百科

methyl 4-azido-2,3-di-O-acetyl-4-deoxy-β-L-arabinopyranosyl-(1->8)-(allyl 3,4,5,7-tetra-O-acetyl-D-glycero-α-D-talo-oct-2-ulopyranoside)onate

methyl 4-azido-2,3-di-O-acetyl-4-deoxy-β-L-arabinopyranosyl-(1->8)-(allyl 3,4,5,7-tetra-O-acetyl-D-glycero-α-D-talo-oct-2-ulopyranoside)onate

CAS号：1356479-22-5

英文名：methyl 4-azido-2,3-di-O-acetyl-4-deoxy-β-L-arabinopyranosyl-(1->8)-(allyl 3,4,5,7-tetra-O-acetyl-D-glycero-α-D-talo-oct-2-ulopyranoside)onate

分子式：C29H39N3O18

分子量：717.629

合成路线

methyl (2R,3S,4S,5R,6R)-2-(allyloxy)-6-((R)-2-((tert-butyldimethylsilyl)oxy)-1-hydroxyethyl)-3,4,5-trihydroxytetrahydro-2H-pyran-2-carboxylate

methyl (2R,3S,4S,5R,6R)-2-(allyloxy)-6-((R)-2-((tert-butyldimethylsilyl)oxy)-1-hydroxyethyl)-3,4,5-trihydroxytetrahydro-2H-pyran-2-carboxylate

methyl 4-azido-2,3-di-O-acetyl-4-deoxy-β-L-arabinopyranosyl-(1->8)-(allyl 3,4,5,7-tetra-O-acetyl-D-glycero-α-D-talo-oct-2-ulopyranoside)onate

methyl 4-azido-2,3-di-O-acetyl-4-deoxy-β-L-arabinopyranosyl-(1->8)-(allyl 3,4,5,7-tetra-O-acetyl-D-glycero-α-D-talo-oct-2-ulopyranoside)onate

methyl (allyl 3,4,5,7-tetra-O-acetyl-8-O-tert-butyldimethylsilyl-D-glycero-α-D-talo-oct-2-ulopyranoside)onate

methyl (allyl 3,4,5,7-tetra-O-acetyl-8-O-tert-butyldimethylsilyl-D-glycero-α-D-talo-oct-2-ulopyranoside)onate

methyl 4-azido-2,3-di-O-acetyl-4-deoxy-β-L-arabinopyranosyl-(1->8)-(allyl 3,4,5,7-tetra-O-acetyl-D-glycero-α-D-talo-oct-2-ulopyranoside)onate

methyl 4-azido-2,3-di-O-acetyl-4-deoxy-β-L-arabinopyranosyl-(1->8)-(allyl 3,4,5,7-tetra-O-acetyl-D-glycero-α-D-talo-oct-2-ulopyranoside)onate

(2R,3S,4S,5S,6R)-6-((R)-1-acetoxy-2-hydroxyethyl)-2-(allyloxy)-2-(methoxycarbonyl)tetrahydro-2H-pyran-3,4,5-triyl triacetate

(2R,3S,4S,5S,6R)-6-((R)-1-acetoxy-2-hydroxyethyl)-2-(allyloxy)-2-(methoxycarbonyl)tetrahydro-2H-pyran-3,4,5-triyl triacetate

methyl 4-azido-2,3-di-O-acetyl-4-deoxy-β-L-arabinopyranosyl-(1->8)-(allyl 3,4,5,7-tetra-O-acetyl-D-glycero-α-D-talo-oct-2-ulopyranoside)onate

methyl 4-azido-2,3-di-O-acetyl-4-deoxy-β-L-arabinopyranosyl-(1->8)-(allyl 3,4,5,7-tetra-O-acetyl-D-glycero-α-D-talo-oct-2-ulopyranoside)onate

methyl 4-azido-2,3-di-O-benzyl-4-deoxy-β-L-arabinopyranosyl-(1->8)-(allyl 3,4,5,7-tetra-O-acetyl-D-glycero-α-D-talo-oct-2-ulopyranoside)onate

methyl 4-azido-2,3-di-O-benzyl-4-deoxy-β-L-arabinopyranosyl-(1->8)-(allyl 3,4,5,7-tetra-O-acetyl-D-glycero-α-D-talo-oct-2-ulopyranoside)onate

methyl 4-azido-2,3-di-O-acetyl-4-deoxy-β-L-arabinopyranosyl-(1->8)-(allyl 3,4,5,7-tetra-O-acetyl-D-glycero-α-D-talo-oct-2-ulopyranoside)onate

methyl 4-azido-2,3-di-O-acetyl-4-deoxy-β-L-arabinopyranosyl-(1->8)-(allyl 3,4,5,7-tetra-O-acetyl-D-glycero-α-D-talo-oct-2-ulopyranoside)onate

methyl 4-azido-2,3-di-O-benzyl-4-deoxy-β-L-arabinopyranosyl-(1->8)-(allyl D-glycero-α-D-talo-oct-2-ulopyranoside)onate

methyl 4-azido-2,3-di-O-benzyl-4-deoxy-β-L-arabinopyranosyl-(1->8)-(allyl D-glycero-α-D-talo-oct-2-ulopyranoside)onate

methyl 4-azido-2,3-di-O-acetyl-4-deoxy-β-L-arabinopyranosyl-(1->8)-(allyl 3,4,5,7-tetra-O-acetyl-D-glycero-α-D-talo-oct-2-ulopyranoside)onate

methyl 4-azido-2,3-di-O-acetyl-4-deoxy-β-L-arabinopyranosyl-(1->8)-(allyl 3,4,5,7-tetra-O-acetyl-D-glycero-α-D-talo-oct-2-ulopyranoside)onate

4-azido-2,3-di-O-benzyl-4-deoxy-β-L-arabinopyranosyl N-phenyltrifluoroacetimidate

4-azido-2,3-di-O-benzyl-4-deoxy-β-L-arabinopyranosyl N-phenyltrifluoroacetimidate

methyl 4-azido-2,3-di-O-acetyl-4-deoxy-β-L-arabinopyranosyl-(1->8)-(allyl 3,4,5,7-tetra-O-acetyl-D-glycero-α-D-talo-oct-2-ulopyranoside)onate

methyl 4-azido-2,3-di-O-acetyl-4-deoxy-β-L-arabinopyranosyl-(1->8)-(allyl 3,4,5,7-tetra-O-acetyl-D-glycero-α-D-talo-oct-2-ulopyranoside)onate

上游原料

(2R,3S,4S,5S,6R)-6-((R)-1-acetoxy-2-hydroxyethyl)-2-(allyloxy)-2-(methoxycarbonyl)tetrahydro-2H-pyran-3,4,5-triyl triacetate methyl (allyl 3,4,5,7-tetra-O-acetyl-8-O-tert-butyldimethylsilyl-D-glycero-α-D-talo-oct-2-ulopyranoside)onate methyl 4-azido-2,3-di-O-benzyl-4-deoxy-β-L-arabinopyranosyl-(1->8)-(allyl 3,4,5,7-tetra-O-acetyl-D-glycero-α-D-talo-oct-2-ulopyranoside)onate 4-azido-2,3-di-O-benzyl-4-deoxy-β-L-arabinopyranosyl N-phenyltrifluoroacetimidate methyl (2R,3S,4S,5R,6R)-2-(allyloxy)-6-((R)-2-((tert-butyldimethylsilyl)oxy)-1-hydroxyethyl)-3,4,5-trihydroxytetrahydro-2H-pyran-2-carboxylate methyl 4-azido-2,3-di-O-benzyl-4-deoxy-β-L-arabinopyranosyl-(1->8)-(allyl D-glycero-α-D-talo-oct-2-ulopyranoside)onate

下游产品

ammonium 4-amino-4-deoxy-β-L-arabinopyranosyl-(1->8)-[3-(3-mercaptopropylthio)propyl D-glycero-α-D-talo-oct-2-ulopyranoside]onate