百科

ethyl (-)-(R)-2-{(2R,3R,6R)-6-[(R)-1-(benzyloxy)propan-2-yl]-3-methyltetrahydro-2H-pyran-2-yl}-2-iodopropanoate

ethyl (-)-(R)-2-{(2R,3R,6R)-6-[(R)-1-(benzyloxy)propan-2-yl]-3-methyltetrahydro-2H-pyran-2-yl}-2-iodopropanoate

CAS号：1370254-41-3

英文名：ethyl (-)-(R)-2-{(2R,3R,6R)-6-[(R)-1-(benzyloxy)propan-2-yl]-3-methyltetrahydro-2H-pyran-2-yl}-2-iodopropanoate

分子式：C21H31IO4

分子量：474.373

合成路线

ethyl (-)-(4R,7R,8R,E)-9-(benzyloxy)-7-hydroxy-2,4,8-trimethylnon-2-enoate

ethyl (-)-(4R,7R,8R,E)-9-(benzyloxy)-7-hydroxy-2,4,8-trimethylnon-2-enoate

ethyl (-)-(R)-2-{(2R,3R,6R)-6-[(R)-1-(benzyloxy)propan-2-yl]-3-methyltetrahydro-2H-pyran-2-yl}-2-iodopropanoate

ethyl (-)-(R)-2-{(2R,3R,6R)-6-[(R)-1-(benzyloxy)propan-2-yl]-3-methyltetrahydro-2H-pyran-2-yl}-2-iodopropanoate

(+)-(2R,3R,6R)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylheptan-3-ol

(+)-(2R,3R,6R)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylheptan-3-ol

ethyl (-)-(R)-2-{(2R,3R,6R)-6-[(R)-1-(benzyloxy)propan-2-yl]-3-methyltetrahydro-2H-pyran-2-yl}-2-iodopropanoate

ethyl (-)-(R)-2-{(2R,3R,6R)-6-[(R)-1-(benzyloxy)propan-2-yl]-3-methyltetrahydro-2H-pyran-2-yl}-2-iodopropanoate

(+)-(5R,8R)-5-[(R)-1-(benzyloxy)propan-2-yl]-2,2,3,3,8,11,11,12,12-nonamethyl-4,10-dioxa-3,11-disilatridecane

(+)-(5R,8R)-5-[(R)-1-(benzyloxy)propan-2-yl]-2,2,3,3,8,11,11,12,12-nonamethyl-4,10-dioxa-3,11-disilatridecane

ethyl (-)-(R)-2-{(2R,3R,6R)-6-[(R)-1-(benzyloxy)propan-2-yl]-3-methyltetrahydro-2H-pyran-2-yl}-2-iodopropanoate

ethyl (-)-(R)-2-{(2R,3R,6R)-6-[(R)-1-(benzyloxy)propan-2-yl]-3-methyltetrahydro-2H-pyran-2-yl}-2-iodopropanoate

(-)-(2R,5R,6R)-7-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-2,6-dimethylheptan-1-ol

(-)-(2R,5R,6R)-7-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-2,6-dimethylheptan-1-ol

ethyl (-)-(R)-2-{(2R,3R,6R)-6-[(R)-1-(benzyloxy)propan-2-yl]-3-methyltetrahydro-2H-pyran-2-yl}-2-iodopropanoate

ethyl (-)-(R)-2-{(2R,3R,6R)-6-[(R)-1-(benzyloxy)propan-2-yl]-3-methyltetrahydro-2H-pyran-2-yl}-2-iodopropanoate

(2R,5R,6R)-7-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-2,6-dimethylheptanal

(2R,5R,6R)-7-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-2,6-dimethylheptanal

ethyl (-)-(R)-2-{(2R,3R,6R)-6-[(R)-1-(benzyloxy)propan-2-yl]-3-methyltetrahydro-2H-pyran-2-yl}-2-iodopropanoate

ethyl (-)-(R)-2-{(2R,3R,6R)-6-[(R)-1-(benzyloxy)propan-2-yl]-3-methyltetrahydro-2H-pyran-2-yl}-2-iodopropanoate

ethyl (-)-(4R,7R,8R,E)-9-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,4,8-trimethylnon-2-enoate

ethyl (-)-(4R,7R,8R,E)-9-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,4,8-trimethylnon-2-enoate

ethyl (-)-(R)-2-{(2R,3R,6R)-6-[(R)-1-(benzyloxy)propan-2-yl]-3-methyltetrahydro-2H-pyran-2-yl}-2-iodopropanoate

ethyl (-)-(R)-2-{(2R,3R,6R)-6-[(R)-1-(benzyloxy)propan-2-yl]-3-methyltetrahydro-2H-pyran-2-yl}-2-iodopropanoate

dimethyl (-)-(R)-4-(benzyloxy)-3-methyl-2-oxobutylphosphonate

dimethyl (-)-(R)-4-(benzyloxy)-3-methyl-2-oxobutylphosphonate

ethyl (-)-(R)-2-{(2R,3R,6R)-6-[(R)-1-(benzyloxy)propan-2-yl]-3-methyltetrahydro-2H-pyran-2-yl}-2-iodopropanoate

ethyl (-)-(R)-2-{(2R,3R,6R)-6-[(R)-1-(benzyloxy)propan-2-yl]-3-methyltetrahydro-2H-pyran-2-yl}-2-iodopropanoate

(+)-(2R,6R,E)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylhept-4-en-3-one

(+)-(2R,6R,E)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylhept-4-en-3-one

ethyl (-)-(R)-2-{(2R,3R,6R)-6-[(R)-1-(benzyloxy)propan-2-yl]-3-methyltetrahydro-2H-pyran-2-yl}-2-iodopropanoate

ethyl (-)-(R)-2-{(2R,3R,6R)-6-[(R)-1-(benzyloxy)propan-2-yl]-3-methyltetrahydro-2H-pyran-2-yl}-2-iodopropanoate

(+)-(2R,3R,6R,E)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylhept-4-en-3-ol

(+)-(2R,3R,6R,E)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylhept-4-en-3-ol

ethyl (-)-(R)-2-{(2R,3R,6R)-6-[(R)-1-(benzyloxy)propan-2-yl]-3-methyltetrahydro-2H-pyran-2-yl}-2-iodopropanoate

ethyl (-)-(R)-2-{(2R,3R,6R)-6-[(R)-1-(benzyloxy)propan-2-yl]-3-methyltetrahydro-2H-pyran-2-yl}-2-iodopropanoate

上游原料

(+)-(2R,3R,6R)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylheptan-3-ol (2R,5R,6R)-7-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-2,6-dimethylheptanal (+)-(5R,8R)-5-[(R)-1-(benzyloxy)propan-2-yl]-2,2,3,3,8,11,11,12,12-nonamethyl-4,10-dioxa-3,11-disilatridecane ethyl (-)-(4R,7R,8R,E)-9-(benzyloxy)-7-hydroxy-2,4,8-trimethylnon-2-enoate dimethyl (-)-(R)-4-(benzyloxy)-3-methyl-2-oxobutylphosphonate ethyl (-)-(4R,7R,8R,E)-9-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,4,8-trimethylnon-2-enoate (+)-(2R,6R,E)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylhept-4-en-3-one (-)-(2R,5R,6R)-7-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-2,6-dimethylheptan-1-ol (+)-(2R,3R,6R,E)-1-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-2,6-dimethylhept-4-en-3-ol

下游产品

ethyl (-)-(R)-2-{(2R,3R,6R)-6-[(R)-1-(benzyloxy)propan-2-yl]-3-methyltetrahydro-2H-pyran-2-yl}propanoate ethyl (-)-(S)-2-{(2R,3R,6R)-6-[(R)-1-(benzyloxy)propan-2-yl]-3-methyltetrahydro-2H-pyran-2-yl}propanoate