百科

(3S,4R,5R)-3,5-dimethyl-7-(trityloxy)hept-1-en-4-ol

(3S,4R,5R)-3,5-dimethyl-7-(trityloxy)hept-1-en-4-ol

CAS号：1361130-21-3

英文名：(3S,4R,5R)-3,5-dimethyl-7-(trityloxy)hept-1-en-4-ol

分子式：C28H32O2

分子量：400.552

合成路线

dipropan-2-yl 2-but-2-enyl-1,3,2-dioxaborolane-4,5-dicarboxylate

dipropan-2-yl 2-but-2-enyl-1,3,2-dioxaborolane-4,5-dicarboxylate

(R)-2-methyl-4-(trityloxy)butanal

(R)-2-methyl-4-(trityloxy)butanal

(3S,4R,5R)-3,5-dimethyl-7-(trityloxy)hept-1-en-4-ol

(3S,4R,5R)-3,5-dimethyl-7-(trityloxy)hept-1-en-4-ol

(R)-tert-butyldimethyl(2-methyl-4-(trityloxy)butoxy)silane

(R)-tert-butyldimethyl(2-methyl-4-(trityloxy)butoxy)silane

(3S,4R,5R)-3,5-dimethyl-7-(trityloxy)hept-1-en-4-ol

(3S,4R,5R)-3,5-dimethyl-7-(trityloxy)hept-1-en-4-ol

(R)-2-methyl-4-(trityloxy)butan-1-ol

(R)-2-methyl-4-(trityloxy)butan-1-ol

(3S,4R,5R)-3,5-dimethyl-7-(trityloxy)hept-1-en-4-ol

(3S,4R,5R)-3,5-dimethyl-7-(trityloxy)hept-1-en-4-ol

(3R)-4-(tert-butyl(dimethyl)silyloxy)-3-methylbutan-1-ol

(3R)-4-(tert-butyl(dimethyl)silyloxy)-3-methylbutan-1-ol

(3S,4R,5R)-3,5-dimethyl-7-(trityloxy)hept-1-en-4-ol

(3S,4R,5R)-3,5-dimethyl-7-(trityloxy)hept-1-en-4-ol

上游原料

(3R)-4-(tert-butyl(dimethyl)silyloxy)-3-methylbutan-1-ol (R)-tert-butyldimethyl(2-methyl-4-(trityloxy)butoxy)silane (R)-2-methyl-4-(trityloxy)butanal (R)-2-methyl-4-(trityloxy)butan-1-ol dipropan-2-yl 2-but-2-enyl-1,3,2-dioxaborolane-4,5-dicarboxylate

下游产品

(3R,4R,5S,6R,9S,10S,12R)-12-((tert-butyldimethylsilyl)oxy)-6-(((3,4-dimethoxybenzyl)oxy)methoxy)-10-methoxy-3,5,9-trimethyl-14-oxo-1-(trityloxy)tetradecan-4-yl acetate (3R,4R,5S,6R,9S,10S,12S)-12,14-bis((tert-butyldimethylsilyl)oxy)-6-hydroxy-10-methoxy-3,5,9-trimethyl-1-(trityloxy)tetradecan-4-yl acetate (3S,4R,5R)-1,2-dihydroxy-3,5-dimethyl-7-(trityloxy)heptan-4-yl acetate (3R,4R,5S,6R,9S,10S,12S)-12,14-bis((tert-butyldimethylsilyl)oxy)-6-(((3,4-dimethoxybenzyl)oxy)methoxy)-10-methoxy-3,5,9-trimethyl-1-(trityloxy)tetradecan-4-yl acetate (2R,3R,4R)-2,4-dimethyl-1-oxo-6-(trityloxy)hexan-3-yl acetate (3R,4R,5S,6R,9S,10S,12S)-12-((tert-butyldimethylsilyl)oxy)-6-(((3,4-dimethoxybenzyl)oxy)methoxy)-14-hydroxy-10-methoxy-3,5,9-trimethyl-1-(trityloxy)tetradecan-4-yl acetate