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(2R,3S,4R)-2-(tert-butyldimethylsilyloxy)-3,4-(isopropylidenedioxy)hex-5-yn-1-ol

(2R,3S,4R)-2-(tert-butyldimethylsilyloxy)-3,4-(isopropylidenedioxy)hex-5-yn-1-ol

CAS号：1354520-05-0

英文名：(2R,3S,4R)-2-(tert-butyldimethylsilyloxy)-3,4-(isopropylidenedioxy)hex-5-yn-1-ol

分子式：C15H28O4Si

分子量：300.466

合成路线

(3aR,4R,6R,6aR)-2,2-dimethyl-6-(trityloxymethyl)-3a,4,6,6a-tetrahydrofuro[3,4-d][1,3]dioxol-4-ol

(3aR,4R,6R,6aR)-2,2-dimethyl-6-(trityloxymethyl)-3a,4,6,6a-tetrahydrofuro[3,4-d][1,3]dioxol-4-ol

(2R,3S,4R)-2-(tert-butyldimethylsilyloxy)-3,4-(isopropylidenedioxy)hex-5-yn-1-ol

(2R,3S,4R)-2-(tert-butyldimethylsilyloxy)-3,4-(isopropylidenedioxy)hex-5-yn-1-ol

(3R,4S,5R)-5-(tert-butyldimethylsilyloxy)-3,4-(isopropylidenedioxy)-6-(triphenylmethoxy)hex-1-yne

(3R,4S,5R)-5-(tert-butyldimethylsilyloxy)-3,4-(isopropylidenedioxy)-6-(triphenylmethoxy)hex-1-yne

(2R,3S,4R)-2-(tert-butyldimethylsilyloxy)-3,4-(isopropylidenedioxy)hex-5-yn-1-ol

(2R,3S,4R)-2-(tert-butyldimethylsilyloxy)-3,4-(isopropylidenedioxy)hex-5-yn-1-ol

3,4-isopropylidene-6-O-triphenylmethyl-1,2-dideoxy-D-ribohex-1-ynitol

3,4-isopropylidene-6-O-triphenylmethyl-1,2-dideoxy-D-ribohex-1-ynitol

(2R,3S,4R)-2-(tert-butyldimethylsilyloxy)-3,4-(isopropylidenedioxy)hex-5-yn-1-ol

(2R,3S,4R)-2-(tert-butyldimethylsilyloxy)-3,4-(isopropylidenedioxy)hex-5-yn-1-ol

上游原料

(3R,4S,5R)-5-(tert-butyldimethylsilyloxy)-3,4-(isopropylidenedioxy)-6-(triphenylmethoxy)hex-1-yne 3,4-isopropylidene-6-O-triphenylmethyl-1,2-dideoxy-D-ribohex-1-ynitol (3aR,4R,6R,6aR)-2,2-dimethyl-6-(trityloxymethyl)-3a,4,6,6a-tetrahydrofuro[3,4-d][1,3]dioxol-4-ol

下游产品

((S)-1-((4S,5R)-5-((Z)-2-bromovinyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethoxyethoxy)(tert-butyl)dimethylsilane tert-butyl((S)-1-((4S,5R)-5-ethynyl-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethoxyethoxy)dimethylsilane tert-butyl((S)-1-((4S,5R)-5-((Z)-2-iodovinyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethoxyethoxy)dimethylsilane