百科

methyl 3-((1R,2R,4aR,6S,8aS)-2-((E)-3-acetoxyprop-1-en-1-yl)-1,6-dimethyl-1,2,4a,5,6,7,8,8a-octahydronaphthalen-1-yl)-3-oxopropanoate

methyl 3-((1R,2R,4aR,6S,8aS)-2-((E)-3-acetoxyprop-1-en-1-yl)-1,6-dimethyl-1,2,4a,5,6,7,8,8a-octahydronaphthalen-1-yl)-3-oxopropanoate

CAS号：1353848-31-3

英文名：methyl 3-((1R,2R,4aR,6S,8aS)-2-((E)-3-acetoxyprop-1-en-1-yl)-1,6-dimethyl-1,2,4a,5,6,7,8,8a-octahydronaphthalen-1-yl)-3-oxopropanoate

分子式：C21H30O5

分子量：362.46

合成路线

(E)-3-((1R,2R,4aR,6S,8aS)-1-(3-(tert-butylthio)-3-oxopropanoyl)-1,6-dimethyl-1,2,4a,5,6,7,8,8a-octahydronaphthalen-2-yl)allyl acetate

(E)-3-((1R,2R,4aR,6S,8aS)-1-(3-(tert-butylthio)-3-oxopropanoyl)-1,6-dimethyl-1,2,4a,5,6,7,8,8a-octahydronaphthalen-2-yl)allyl acetate

methyl 3-((1R,2R,4aR,6S,8aS)-2-((E)-3-acetoxyprop-1-en-1-yl)-1,6-dimethyl-1,2,4a,5,6,7,8,8a-octahydronaphthalen-1-yl)-3-oxopropanoate

methyl 3-((1R,2R,4aR,6S,8aS)-2-((E)-3-acetoxyprop-1-en-1-yl)-1,6-dimethyl-1,2,4a,5,6,7,8,8a-octahydronaphthalen-1-yl)-3-oxopropanoate

(S)-6-((tert-butyldimethylsilyl)oxy)-3-methylhexanal

(S)-6-((tert-butyldimethylsilyl)oxy)-3-methylhexanal

methyl 3-((1R,2R,4aR,6S,8aS)-2-((E)-3-acetoxyprop-1-en-1-yl)-1,6-dimethyl-1,2,4a,5,6,7,8,8a-octahydronaphthalen-1-yl)-3-oxopropanoate

methyl 3-((1R,2R,4aR,6S,8aS)-2-((E)-3-acetoxyprop-1-en-1-yl)-1,6-dimethyl-1,2,4a,5,6,7,8,8a-octahydronaphthalen-1-yl)-3-oxopropanoate

(S,2E,4E,6E)-12-hydroxy-9-methyldodeca-2,4,6-trien-1-yl acetate

(S,2E,4E,6E)-12-hydroxy-9-methyldodeca-2,4,6-trien-1-yl acetate

methyl 3-((1R,2R,4aR,6S,8aS)-2-((E)-3-acetoxyprop-1-en-1-yl)-1,6-dimethyl-1,2,4a,5,6,7,8,8a-octahydronaphthalen-1-yl)-3-oxopropanoate

methyl 3-((1R,2R,4aR,6S,8aS)-2-((E)-3-acetoxyprop-1-en-1-yl)-1,6-dimethyl-1,2,4a,5,6,7,8,8a-octahydronaphthalen-1-yl)-3-oxopropanoate

(S,2E,4E,6E)-9-methyl-12-oxododeca-2,4,6-trien-1-yl acetate

(S,2E,4E,6E)-9-methyl-12-oxododeca-2,4,6-trien-1-yl acetate

methyl 3-((1R,2R,4aR,6S,8aS)-2-((E)-3-acetoxyprop-1-en-1-yl)-1,6-dimethyl-1,2,4a,5,6,7,8,8a-octahydronaphthalen-1-yl)-3-oxopropanoate

methyl 3-((1R,2R,4aR,6S,8aS)-2-((E)-3-acetoxyprop-1-en-1-yl)-1,6-dimethyl-1,2,4a,5,6,7,8,8a-octahydronaphthalen-1-yl)-3-oxopropanoate

(S,2E,4E,6E,12E)-16-(tert-butylthio)-9,13-dimethyl-14,16-dioxohexadeca-2,4,6,12-tetraen-1-yl acetate

(S,2E,4E,6E,12E)-16-(tert-butylthio)-9,13-dimethyl-14,16-dioxohexadeca-2,4,6,12-tetraen-1-yl acetate

methyl 3-((1R,2R,4aR,6S,8aS)-2-((E)-3-acetoxyprop-1-en-1-yl)-1,6-dimethyl-1,2,4a,5,6,7,8,8a-octahydronaphthalen-1-yl)-3-oxopropanoate

methyl 3-((1R,2R,4aR,6S,8aS)-2-((E)-3-acetoxyprop-1-en-1-yl)-1,6-dimethyl-1,2,4a,5,6,7,8,8a-octahydronaphthalen-1-yl)-3-oxopropanoate

methyl (S,2E,4E,6E)-12-((tert-butyldimethylsilyl)oxy)-9-methyldodeca-2,4,6-trienoate

methyl (S,2E,4E,6E)-12-((tert-butyldimethylsilyl)oxy)-9-methyldodeca-2,4,6-trienoate

methyl 3-((1R,2R,4aR,6S,8aS)-2-((E)-3-acetoxyprop-1-en-1-yl)-1,6-dimethyl-1,2,4a,5,6,7,8,8a-octahydronaphthalen-1-yl)-3-oxopropanoate

methyl 3-((1R,2R,4aR,6S,8aS)-2-((E)-3-acetoxyprop-1-en-1-yl)-1,6-dimethyl-1,2,4a,5,6,7,8,8a-octahydronaphthalen-1-yl)-3-oxopropanoate

(S,2E,4E,6E)-12-((tert-butyldimethylsilyl)oxy)-9-methyldodeca-2,4,6-trien-1-ol

(S,2E,4E,6E)-12-((tert-butyldimethylsilyl)oxy)-9-methyldodeca-2,4,6-trien-1-ol

methyl 3-((1R,2R,4aR,6S,8aS)-2-((E)-3-acetoxyprop-1-en-1-yl)-1,6-dimethyl-1,2,4a,5,6,7,8,8a-octahydronaphthalen-1-yl)-3-oxopropanoate

methyl 3-((1R,2R,4aR,6S,8aS)-2-((E)-3-acetoxyprop-1-en-1-yl)-1,6-dimethyl-1,2,4a,5,6,7,8,8a-octahydronaphthalen-1-yl)-3-oxopropanoate

(S,2E,4E,6E)-12-((tert-butyldimethylsilyl)oxy)-9-methyldodeca-2,4,6-trien-1-yl acetate

(S,2E,4E,6E)-12-((tert-butyldimethylsilyl)oxy)-9-methyldodeca-2,4,6-trien-1-yl acetate

methyl 3-((1R,2R,4aR,6S,8aS)-2-((E)-3-acetoxyprop-1-en-1-yl)-1,6-dimethyl-1,2,4a,5,6,7,8,8a-octahydronaphthalen-1-yl)-3-oxopropanoate

methyl 3-((1R,2R,4aR,6S,8aS)-2-((E)-3-acetoxyprop-1-en-1-yl)-1,6-dimethyl-1,2,4a,5,6,7,8,8a-octahydronaphthalen-1-yl)-3-oxopropanoate

上游原料

(S,2E,4E,6E)-9-methyl-12-oxododeca-2,4,6-trien-1-yl acetate (S,2E,4E,6E,12E)-16-(tert-butylthio)-9,13-dimethyl-14,16-dioxohexadeca-2,4,6,12-tetraen-1-yl acetate (S)-6-((tert-butyldimethylsilyl)oxy)-3-methylhexanal (S,2E,4E,6E)-12-hydroxy-9-methyldodeca-2,4,6-trien-1-yl acetate methyl (S,2E,4E,6E)-12-((tert-butyldimethylsilyl)oxy)-9-methyldodeca-2,4,6-trienoate (S,2E,4E,6E)-12-((tert-butyldimethylsilyl)oxy)-9-methyldodeca-2,4,6-trien-1-ol (E)-3-((1R,2R,4aR,6S,8aS)-1-(3-(tert-butylthio)-3-oxopropanoyl)-1,6-dimethyl-1,2,4a,5,6,7,8,8a-octahydronaphthalen-2-yl)allyl acetate (S,2E,4E,6E)-12-((tert-butyldimethylsilyl)oxy)-9-methyldodeca-2,4,6-trien-1-yl acetate

下游产品

methyl (2S,3R,3aR,5aR,7S,9aS,9bR)-7,9b-dimethyl-1-oxo-3-vinyl-2,3,3a,5a,6,7,8,9,9a,9b-decahydro-1H-cyclopenta[a]naphthalene-2-carboxylate methyl (Z)-2-((3R,3aS,5aR,7S,9aS,9bR)-7,9b-dimethyl-3-vinyl-3a,5a,6,7,8,9,9a,9b-octahydronaphtho[1,2-c]furan-1(3H)-ylidene)acetate