百科

((1aR,1a1R,3aR,5R,5aR)-1a-(((2S,3R,4S,5R,6R)-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)-3-((2-chloro-2-methylpropanoyl)oxy)tetrahydro-2H-pyran-2-yl)oxy)-5-((tert-butyldimethylsilyl)oxy)-2-oxohexahydro-3-oxacyclobuta[cd]pentalen-1a1(1H)-yl)methyl benzoate

CAS号：1361049-65-1

英文名：((1aR,1a1R,3aR,5R,5aR)-1a-(((2S,3R,4S,5R,6R)-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)-3-((2-chloro-2-methylpropanoyl)oxy)tetrahydro-2H-pyran-2-yl)oxy)-5-((tert-butyldimethylsilyl)oxy)-2-oxohexahydro-3-oxacyclobuta[cd]pentalen-1a1(1H)-yl)methyl benzoate

分子式：C53H63ClO12Si

分子量：955.599

合成路线

1361049-60-6

methyl (3R,5R)-5-(tert-butyldimethylsilyloxy)-3-hydroxy-6-heptenoate

1361049-65-1

((1aR,1a1R,3aR,5R,5aR)-1a-(((2S,3R,4S,5R,6R)-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)-3-((2-chloro-2-methylpropanoyl)oxy)tetrahydro-2H-pyran-2-yl)oxy)-5-((tert-butyldimethylsilyl)oxy)-2-oxohexahydro-3-oxacyclobuta[cd]pentalen-1a1(1H)-yl)methyl benzoate

1361049-75-3

((1aR,1a1R,3aR,5R,5aR)-1a-(((2R,3R,4S,5R,6R)-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)-3-((2-chloro-2-methylpropanoyl)oxy)tetrahydro-2H-pyran-2-yl)oxy)-5-((tert-butyldimethylsilyl)oxy)-2-oxohexahydro-3-oxacyclobuta[cd]pentalen-1a1(1H)-yl)methyl benzoate

上游原料

methyl (3R,5R)-5-(tert-butyldimethylsilyloxy)-3-hydroxy-6-heptenoate

下游产品

(1aR,1a1R,3aR,5R,5aR)-1a-(((2S,3R,4R,5R,6R)-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)-3-hydroxytetrahydro-2H-pyran-2-yl)oxy)-5-((tert-butyldimethylsilyl)oxy)-1a1-(hydroxymethyl)-2-methyloctahydro-3-oxacyclobuta[cd]pentalen-2-ol