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N-{(2R,3R)-1-[difluoro(phenylseleno)methyl]-2,3-dihydroxypent-4-yn-1-yl}-2-methylpropane-2-sulfinamide

N-{(2R,3R)-1-[difluoro(phenylseleno)methyl]-2,3-dihydroxypent-4-yn-1-yl}-2-methylpropane-2-sulfinamide

CAS号：1359718-19-6

英文名：N-{(2R,3R)-1-[difluoro(phenylseleno)methyl]-2,3-dihydroxypent-4-yn-1-yl}-2-methylpropane-2-sulfinamide

分子式：C16H21F2NO3SSe

分子量：424.365

合成路线

5-[(tert-Butyldimethylsilyl)oxy]-1,2-dideoxy-3,4-O-(1-methylethylidene)-D-threo-pent-1-yne

5-[(tert-Butyldimethylsilyl)oxy]-1,2-dideoxy-3,4-O-(1-methylethylidene)-D-threo-pent-1-yne

N-{(2R,3R)-1-[difluoro(phenylseleno)methyl]-2,3-dihydroxypent-4-yn-1-yl}-2-methylpropane-2-sulfinamide

N-{(2R,3R)-1-[difluoro(phenylseleno)methyl]-2,3-dihydroxypent-4-yn-1-yl}-2-methylpropane-2-sulfinamide

(S)-N-((2R,3R,4R)-1,1-difluoro-3,4-dihydroxy-1-(phenylselanyl)-6-(trimethylsilyl)hex-5-yn-2-yl)-2-methylpropane-2-sulfinamide

(S)-N-((2R,3R,4R)-1,1-difluoro-3,4-dihydroxy-1-(phenylselanyl)-6-(trimethylsilyl)hex-5-yn-2-yl)-2-methylpropane-2-sulfinamide

N-{(2R,3R)-1-[difluoro(phenylseleno)methyl]-2,3-dihydroxypent-4-yn-1-yl}-2-methylpropane-2-sulfinamide

N-{(2R,3R)-1-[difluoro(phenylseleno)methyl]-2,3-dihydroxypent-4-yn-1-yl}-2-methylpropane-2-sulfinamide

(SS,2R,3R,4R)-2-tert-butanesulfinamido-3,4-(O-isopropylidene)-6-trimethylsilyl-1,1-difluoro-1-phenylselanyl-hex-5-yne

(SS,2R,3R,4R)-2-tert-butanesulfinamido-3,4-(O-isopropylidene)-6-trimethylsilyl-1,1-difluoro-1-phenylselanyl-hex-5-yne

N-{(2R,3R)-1-[difluoro(phenylseleno)methyl]-2,3-dihydroxypent-4-yn-1-yl}-2-methylpropane-2-sulfinamide

N-{(2R,3R)-1-[difluoro(phenylseleno)methyl]-2,3-dihydroxypent-4-yn-1-yl}-2-methylpropane-2-sulfinamide

N-{[(4R,5R)-5-ethynyl-2,2-dimethyl-1,3-dioxolan-4-yl]methylene}-2-methylpropane-2-sulfinamide

N-{[(4R,5R)-5-ethynyl-2,2-dimethyl-1,3-dioxolan-4-yl]methylene}-2-methylpropane-2-sulfinamide

N-{(2R,3R)-1-[difluoro(phenylseleno)methyl]-2,3-dihydroxypent-4-yn-1-yl}-2-methylpropane-2-sulfinamide

N-{(2R,3R)-1-[difluoro(phenylseleno)methyl]-2,3-dihydroxypent-4-yn-1-yl}-2-methylpropane-2-sulfinamide

上游原料

5-[(tert-Butyldimethylsilyl)oxy]-1,2-dideoxy-3,4-O-(1-methylethylidene)-D-threo-pent-1-yne (S)-N-((2R,3R,4R)-1,1-difluoro-3,4-dihydroxy-1-(phenylselanyl)-6-(trimethylsilyl)hex-5-yn-2-yl)-2-methylpropane-2-sulfinamide (SS,2R,3R,4R)-2-tert-butanesulfinamido-3,4-(O-isopropylidene)-6-trimethylsilyl-1,1-difluoro-1-phenylselanyl-hex-5-yne N-{[(4R,5R)-5-ethynyl-2,2-dimethyl-1,3-dioxolan-4-yl]methylene}-2-methylpropane-2-sulfinamide

下游产品

(SS,2R,3R,4R)-2-tert-butanesulfinamido-1,1-difluoro-5-methylenecyclopentane-3,4-diol