百科

(2S,6S,E)-methyl 2-((benzyloxycarbonyl)(tert-butoxycarbonyl)amino)-6-(tert-butyldiphenylsilyloxy)-4-methylhept-4-enoate

(2S,6S,E)-methyl 2-((benzyloxycarbonyl)(tert-butoxycarbonyl)amino)-6-(tert-butyldiphenylsilyloxy)-4-methylhept-4-enoate

CAS号：1354913-17-9

英文名：(2S,6S,E)-methyl 2-((benzyloxycarbonyl)(tert-butoxycarbonyl)amino)-6-(tert-butyldiphenylsilyloxy)-4-methylhept-4-enoate

分子式：C38H49NO7Si

分子量：659.884

合成路线

methyl (S,E)-4-(tert-butyldiphenylsilyloxy)-2-methylpent-2-en-1-ol

methyl (S,E)-4-(tert-butyldiphenylsilyloxy)-2-methylpent-2-en-1-ol

(2S,6S,E)-methyl 2-((benzyloxycarbonyl)(tert-butoxycarbonyl)amino)-6-(tert-butyldiphenylsilyloxy)-4-methylhept-4-enoate

(2S,6S,E)-methyl 2-((benzyloxycarbonyl)(tert-butoxycarbonyl)amino)-6-(tert-butyldiphenylsilyloxy)-4-methylhept-4-enoate

(S,E)-4-(((tert-butyl)diphenylsilyl)oxy)-2-methylpent-2-enal

(S,E)-4-(((tert-butyl)diphenylsilyl)oxy)-2-methylpent-2-enal

(2S,6S,E)-methyl 2-((benzyloxycarbonyl)(tert-butoxycarbonyl)amino)-6-(tert-butyldiphenylsilyloxy)-4-methylhept-4-enoate

(2S,6S,E)-methyl 2-((benzyloxycarbonyl)(tert-butoxycarbonyl)amino)-6-(tert-butyldiphenylsilyloxy)-4-methylhept-4-enoate

(S,E)-ethyl 4-(tert-butyldiphenylsilyloxy)-2-methylpent-2-enoate

(S,E)-ethyl 4-(tert-butyldiphenylsilyloxy)-2-methylpent-2-enoate

(2S,6S,E)-methyl 2-((benzyloxycarbonyl)(tert-butoxycarbonyl)amino)-6-(tert-butyldiphenylsilyloxy)-4-methylhept-4-enoate

(2S,6S,E)-methyl 2-((benzyloxycarbonyl)(tert-butoxycarbonyl)amino)-6-(tert-butyldiphenylsilyloxy)-4-methylhept-4-enoate

(S,2Z,4E)-methyl 2-(benzyloxycarbonylamino)-6-(tert-butyl-diphenylsilyloxy)-4-methylhepta-2,4-dienoate

(S,2Z,4E)-methyl 2-(benzyloxycarbonylamino)-6-(tert-butyl-diphenylsilyloxy)-4-methylhepta-2,4-dienoate

(2S,6S,E)-methyl 2-((benzyloxycarbonyl)(tert-butoxycarbonyl)amino)-6-(tert-butyldiphenylsilyloxy)-4-methylhept-4-enoate

(2S,6S,E)-methyl 2-((benzyloxycarbonyl)(tert-butoxycarbonyl)amino)-6-(tert-butyldiphenylsilyloxy)-4-methylhept-4-enoate

上游原料

(S,2Z,4E)-methyl 2-(benzyloxycarbonylamino)-6-(tert-butyl-diphenylsilyloxy)-4-methylhepta-2,4-dienoate (S,E)-ethyl 4-(tert-butyldiphenylsilyloxy)-2-methylpent-2-enoate (S,E)-4-(((tert-butyl)diphenylsilyl)oxy)-2-methylpent-2-enal methyl (S,E)-4-(tert-butyldiphenylsilyloxy)-2-methylpent-2-en-1-ol

下游产品

(2S,4R)-methyl 2-((benzyloxycarbonyl)(tert-butoxycarbonyl)-amino)-4-(tert-butoxycarbonylamino)-5-hydroxy-4-methylpentanoate tert-butyl (3S,5R)-5-methyl-2-oxotetrahydro-2H-pyran-3,5-diyldicarbamate (2S,4R,E)-methyl 2-((benzyloxycarbonyl)(tert-butoxycarbonyl)amino)-4-(tert-butoxycarbonylamino)-4-methylhept-5-enoate methyl (2S,4R)-2,4-bis((tert-butoxycarbonyl)amino)-5-hydroxy-4-methylpentanoate (2S,6S,E)-methyl 2-((benzyloxycarbonyl)(tert-butoxycarbonyl)amino)-6-hydroxy-4-methylhept-4-enoate (2S,6S,E)-methyl 2-((benzyloxycarbonyl)(tert-butoxycarbonyl)amino)-6-(carbamoyloxy)-4-methylhept-4-enoate