百科

(5S,7S)-5-((R)-1-((1S,4R,5R)-4-(benzyloxy)-5-methoxycyclohex-2-en-1-yl)propan-2-yl)-7-((R)-1-(benzyloxy)propan-2-yl)-2,2,3,3,9,9,10,10-octamethyl-4,8-dioxa-3,9-disilaundecane

(5S,7S)-5-((R)-1-((1S,4R,5R)-4-(benzyloxy)-5-methoxycyclohex-2-en-1-yl)propan-2-yl)-7-((R)-1-(benzyloxy)propan-2-yl)-2,2,3,3,9,9,10,10-octamethyl-4,8-dioxa-3,9-disilaundecane

CAS号：135708-90-6

英文名：(5S,7S)-5-((R)-1-((1S,4R,5R)-4-(benzyloxy)-5-methoxycyclohex-2-en-1-yl)propan-2-yl)-7-((R)-1-(benzyloxy)propan-2-yl)-2,2,3,3,9,9,10,10-octamethyl-4,8-dioxa-3,9-disilaundecane

分子式：C42H70O5Si2

分子量：711.173

合成路线

(3R,4S,6S,7R)-8-Benzyloxy-4,6-bis-(tert-butyl-dimethyl-silanyloxy)-3,7-dimethyl-octanoic acid (1S,5R,6S)-6-benzyloxy-5-methoxy-cyclohex-2-enyl ester

(3R,4S,6S,7R)-8-Benzyloxy-4,6-bis-(tert-butyl-dimethyl-silanyloxy)-3,7-dimethyl-octanoic acid (1S,5R,6S)-6-benzyloxy-5-methoxy-cyclohex-2-enyl ester

(5S,7S)-5-((R)-1-((1S,4R,5R)-4-(benzyloxy)-5-methoxycyclohex-2-en-1-yl)propan-2-yl)-7-((R)-1-(benzyloxy)propan-2-yl)-2,2,3,3,9,9,10,10-octamethyl-4,8-dioxa-3,9-disilaundecane

(5S,7S)-5-((R)-1-((1S,4R,5R)-4-(benzyloxy)-5-methoxycyclohex-2-en-1-yl)propan-2-yl)-7-((R)-1-(benzyloxy)propan-2-yl)-2,2,3,3,9,9,10,10-octamethyl-4,8-dioxa-3,9-disilaundecane

(2S,3S)-1-(benzyloxy)-2-methylhept-5-en-3-ol

(2S,3S)-1-(benzyloxy)-2-methylhept-5-en-3-ol

(5S,7S)-5-((R)-1-((1S,4R,5R)-4-(benzyloxy)-5-methoxycyclohex-2-en-1-yl)propan-2-yl)-7-((R)-1-(benzyloxy)propan-2-yl)-2,2,3,3,9,9,10,10-octamethyl-4,8-dioxa-3,9-disilaundecane

(5S,7S)-5-((R)-1-((1S,4R,5R)-4-(benzyloxy)-5-methoxycyclohex-2-en-1-yl)propan-2-yl)-7-((R)-1-(benzyloxy)propan-2-yl)-2,2,3,3,9,9,10,10-octamethyl-4,8-dioxa-3,9-disilaundecane

135708-85-9

(5S,7S)-5-((R)-1-((1S,4R,5R)-4-(benzyloxy)-5-methoxycyclohex-2-en-1-yl)propan-2-yl)-7-((R)-1-(benzyloxy)propan-2-yl)-2,2,3,3,9,9,10,10-octamethyl-4,8-dioxa-3,9-disilaundecane

(5S,7S)-5-((R)-1-((1S,4R,5R)-4-(benzyloxy)-5-methoxycyclohex-2-en-1-yl)propan-2-yl)-7-((R)-1-(benzyloxy)propan-2-yl)-2,2,3,3,9,9,10,10-octamethyl-4,8-dioxa-3,9-disilaundecane

(2R,3S,5S,6R)-1-Benzyloxy-2,6-dimethyl-oct-7-ene-3,5-diol

(2R,3S,5S,6R)-1-Benzyloxy-2,6-dimethyl-oct-7-ene-3,5-diol

(5S,7S)-5-((R)-1-((1S,4R,5R)-4-(benzyloxy)-5-methoxycyclohex-2-en-1-yl)propan-2-yl)-7-((R)-1-(benzyloxy)propan-2-yl)-2,2,3,3,9,9,10,10-octamethyl-4,8-dioxa-3,9-disilaundecane

(5S,7S)-5-((R)-1-((1S,4R,5R)-4-(benzyloxy)-5-methoxycyclohex-2-en-1-yl)propan-2-yl)-7-((R)-1-(benzyloxy)propan-2-yl)-2,2,3,3,9,9,10,10-octamethyl-4,8-dioxa-3,9-disilaundecane

上游原料

(2S,3S)-1-(benzyloxy)-2-methylhept-5-en-3-ol (2R,3S,5S,6R)-1-Benzyloxy-2,6-dimethyl-oct-7-ene-3,5-diol (3R,4S,6S,7R)-8-Benzyloxy-4,6-bis-(tert-butyl-dimethyl-silanyloxy)-3,7-dimethyl-octanoic acid (1S,5R,6S)-6-benzyloxy-5-methoxy-cyclohex-2-enyl ester

下游产品

(1R,2R,4S)-4-[(2R,3S,5S,6R)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-7-hydroxy-2,6-dimethyl-heptyl]-2-methoxy-cyclohexanol (E)-(4R,5S,7S,8R)-5,7-Bis-(tert-butyl-dimethyl-silanyloxy)-9-((1S,3R,4R)-4-hydroxy-3-methoxy-cyclohexyl)-2,4,8-trimethyl-non-2-enoic acid methyl ester (2S,3S,5S,6R)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-7-((1S,3R,4R)-4-hydroxy-3-methoxy-cyclohexyl)-2,6-dimethyl-heptanal