百科

(3E<2E,4S,5S,6E,8<2R,4S,6S,8R(S),9S>>,3aS,4S,6S,7R,7aR)-octahydro-3a,7-dihydroxy-3-<5-hydroxy-8-<4-hydroxy-9-methyl-8-(1-methylpropyl)-1,7-dioxaspiro<5.5>undec-10-en-2-yl>-4,6-dimethylocta-2,6-dienylidene>-6-methylbenzofuran-4-carbaldehyde

(3E<2E,4S,5S,6E,8<2R,4S,6S,8R(S),9S>>,3aS,4S,6S,7R,7aR)-octahydro-3a,7-dihydroxy-3-<5-hydroxy-8-<4-hydroxy-9-methyl-8-(1-methylpropyl)-1,7-dioxaspiro<5.5>undec-10-en-2-yl>-4,6-dimethylocta-2,6-dienylidene>-6-methylbenzofuran-4-carbaldehyde

CAS号：135419-92-0

英文名：(3E<2E,4S,5S,6E,8<2R,4S,6S,8R(S),9S>>,3aS,4S,6S,7R,7aR)-octahydro-3a,7-dihydroxy-3-<5-hydroxy-8-<4-hydroxy-9-methyl-8-(1-methylpropyl)-1,7-dioxaspiro<5.5>undec-10-en-2-yl>-4,6-dimethylocta-2,6-dienylidene>-6-methylbenzofuran-4-carbaldehyde

分子式：C34H52O8

分子量：588.772

合成路线

(4S,6S)-6-<(tert-butyldiphenylsilyloxy)methyl>-4-methylcyclohex-2-enone

(4S,6S)-6-<(tert-butyldiphenylsilyloxy)methyl>-4-methylcyclohex-2-enone

(3E<2E,4S,5S,6E,8<2R,4S,6S,8R(S),9S>>,3aS,4S,6S,7R,7aR)-octahydro-3a,7-dihydroxy-3-<5-hydroxy-8-<4-hydroxy-9-methyl-8-(1-methylpropyl)-1,7-dioxaspiro<5.5>undec-10-en-2-yl>-4,6-dimethylocta-2,6-dienylidene>-6-methylbenzofuran-4-carbaldehyde

(3E<2E,4S,5S,6E,8<2R,4S,6S,8R(S),9S>>,3aS,4S,6S,7R,7aR)-octahydro-3a,7-dihydroxy-3-<5-hydroxy-8-<4-hydroxy-9-methyl-8-(1-methylpropyl)-1,7-dioxaspiro<5.5>undec-10-en-2-yl>-4,6-dimethylocta-2,6-dienylidene>-6-methylbenzofuran-4-carbaldehyde

(3E<2E,4S,5S,6E,8<2R,4S,6S,8R(S),9S>>,3aS,4S,6S,7R,7aR)-octahydro-4-(hydroxymethyl)-3-<5-hydroxy-8-<4-hydroxy-9-methyl-8-(1-methylpropyl)-1,7-dioxaspiro<5.5>undec-10-en-2-yl>-4,6-dimethylocta-2,6-dienylidene>-6-methylbenzofuran-3a,7-diol

(3E<2E,4S,5S,6E,8<2R,4S,6S,8R(S),9S>>,3aS,4S,6S,7R,7aR)-octahydro-4-(hydroxymethyl)-3-<5-hydroxy-8-<4-hydroxy-9-methyl-8-(1-methylpropyl)-1,7-dioxaspiro<5.5>undec-10-en-2-yl>-4,6-dimethylocta-2,6-dienylidene>-6-methylbenzofuran-3a,7-diol

(3E<2E,4S,5S,6E,8<2R,4S,6S,8R(S),9S>>,3aS,4S,6S,7R,7aR)-octahydro-3a,7-dihydroxy-3-<5-hydroxy-8-<4-hydroxy-9-methyl-8-(1-methylpropyl)-1,7-dioxaspiro<5.5>undec-10-en-2-yl>-4,6-dimethylocta-2,6-dienylidene>-6-methylbenzofuran-4-carbaldehyde

(3E<2E,4S,5S,6E,8<2R,4S,6S,8R(S),9S>>,3aS,4S,6S,7R,7aR)-octahydro-3a,7-dihydroxy-3-<5-hydroxy-8-<4-hydroxy-9-methyl-8-(1-methylpropyl)-1,7-dioxaspiro<5.5>undec-10-en-2-yl>-4,6-dimethylocta-2,6-dienylidene>-6-methylbenzofuran-4-carbaldehyde

(3E,3aS,4S,6S,7R,7aR)-7-(tert-butyldimethylsilyloxy)-4-<(tert-butyldiphenylsilyloxy)methyl>octahydro-6-methyl-3-<2-(phenylsulphonyl)ethylidene>benzofuran-3a-ol

(3E,3aS,4S,6S,7R,7aR)-7-(tert-butyldimethylsilyloxy)-4-<(tert-butyldiphenylsilyloxy)methyl>octahydro-6-methyl-3-<2-(phenylsulphonyl)ethylidene>benzofuran-3a-ol

(3E<2E,4S,5S,6E,8<2R,4S,6S,8R(S),9S>>,3aS,4S,6S,7R,7aR)-octahydro-3a,7-dihydroxy-3-<5-hydroxy-8-<4-hydroxy-9-methyl-8-(1-methylpropyl)-1,7-dioxaspiro<5.5>undec-10-en-2-yl>-4,6-dimethylocta-2,6-dienylidene>-6-methylbenzofuran-4-carbaldehyde

(3E<2E,4S,5S,6E,8<2R,4S,6S,8R(S),9S>>,3aS,4S,6S,7R,7aR)-octahydro-3a,7-dihydroxy-3-<5-hydroxy-8-<4-hydroxy-9-methyl-8-(1-methylpropyl)-1,7-dioxaspiro<5.5>undec-10-en-2-yl>-4,6-dimethylocta-2,6-dienylidene>-6-methylbenzofuran-4-carbaldehyde

<3R(E),3aR,4S,6S,7R,7aR>-7-(tert-butyldimethylsilyloxy)-4-<(tert-butyldiphenylsilyloxy)methyl>octahydro-6-methyl-3-<2-(phenylsulphonyl)vinyl>benzofuran-3a-ol

<3R(E),3aR,4S,6S,7R,7aR>-7-(tert-butyldimethylsilyloxy)-4-<(tert-butyldiphenylsilyloxy)methyl>octahydro-6-methyl-3-<2-(phenylsulphonyl)vinyl>benzofuran-3a-ol

(3E<2E,4S,5S,6E,8<2R,4S,6S,8R(S),9S>>,3aS,4S,6S,7R,7aR)-octahydro-3a,7-dihydroxy-3-<5-hydroxy-8-<4-hydroxy-9-methyl-8-(1-methylpropyl)-1,7-dioxaspiro<5.5>undec-10-en-2-yl>-4,6-dimethylocta-2,6-dienylidene>-6-methylbenzofuran-4-carbaldehyde

(3E<2E,4S,5S,6E,8<2R,4S,6S,8R(S),9S>>,3aS,4S,6S,7R,7aR)-octahydro-3a,7-dihydroxy-3-<5-hydroxy-8-<4-hydroxy-9-methyl-8-(1-methylpropyl)-1,7-dioxaspiro<5.5>undec-10-en-2-yl>-4,6-dimethylocta-2,6-dienylidene>-6-methylbenzofuran-4-carbaldehyde

(1E,3S,4S)-1-bromo-2,4-dimethylhexa-1,5-dien-3-ol

(1E,3S,4S)-1-bromo-2,4-dimethylhexa-1,5-dien-3-ol

(3E<2E,4S,5S,6E,8<2R,4S,6S,8R(S),9S>>,3aS,4S,6S,7R,7aR)-octahydro-3a,7-dihydroxy-3-<5-hydroxy-8-<4-hydroxy-9-methyl-8-(1-methylpropyl)-1,7-dioxaspiro<5.5>undec-10-en-2-yl>-4,6-dimethylocta-2,6-dienylidene>-6-methylbenzofuran-4-carbaldehyde

(3E<2E,4S,5S,6E,8<2R,4S,6S,8R(S),9S>>,3aS,4S,6S,7R,7aR)-octahydro-3a,7-dihydroxy-3-<5-hydroxy-8-<4-hydroxy-9-methyl-8-(1-methylpropyl)-1,7-dioxaspiro<5.5>undec-10-en-2-yl>-4,6-dimethylocta-2,6-dienylidene>-6-methylbenzofuran-4-carbaldehyde

上游原料

(3E,3aS,4S,6S,7R,7aR)-7-(tert-butyldimethylsilyloxy)-4-<(tert-butyldiphenylsilyloxy)methyl>octahydro-6-methyl-3-<2-(phenylsulphonyl)ethylidene>benzofuran-3a-ol (4S,6S)-6-<(tert-butyldiphenylsilyloxy)methyl>-4-methylcyclohex-2-enone (1E,3S,4S)-1-bromo-2,4-dimethylhexa-1,5-dien-3-ol (3E<2E,4S,5S,6E,8<2R,4S,6S,8R(S),9S>>,3aS,4S,6S,7R,7aR)-octahydro-4-(hydroxymethyl)-3-<5-hydroxy-8-<4-hydroxy-9-methyl-8-(1-methylpropyl)-1,7-dioxaspiro<5.5>undec-10-en-2-yl>-4,6-dimethylocta-2,6-dienylidene>-6-methylbenzofuran-3a,7-diol <3R(E),3aR,4S,6S,7R,7aR>-7-(tert-butyldimethylsilyloxy)-4-<(tert-butyldiphenylsilyloxy)methyl>octahydro-6-methyl-3-<2-(phenylsulphonyl)vinyl>benzofuran-3a-ol

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