百科

(2Z,4E,6R,7S,9R,10Z,12S,13R)-methyl-7,13-bis(tert-butyldimethylsilyloxy)-9-hydroxy-6,12-dimethyl-14-phenyltetradeca-2,4,10-trienoate

(2Z,4E,6R,7S,9R,10Z,12S,13R)-methyl-7,13-bis(tert-butyldimethylsilyloxy)-9-hydroxy-6,12-dimethyl-14-phenyltetradeca-2,4,10-trienoate

CAS号：1356452-27-1

英文名：(2Z,4E,6R,7S,9R,10Z,12S,13R)-methyl-7,13-bis(tert-butyldimethylsilyloxy)-9-hydroxy-6,12-dimethyl-14-phenyltetradeca-2,4,10-trienoate

分子式：C35H60O5Si2

分子量：617.019

合成路线

tert-butyl[(2R,3S,Z)-5-iodo-3-methyl-1-phenylpent-4-en-2-yloxy]dimethylsilane

tert-butyl[(2R,3S,Z)-5-iodo-3-methyl-1-phenylpent-4-en-2-yloxy]dimethylsilane

methyl (2Z,4E)-(6R,7S)-7-(tert-butyldimethylsilyloxy)-6-methyl-9-oxo-nona-2,4-dienoate

methyl (2Z,4E)-(6R,7S)-7-(tert-butyldimethylsilyloxy)-6-methyl-9-oxo-nona-2,4-dienoate

(2Z,4E,6R,7S,9R,10Z,12S,13R)-methyl-7,13-bis(tert-butyldimethylsilyloxy)-9-hydroxy-6,12-dimethyl-14-phenyltetradeca-2,4,10-trienoate

(2Z,4E,6R,7S,9R,10Z,12S,13R)-methyl-7,13-bis(tert-butyldimethylsilyloxy)-9-hydroxy-6,12-dimethyl-14-phenyltetradeca-2,4,10-trienoate

(2Z,4E,6R,7S,9S,10Z,12S,13R)-methyl-7,13-bis(tert-butyldimethylsilyloxy)-9-hydroxy-6,12-dimethyl-14-phenyltetradeca-2,4,10-trienoate

(2Z,4E,6R,7S,9S,10Z,12S,13R)-methyl-7,13-bis(tert-butyldimethylsilyloxy)-9-hydroxy-6,12-dimethyl-14-phenyltetradeca-2,4,10-trienoate

(2R,3S)-3-methyl-1-phenylpent-4-yn-2-ol

(2R,3S)-3-methyl-1-phenylpent-4-yn-2-ol

(2Z,4E,6R,7S,9R,10Z,12S,13R)-methyl-7,13-bis(tert-butyldimethylsilyloxy)-9-hydroxy-6,12-dimethyl-14-phenyltetradeca-2,4,10-trienoate

(2Z,4E,6R,7S,9R,10Z,12S,13R)-methyl-7,13-bis(tert-butyldimethylsilyloxy)-9-hydroxy-6,12-dimethyl-14-phenyltetradeca-2,4,10-trienoate

tert-butyldimethyl[(2R,3S)-3-methyl-1-phenylpent-4-yn-2-yloxy]silane

tert-butyldimethyl[(2R,3S)-3-methyl-1-phenylpent-4-yn-2-yloxy]silane

(2Z,4E,6R,7S,9R,10Z,12S,13R)-methyl-7,13-bis(tert-butyldimethylsilyloxy)-9-hydroxy-6,12-dimethyl-14-phenyltetradeca-2,4,10-trienoate

(2Z,4E,6R,7S,9R,10Z,12S,13R)-methyl-7,13-bis(tert-butyldimethylsilyloxy)-9-hydroxy-6,12-dimethyl-14-phenyltetradeca-2,4,10-trienoate

tert-butyl[(2R,3S)-5-iodo-3-methyl-1-phenylpent-4-yn-2-yloxy]dimethylsilane

tert-butyl[(2R,3S)-5-iodo-3-methyl-1-phenylpent-4-yn-2-yloxy]dimethylsilane

(2Z,4E,6R,7S,9R,10Z,12S,13R)-methyl-7,13-bis(tert-butyldimethylsilyloxy)-9-hydroxy-6,12-dimethyl-14-phenyltetradeca-2,4,10-trienoate

(2Z,4E,6R,7S,9R,10Z,12S,13R)-methyl-7,13-bis(tert-butyldimethylsilyloxy)-9-hydroxy-6,12-dimethyl-14-phenyltetradeca-2,4,10-trienoate

上游原料

tert-butyl[(2R,3S)-5-iodo-3-methyl-1-phenylpent-4-yn-2-yloxy]dimethylsilane tert-butyldimethyl[(2R,3S)-3-methyl-1-phenylpent-4-yn-2-yloxy]silane methyl (2Z,4E)-(6R,7S)-7-(tert-butyldimethylsilyloxy)-6-methyl-9-oxo-nona-2,4-dienoate (2R,3S)-3-methyl-1-phenylpent-4-yn-2-ol tert-butyl[(2R,3S,Z)-5-iodo-3-methyl-1-phenylpent-4-en-2-yloxy]dimethylsilane

下游产品

(R,2Z,4E)-methyl-6-[(4S,6R)-6-{(3S,4R,Z)-4-hydroxy-3-methyl-5-phenylpent-1-enyl}-2,2-dimethyl-1,3-dioxan-4-yl]hepta-2,4-dienoate