百科

(1R,2R,3R,5S,6R,7R,7aR)-1,2-dibenzyloxy-6,7-dihydroxy-3-hydroxymethyl-5-methylpyrrolizidine

(1R,2R,3R,5S,6R,7R,7aR)-1,2-dibenzyloxy-6,7-dihydroxy-3-hydroxymethyl-5-methylpyrrolizidine

CAS号：1361194-09-3

英文名：(1R,2R,3R,5S,6R,7R,7aR)-1,2-dibenzyloxy-6,7-dihydroxy-3-hydroxymethyl-5-methylpyrrolizidine

分子式：C23H29NO5

分子量：399.48

合成路线

(1R,2R,3R,5S,6R,7R,7aR)-1,2-dibenzyloxy-3-tert-butyldiphenylsilyloxymethyl-6,7-dihydroxy-5-methylpyrrolizidine

(1R,2R,3R,5S,6R,7R,7aR)-1,2-dibenzyloxy-3-tert-butyldiphenylsilyloxymethyl-6,7-dihydroxy-5-methylpyrrolizidine

(1R,2R,3R,5S,6R,7R,7aR)-1,2-dibenzyloxy-6,7-dihydroxy-3-hydroxymethyl-5-methylpyrrolizidine

(1R,2R,3R,5S,6R,7R,7aR)-1,2-dibenzyloxy-6,7-dihydroxy-3-hydroxymethyl-5-methylpyrrolizidine

(2R,3R,4R,5R)-3,4-dibenzyloxy-N-benzyloxycarbonyl-2'-O-tert-butyldiphenylsilyl-2,5-bis(hydroxymethyl)pyrrolidine

(2R,3R,4R,5R)-3,4-dibenzyloxy-N-benzyloxycarbonyl-2'-O-tert-butyldiphenylsilyl-2,5-bis(hydroxymethyl)pyrrolidine

(1R,2R,3R,5S,6R,7R,7aR)-1,2-dibenzyloxy-6,7-dihydroxy-3-hydroxymethyl-5-methylpyrrolizidine

(1R,2R,3R,5S,6R,7R,7aR)-1,2-dibenzyloxy-6,7-dihydroxy-3-hydroxymethyl-5-methylpyrrolizidine

(E)-4-[(2'R,3'R,4'R,5'R)-3',4'-dibenzyloxy-N-benzyloxycarbonyl-5'-tert-butyldiphenylsilyloximethylpyrrolidin-2'-yl]but-3-en-2-one

(E)-4-[(2'R,3'R,4'R,5'R)-3',4'-dibenzyloxy-N-benzyloxycarbonyl-5'-tert-butyldiphenylsilyloximethylpyrrolidin-2'-yl]but-3-en-2-one

(1R,2R,3R,5S,6R,7R,7aR)-1,2-dibenzyloxy-6,7-dihydroxy-3-hydroxymethyl-5-methylpyrrolizidine

(1R,2R,3R,5S,6R,7R,7aR)-1,2-dibenzyloxy-6,7-dihydroxy-3-hydroxymethyl-5-methylpyrrolizidine

(2R,3R,4R,5R)-3,4-dibenzyloxy-N-benzyloxycarbonyl-2-tert-butyldiphenylsilyloxymethyl-5-[(1'R,2'S)-1'-2'-dihydroxy-3'-oxobutyl]pyrrolidine

(2R,3R,4R,5R)-3,4-dibenzyloxy-N-benzyloxycarbonyl-2-tert-butyldiphenylsilyloxymethyl-5-[(1'R,2'S)-1'-2'-dihydroxy-3'-oxobutyl]pyrrolidine

(1R,2R,3R,5S,6R,7R,7aR)-1,2-dibenzyloxy-6,7-dihydroxy-3-hydroxymethyl-5-methylpyrrolizidine

(1R,2R,3R,5S,6R,7R,7aR)-1,2-dibenzyloxy-6,7-dihydroxy-3-hydroxymethyl-5-methylpyrrolizidine

上游原料

(E)-4-[(2'R,3'R,4'R,5'R)-3',4'-dibenzyloxy-N-benzyloxycarbonyl-5'-tert-butyldiphenylsilyloximethylpyrrolidin-2'-yl]but-3-en-2-one (2R,3R,4R,5R)-3,4-dibenzyloxy-N-benzyloxycarbonyl-2'-O-tert-butyldiphenylsilyl-2,5-bis(hydroxymethyl)pyrrolidine (1R,2R,3R,5S,6R,7R,7aR)-1,2-dibenzyloxy-3-tert-butyldiphenylsilyloxymethyl-6,7-dihydroxy-5-methylpyrrolizidine (2R,3R,4R,5R)-3,4-dibenzyloxy-N-benzyloxycarbonyl-2-tert-butyldiphenylsilyloxymethyl-5-[(1'R,2'S)-1'-2'-dihydroxy-3'-oxobutyl]pyrrolidine

下游产品

(+)-6,7-di-epi-hyacinthacine C5