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(-)-(2R,3S,6R,E)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylhept-4-en-3-ol

(-)-(2R,3S,6R,E)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylhept-4-en-3-ol

CAS号：1370254-24-2

英文名：(-)-(2R,3S,6R,E)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylhept-4-en-3-ol

分子式：C22H38O3Si

分子量：378.621

合成路线

dimethyl (-)-(R)-4-(benzyloxy)-3-methyl-2-oxobutylphosphonate

dimethyl (-)-(R)-4-(benzyloxy)-3-methyl-2-oxobutylphosphonate

(-)-(2R,3S,6R,E)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylhept-4-en-3-ol

(-)-(2R,3S,6R,E)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylhept-4-en-3-ol

上游原料

dimethyl (-)-(R)-4-(benzyloxy)-3-methyl-2-oxobutylphosphonate

下游产品

(2R,5S,6R)-7-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-2,6-dimethylheptanal ethyl (-)-(R)-2-{(2R,3R,6S)-6-[(R)-1-(benzyloxy)propan-2-yl]-3-methyltetrahydro-2H-pyran-2-yl}-2-iodopropanoate (+)-(5S,8R)-5-[(R)-1-(benzyloxy)propan-2-yl]-2,2,3,3,8,11,11,12,12-nonamethyl-4,10-dioxa-3,11-disilatridecane ethyl (-)-(4R,7S,8R,E)-9-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,4,8-trimethylnon-2-enoate ethyl (-)-(4R,7S,8R,E)-9-(benzyloxy)-7-hydroxy-2,4,8-trimethylnon-2-enoate (+)-(2R,5S,6R)-7-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-2,6-dimethylheptan-1-ol (+)-(2R,3S,6R)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylheptan-3-ol ethyl (+)-(R)-2-{(2R,3R,6S)-6-[(R)-1-(benzyloxy)propan-2-yl]-3-methyltetrahydro-2H-pyran-2-yl}propanoate ethyl (-)-(S)-2-{(2R,3R,6S)-6-[(R)-1-(benzyloxy)propan-2-yl]-3-methyltetrahydro-2H-pyran-2-yl}propanoate