百科

(2Z,4E,6R,7S,9S,10Z,12S,13S,14S)-methyl-7,13-bis(tert-butyldimethylsilyloxy)-9-hydroxy-6,12-dimethyl-14-phenylpentadeca-2,4,10-trienoate

(2Z,4E,6R,7S,9S,10Z,12S,13S,14S)-methyl-7,13-bis(tert-butyldimethylsilyloxy)-9-hydroxy-6,12-dimethyl-14-phenylpentadeca-2,4,10-trienoate

CAS号：1356452-29-3

英文名：(2Z,4E,6R,7S,9S,10Z,12S,13S,14S)-methyl-7,13-bis(tert-butyldimethylsilyloxy)-9-hydroxy-6,12-dimethyl-14-phenylpentadeca-2,4,10-trienoate

分子式：C36H62O5Si2

分子量：631.045

合成路线

methyl (2Z,4E)-(6R,7S)-7-(tert-butyldimethylsilyloxy)-6-methyl-9-oxo-nona-2,4-dienoate

methyl (2Z,4E)-(6R,7S)-7-(tert-butyldimethylsilyloxy)-6-methyl-9-oxo-nona-2,4-dienoate

tert-butyl[(2S,3S,4S,Z)-6-iodo-4-methyl-2-phenylhex-5-en-3-yloxy]dimethylsilane

tert-butyl[(2S,3S,4S,Z)-6-iodo-4-methyl-2-phenylhex-5-en-3-yloxy]dimethylsilane

(2Z,4E,6R,7S,9S,10Z,12S,13S,14S)-methyl-7,13-bis(tert-butyldimethylsilyloxy)-9-hydroxy-6,12-dimethyl-14-phenylpentadeca-2,4,10-trienoate

(2Z,4E,6R,7S,9S,10Z,12S,13S,14S)-methyl-7,13-bis(tert-butyldimethylsilyloxy)-9-hydroxy-6,12-dimethyl-14-phenylpentadeca-2,4,10-trienoate

(2Z,4E,6R,7S,9R,10Z,12S,13S,14S)-methyl-7,13-bis(tert-butyldimethylsilyloxy)-9-hydroxy-6,12-dimethyl-14-phenylpentadeca-2,4,10-trienoate

(2Z,4E,6R,7S,9R,10Z,12S,13S,14S)-methyl-7,13-bis(tert-butyldimethylsilyloxy)-9-hydroxy-6,12-dimethyl-14-phenylpentadeca-2,4,10-trienoate

(2S,3S,4S)-4-methyl-2-phenylhex-5-yn-3-ol

(2S,3S,4S)-4-methyl-2-phenylhex-5-yn-3-ol

(2Z,4E,6R,7S,9S,10Z,12S,13S,14S)-methyl-7,13-bis(tert-butyldimethylsilyloxy)-9-hydroxy-6,12-dimethyl-14-phenylpentadeca-2,4,10-trienoate

(2Z,4E,6R,7S,9S,10Z,12S,13S,14S)-methyl-7,13-bis(tert-butyldimethylsilyloxy)-9-hydroxy-6,12-dimethyl-14-phenylpentadeca-2,4,10-trienoate

tert-butyldimethyl[(2S,3S,4S)-4-methyl-2-phenylhex-5-yn-3-yloxy]silane

tert-butyldimethyl[(2S,3S,4S)-4-methyl-2-phenylhex-5-yn-3-yloxy]silane

(2Z,4E,6R,7S,9S,10Z,12S,13S,14S)-methyl-7,13-bis(tert-butyldimethylsilyloxy)-9-hydroxy-6,12-dimethyl-14-phenylpentadeca-2,4,10-trienoate

(2Z,4E,6R,7S,9S,10Z,12S,13S,14S)-methyl-7,13-bis(tert-butyldimethylsilyloxy)-9-hydroxy-6,12-dimethyl-14-phenylpentadeca-2,4,10-trienoate

tert-butyl[(2S,3R,4S)-6-iodo-4-methyl-2-phenylhex-5-yn-3-yloxy]dimethylsilane

tert-butyl[(2S,3R,4S)-6-iodo-4-methyl-2-phenylhex-5-yn-3-yloxy]dimethylsilane

(2Z,4E,6R,7S,9S,10Z,12S,13S,14S)-methyl-7,13-bis(tert-butyldimethylsilyloxy)-9-hydroxy-6,12-dimethyl-14-phenylpentadeca-2,4,10-trienoate

(2Z,4E,6R,7S,9S,10Z,12S,13S,14S)-methyl-7,13-bis(tert-butyldimethylsilyloxy)-9-hydroxy-6,12-dimethyl-14-phenylpentadeca-2,4,10-trienoate

上游原料

(2S,3S,4S)-4-methyl-2-phenylhex-5-yn-3-ol tert-butyl[(2S,3S,4S,Z)-6-iodo-4-methyl-2-phenylhex-5-en-3-yloxy]dimethylsilane tert-butyl[(2S,3R,4S)-6-iodo-4-methyl-2-phenylhex-5-yn-3-yloxy]dimethylsilane methyl (2Z,4E)-(6R,7S)-7-(tert-butyldimethylsilyloxy)-6-methyl-9-oxo-nona-2,4-dienoate tert-butyldimethyl[(2S,3S,4S)-4-methyl-2-phenylhex-5-yn-3-yloxy]silane

下游产品

(R,2Z,4E)-methyl-6-[(4S,6S)-6-{(3S,4S,5S,Z)-4-hydroxy-3-methyl-5-phenylhex-1-enyl}-2,2-dimethyl-1,3-dioxan-4-yl]hepta-2,4-dienoate