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(4S)-4-[(tert-butyldimethylsilyl)oxy]-3-methyl-cyclohex-2-en-1-one

(4S)-4-[(tert-butyldimethylsilyl)oxy]-3-methyl-cyclohex-2-en-1-one

CAS号：136611-25-1

英文名：(4S)-4-[(tert-butyldimethylsilyl)oxy]-3-methyl-cyclohex-2-en-1-one

分子式：C13H24O2Si

分子量：240.414

合成路线

(-)-4-acetoxy-3-methyl-2-cyclohexen-1-one

(-)-4-acetoxy-3-methyl-2-cyclohexen-1-one

(4S)-4-[(tert-butyldimethylsilyl)oxy]-3-methyl-cyclohex-2-en-1-one

(4S)-4-[(tert-butyldimethylsilyl)oxy]-3-methyl-cyclohex-2-en-1-one

上游原料

(-)-4-acetoxy-3-methyl-2-cyclohexen-1-one

下游产品

carbonic acid (1S,2S)-2-[2-(tert-butyldimethylsilyloxy)-5-hydroxy-1-methyl-cyclohexyl]ethyl ester (1R,3R,5S,8S)-3-(tert-butyldimethylsilyloxy)-8-methyl-2-methylene-7-oxo-6-oxabicyclo[3.2.1]octane-8-carbaldehyde (3S,4S)-4-(tert-butyldimethylsilyloxy)-3-(2-hydroxyethyl)-3-methyl-cyclohexanol (3S,4S)-4-<(t-butyldimethylsilyl)oxy>-3-methyl-3-vinylcyclohexanone (1'R,3'S)-(+)-cis-(3'-hydroxy-2',2'-dimethyl-6'-methylene-1'-cyclohexyl)methanol (1S,5S)-8,8-dimethyl-2-oxo-6-oxabicyclo[3.2.1]octan-7-one (1S,2R,3S,4R,5R)-2-benzyloxymethyl-5-(tert-butyldimethylsilyloxy)-4-chloromethyl-4-methoxymethoxy-2-methyl-3-vinyl-cyclohexyl benzoate (3S,4S,5R,6S,8R)-8-(tert-butyldimethylsilyloxy)-5-hydroxymethyl-5-methyl-1-oxaspiro[2.5]octane-4,6-carbolactone carbonic acid (1R,2S)-2-[2-(tert-butyldimethylsilyloxy)-1-methyl-5-oxo-cyclohexyl]ethyl ester