百科

(1S,4S,4aS,8aR)-4-((2R,5S)-5-chloro-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)-6-methyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol

CAS号：1354928-65-6

英文名：(1S,4S,4aS,8aR)-4-((2R,5S)-5-chloro-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)-6-methyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol

分子式：C19H31ClO2

分子量：326.901

合成路线

440333-40-4

(4S,4aR,8aR)-4-((2R,5S)-5-chloro-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)-6-methyl-3,4,4a,7,8,8a-hexahydronaphthalen-1-one

1354928-65-6

(1S,4S,4aS,8aR)-4-((2R,5S)-5-chloro-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)-6-methyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol

1354928-66-7

(1R,4S,4aS,8aR)-4-((2R,5S)-5-chloro-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)-6-methyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol

440333-45-9

(2S,6R)-2-(3-(benzyloxy)propyl)-6-hydroxy-3,7-dimethyloct-7-ene-1,3-diyl diacetate

1354928-65-6

(1S,4S,4aS,8aR)-4-((2R,5S)-5-chloro-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)-6-methyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol

1354928-66-7

(1R,4S,4aS,8aR)-4-((2R,5S)-5-chloro-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)-6-methyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol

440333-31-3

(2S,3R,6R)-3-acetoxy-2-(3-benzyloxypropyl)-6-chloro-3,7-dimethyl-7-octenyl acetate

1354928-65-6

(1S,4S,4aS,8aR)-4-((2R,5S)-5-chloro-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)-6-methyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol

1354928-66-7

(1R,4S,4aS,8aR)-4-((2R,5S)-5-chloro-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)-6-methyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol

440333-33-5

(2S,6S)-2-(3-(benzyloxy)propyl)-6-chloro-3-hydroxy-3,7-dimethyloct-7-en-1-yl pivalate

1354928-65-6

(1S,4S,4aS,8aR)-4-((2R,5S)-5-chloro-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)-6-methyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol

1354928-66-7

(1R,4S,4aS,8aR)-4-((2R,5S)-5-chloro-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)-6-methyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol

440333-17-5

((2R,3R)-3-((R)-3-((tert-butyldiphenylsilyl)oxy)-4-methylpent-4-en-1-yl)-3-methyloxiran-2-yl)methanol

1354928-65-6

(1S,4S,4aS,8aR)-4-((2R,5S)-5-chloro-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)-6-methyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol

1354928-66-7

(1R,4S,4aS,8aR)-4-((2R,5S)-5-chloro-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)-6-methyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol

440333-58-4

1354928-65-6

(1S,4S,4aS,8aR)-4-((2R,5S)-5-chloro-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)-6-methyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol

1354928-66-7

(1R,4S,4aS,8aR)-4-((2R,5S)-5-chloro-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)-6-methyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol

440333-27-7

(2S,6R)-2-(3-(benzyloxy)propyl)-6-((tert-butyldiphenylsilyl)oxy)-3,7-dimethyloct-7-ene-1,3-diyl diacetate

1354928-65-6

(1S,4S,4aS,8aR)-4-((2R,5S)-5-chloro-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)-6-methyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol

1354928-66-7

(1R,4S,4aS,8aR)-4-((2R,5S)-5-chloro-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)-6-methyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol

440333-44-8

(E)-(R)-6-(tert-Butyl-diphenyl-silanyloxy)-3,7-dimethyl-octa-2,7-dien-1-ol

1354928-65-6

(1S,4S,4aS,8aR)-4-((2R,5S)-5-chloro-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)-6-methyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol

1354928-66-7

(1R,4S,4aS,8aR)-4-((2R,5S)-5-chloro-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)-6-methyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol

440333-35-7

(2S)-5-benzyloxy-2-[(2R,5S)-(5-chloro-2,6,6-trimethyltetrahydropyran-2-yl)]-pentyl pivalate

1354928-65-6

(1S,4S,4aS,8aR)-4-((2R,5S)-5-chloro-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)-6-methyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol

1354928-66-7

(1R,4S,4aS,8aR)-4-((2R,5S)-5-chloro-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)-6-methyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol

440333-37-9

(2S,5RS)-5-(tert-butyldimethylsilanyloxy)-2-[(2R,5S)-(5-chloro-2,6,6-trimethyltetrahydropyran-2-yl)]-6-heptenyl pivalate

1354928-65-6

(1S,4S,4aS,8aR)-4-((2R,5S)-5-chloro-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)-6-methyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol

1354928-66-7

(1R,4S,4aS,8aR)-4-((2R,5S)-5-chloro-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)-6-methyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol

上游原料

(2S,3R,6R)-3-acetoxy-2-(3-benzyloxypropyl)-6-chloro-3,7-dimethyl-7-octenyl acetate (E)-(R)-8-(tert-Butyl-dimethyl-silanyloxy)-2,6-dimethyl-octa-1,6-dien-3-ol (4S,4aR,8aR)-4-((2R,5S)-5-chloro-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)-6-methyl-3,4,4a,7,8,8a-hexahydronaphthalen-1-one (2S,6R)-2-(3-(benzyloxy)propyl)-6-hydroxy-3,7-dimethyloct-7-ene-1,3-diyl diacetate (2S)-5-benzyloxy-2-[(2R,5S)-(5-chloro-2,6,6-trimethyltetrahydropyran-2-yl)]-pentyl pivalate 2,2-Dimethyl-propionic acid (S)-2-((2R,5S)-5-chloro-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-5-oxo-pentyl ester (E)-(R)-6-(tert-Butyl-diphenyl-silanyloxy)-3,7-dimethyl-octa-2,7-dien-1-ol (2S,5RS)-5-(tert-butyldimethylsilanyloxy)-2-[(2R,5S)-(5-chloro-2,6,6-trimethyltetrahydropyran-2-yl)]-6-hepten-1-ol (2S,6S)-2-(3-(benzyloxy)propyl)-6-chloro-3-hydroxy-3,7-dimethyloct-7-en-1-yl pivalate 2,2-Dimethyl-propionic acid (S)-2-((2R,5S)-5-chloro-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-5-hydroxy-pentyl ester 2,2-Dimethyl-propionic acid (S)-2-((2R,5S)-5-chloro-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-5-hydroxy-hept-6-enyl ester (2S,5RS)-5-(tert-butyldimethylsilanyloxy)-2-[(2R,5S)-(5-chloro-2,6,6-trimethyltetrahydropyran-2-yl)]-6-heptenyl pivalate (2S,6R)-2-(3-(benzyloxy)propyl)-6-((tert-butyldiphenylsilyl)oxy)-3,7-dimethyloct-7-ene-1,3-diyl diacetate

下游产品

tert-butyl((1aR,3aR,4S,7S,7aS,7bS)-7-((2R,5S)-5-chloro-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)-1a-methyldecahydronaphtho[2,1-b]oxiren-4-yloxy)dimethylsilane (4S,4aR,5R,6R,8aS)-5-azido-4-((2R,5S)-5-chloro-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)-6-hydroxy-6-methyloctahydronaphthalen-1(2H)-one (1aR,3aR,4S,7S,7aS,7bS)-7-((2R,5S)-5-chloro-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)-1a-methyldecahydronaphtho[1,2-b]oxiren-4-ol (1aR,3aR,7S,7aR,7bS)-7-((2R,5S)-5-chloro-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)-1a-methyl-octahydronaphtho[2,1-b]oxiren-4(7bH)-one