百科

(+)-(5R,8R)-5-[(R)-1-(benzyloxy)propan-2-yl]-2,2,3,3,8,11,11,12,12-nonamethyl-4,10-dioxa-3,11-disilatridecane

(+)-(5R,8R)-5-[(R)-1-(benzyloxy)propan-2-yl]-2,2,3,3,8,11,11,12,12-nonamethyl-4,10-dioxa-3,11-disilatridecane

CAS号：1370254-29-7

英文名：(+)-(5R,8R)-5-[(R)-1-(benzyloxy)propan-2-yl]-2,2,3,3,8,11,11,12,12-nonamethyl-4,10-dioxa-3,11-disilatridecane

分子式：C28H54O3Si2

分子量：494.898

合成路线

dimethyl (-)-(R)-4-(benzyloxy)-3-methyl-2-oxobutylphosphonate

dimethyl (-)-(R)-4-(benzyloxy)-3-methyl-2-oxobutylphosphonate

(+)-(5R,8R)-5-[(R)-1-(benzyloxy)propan-2-yl]-2,2,3,3,8,11,11,12,12-nonamethyl-4,10-dioxa-3,11-disilatridecane

(+)-(5R,8R)-5-[(R)-1-(benzyloxy)propan-2-yl]-2,2,3,3,8,11,11,12,12-nonamethyl-4,10-dioxa-3,11-disilatridecane

(+)-(2R,6R,E)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylhept-4-en-3-one

(+)-(2R,6R,E)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylhept-4-en-3-one

(+)-(5R,8R)-5-[(R)-1-(benzyloxy)propan-2-yl]-2,2,3,3,8,11,11,12,12-nonamethyl-4,10-dioxa-3,11-disilatridecane

(+)-(5R,8R)-5-[(R)-1-(benzyloxy)propan-2-yl]-2,2,3,3,8,11,11,12,12-nonamethyl-4,10-dioxa-3,11-disilatridecane

上游原料

dimethyl (-)-(R)-4-(benzyloxy)-3-methyl-2-oxobutylphosphonate (+)-(2R,6R,E)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylhept-4-en-3-one

下游产品

(2R,5R,6R)-7-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-2,6-dimethylheptanal ethyl (-)-(R)-2-{(2R,3R,6R)-6-[(R)-1-(benzyloxy)propan-2-yl]-3-methyltetrahydro-2H-pyran-2-yl}-2-iodopropanoate ethyl (-)-(4R,7R,8R,E)-9-(benzyloxy)-7-hydroxy-2,4,8-trimethylnon-2-enoate ethyl (-)-(4R,7R,8R,E)-9-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,4,8-trimethylnon-2-enoate ethyl (-)-(R)-2-{(2R,3R,6R)-6-[(R)-1-(benzyloxy)propan-2-yl]-3-methyltetrahydro-2H-pyran-2-yl}propanoate ethyl (-)-(S)-2-{(2R,3R,6R)-6-[(R)-1-(benzyloxy)propan-2-yl]-3-methyltetrahydro-2H-pyran-2-yl}propanoate (-)-(2R,5R,6R)-7-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-2,6-dimethylheptan-1-ol