百科

(1S,6S,9R,13R,14S,15S,17R,19S)-15-((tert-butyldimethylsilyl)oxy)-14-hydroxy-6,13,19-trimethyl-11-methylene-9-propyl-8,20-dioxabicyclo[15.2.1]icosan-7-one

CAS号：1359738-84-3

英文名：(1S,6S,9R,13R,14S,15S,17R,19S)-15-((tert-butyldimethylsilyl)oxy)-14-hydroxy-6,13,19-trimethyl-11-methylene-9-propyl-8,20-dioxabicyclo[15.2.1]icosan-7-one

分子式：C31H58O5Si

分子量：538.875

合成路线

1312689-11-4

(1S,6S,9R,13R,17S,19S,E)-6,13,19-trimethyl-11-methylene-9-propyl-8,20-dioxabicyclo[15.2.1]icos-14-en-7-one

1359738-84-3

(1S,6S,9R,13R,14S,15S,17R,19S)-15-((tert-butyldimethylsilyl)oxy)-14-hydroxy-6,13,19-trimethyl-11-methylene-9-propyl-8,20-dioxabicyclo[15.2.1]icosan-7-one

上游原料

(1S,6S,9R,13R,17S,19S,E)-6,13,19-trimethyl-11-methylene-9-propyl-8,20-dioxabicyclo[15.2.1]icos-14-en-7-one

下游产品

(+)-(15S)-(tert-butyldimethylsilanyloxy)-(6S,13R,19S)-trimethyl-11-methylene-(9R)-propyl-8,20-dioxabicyclo[15.2.1]icosane-7,14-dione (-)-amphidinolide T4