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2,6-anhydro-3,4,5,7-tetra-O-benzyl-(1S)-C-phenyl-D-erythro-L-guloheptitol

2,6-anhydro-3,4,5,7-tetra-O-benzyl-(1S)-C-phenyl-D-erythro-L-guloheptitol

CAS号：136034-22-5

英文名：2,6-anhydro-3,4,5,7-tetra-O-benzyl-(1S)-C-phenyl-D-erythro-L-guloheptitol

分子式：C41H42O6

分子量：630.769

合成路线

(S)-[(4S,5R,6R)-3-((R)-Benzenesulfinyl)-4,5-bis-benzyloxy-6-benzyloxymethyl-5,6-dihydro-4H-pyran-2-yl]-phenyl-methanol

(S)-[(4S,5R,6R)-3-((R)-Benzenesulfinyl)-4,5-bis-benzyloxy-6-benzyloxymethyl-5,6-dihydro-4H-pyran-2-yl]-phenyl-methanol

2,6-anhydro-3,4,5,7-tetra-O-benzyl-(1S)-C-phenyl-D-erythro-L-guloheptitol

2,6-anhydro-3,4,5,7-tetra-O-benzyl-(1S)-C-phenyl-D-erythro-L-guloheptitol

(S)-[(4S,5R,6R)-3-((S)-Benzenesulfinyl)-4,5-bis-benzyloxy-6-benzyloxymethyl-5,6-dihydro-4H-pyran-2-yl]-phenyl-methanol

(S)-[(4S,5R,6R)-3-((S)-Benzenesulfinyl)-4,5-bis-benzyloxy-6-benzyloxymethyl-5,6-dihydro-4H-pyran-2-yl]-phenyl-methanol

2,6-anhydro-3,4,5,7-tetra-O-benzyl-(1S)-C-phenyl-D-erythro-L-guloheptitol

2,6-anhydro-3,4,5,7-tetra-O-benzyl-(1S)-C-phenyl-D-erythro-L-guloheptitol

(2S,4S,4aS,6R,7R,8S,8aR)-7,8-Bis-benzyloxy-6-benzyloxymethyl-2,4-diphenyl-hexahydro-pyrano[3,2-d][1,3]dioxine

(2S,4S,4aS,6R,7R,8S,8aR)-7,8-Bis-benzyloxy-6-benzyloxymethyl-2,4-diphenyl-hexahydro-pyrano[3,2-d][1,3]dioxine

2,6-anhydro-3,4,5,7-tetra-O-benzyl-(1S)-C-phenyl-D-erythro-L-guloheptitol

2,6-anhydro-3,4,5,7-tetra-O-benzyl-(1S)-C-phenyl-D-erythro-L-guloheptitol

D-arabino-Hept-2-enitol,2,6-anhydro-3-deoxy-1-C-phenyl-4,5,7-tris-O-(phenylmethyl)-, (1S)-

D-arabino-Hept-2-enitol,2,6-anhydro-3-deoxy-1-C-phenyl-4,5,7-tris-O-(phenylmethyl)-, (1S)-

2,6-anhydro-3,4,5,7-tetra-O-benzyl-(1S)-C-phenyl-D-erythro-L-guloheptitol

2,6-anhydro-3,4,5,7-tetra-O-benzyl-(1S)-C-phenyl-D-erythro-L-guloheptitol

上游原料

(2S,4S,4aS,6R,7R,8S,8aR)-7,8-Bis-benzyloxy-6-benzyloxymethyl-2,4-diphenyl-hexahydro-pyrano[3,2-d][1,3]dioxine (S)-[(4S,5R,6R)-3-((S)-Benzenesulfinyl)-4,5-bis-benzyloxy-6-benzyloxymethyl-5,6-dihydro-4H-pyran-2-yl]-phenyl-methanol (S)-[(4S,5R,6R)-3-((R)-Benzenesulfinyl)-4,5-bis-benzyloxy-6-benzyloxymethyl-5,6-dihydro-4H-pyran-2-yl]-phenyl-methanol

下游产品

β-D-Glucopyranosylphenylmethane [(R)-Phenyl-((2S,3S,4R,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-methyl]-carbamic acid tert-butyl ester C-[(R)-C-Phenyl-C-((2S,3S,4R,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)]-methylamine (2S,3R,4R,5S,6R)-2-((R)-Amino-phenyl-methyl)-6-hydroxymethyl-tetrahydro-pyran-3,4,5-triol; compound with trifluoro-acetic acid (2R,3R,4S,5R)-3,4,5-Tris-benzyloxy-2-benzyloxymethyl-6-[1-phenyl-meth-(Z)-ylidene]-tetrahydro-pyran [(R)-Phenyl-((2S,3R,4R,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yl)-methyl]-carbamic acid tert-butyl ester