy)-1-((4S,5R)-5-ethynyl-2,2-dimethyl-1,3-dioxolan-4-yl)hexan-1-ol (S)-6-(benzyloxy)-1-((4S,5R)-5-ethynyl-2,2-dimethyl-1,3-dioxolan-4-yl)hexan-1-ol (4S,5R)-4-((R)-6-(benzyloxy)-1-(methoxymethoxy)hexyl)-5-ethynyl-2,2-dimethyl-1,3-dioxolane (S)-tert-butyl-4-((18-((4R,5S)-5-((R)-6-(benzyloxy)-1-(methoxymethoxy)hexyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-16-oxooctadec-17-ynyloxy)methyl)-2,2-dimethyloxazolidine-3-carboxylate